Citation: Zhenqiang Guo, Huicong Yang, Qian Wei, Shengjun Xu, Guangjian Hu, Shuo Bai, Feng Li. Dual-additives enable stable electrode-electrolyte interfaces for long life Li-SPAN batteries[J]. Chinese Chemical Letters, ;2024, 35(5): 108622. doi: 10.1016/j.cclet.2023.108622 shu

Dual-additives enable stable electrode-electrolyte interfaces for long life Li-SPAN batteries

Zhenqiang Guo ^{a, b, 1} ,
Huicong Yang ^{a, b, 1} ,
Qian Wei ^{a, b} ,
Shengjun Xu ^{a, b} ,
Guangjian Hu ^{a, b, e, *,} ,
Shuo Bai ^{a, b} ,
Feng Li ^{a, b, c, d, *,}

a.
School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
b.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
c.
Department of Biochemistry and Molecular Biology, College of Life Science, China Medical University, Shenyang 110122, China
d.
Dalian National Laboratory for Clean Energy, Dalian 116023, China
e.
Shenyang King Power Technology Co., Ltd., Shenyang 110016, China

gjhu@imr.ac.cn

fli@imr.ac.cn

Received Date: 27 April 2023
Revised Date: 16 May 2023
Accepted Date: 29 May 2023
Available Online: 30 May 2023

Figures(6)

Sulfurized polyacrylonitrile (SPAN) is proposed as a promising cathode material for lithium sulfur batteries. However, the continuous side reactions at the electrolyte-electrode interfaces as well as the slow redox kinetics of SPAN cathode deteriorate the electrochemical performance. In this study, an electrolyte with dual-additives comprising 2-fluoropyridine (2-FP) and lithium difluorobis (oxalato) phosphate (LiDFBOP) was used to improve the performance of Li||SPAN cells. 2-FP has a lower lowest occupied molecular orbital energy than that of the solvents in the electrolyte, leading to its prior reduction. A LiF-rich film can be formed on the electrode, effectively improving the stability of the electrolyte-electrode interfaces and prolonging the life. Simultaneously, LiDFBOP could form an electrolyte-electrode interface film containing a large amount of Li_xPO_yF_z species, compensating for the kinetic deterioration caused by the lower ionic conductive of LiF formed at the electrolyte-electrode interface. Hence, an electrode-interface film with good chemical stability and high Li⁺ transport was established by LiF and Li_xPO_yF_z-rich species. The Li||SPAN cell with the electrolyte containing dual-additives demonstrates an excellent capacity retention of 97.5% after 200 cycles at 1.0 C, 25 ℃, comparing to 56.2% capacity retention without additives. Moreover, the rate capacities of cells with dual-additives can reach 1128.1 mAh/g at 5 C, comparing to only 813.5 mAh/g using electrolyte without additives. Our results shown that the dual-additives in electrolyte provide a promising strategy for practical application of lithium sulfur batteries with SPAN cathodes.
- Sulfurized polyacrylonitrile,
- Lithium metal,
- Interface film,
- 2-Fluoropyridine,
- Difluorobis (oxalato) phosphate
1. [1]
  M. Ryu, Y.K. Hong, S.Y. Lee, J.H. Park, Nat. Commun. 14 (2023) 1316. doi: 10.1038/s41467-023-37009-7
2. [2]
  J. Kang, D.Y. Han, S. Kim, J. Ryu, S. Park, Adv. Mater. 35 (2023) 2203194. doi: 10.1002/adma.202203194
3. [3]
  G.H. Al-Shawesh, J.W. Zhu, W. Zhang, et al., Chin. Chem. Lett. 34 (2023) 108190. doi: 10.1016/j.cclet.2023.108190
4. [4]
  D. Wang, H. Xie, Q. Liu, et al., Angew. Chem. Int. Ed. 62 (2023) e202302767. doi: 10.1002/anie.202302767
5. [5]
  A. Benitez, D. Brandell, One Earth 5 (2022) 224–226. doi: 10.1016/j.oneear.2022.02.009
6. [6]
  Z. Jin, X. Ma, L. Qiu, et al., Ionics 28 (2022) 1157–1166. doi: 10.1007/s11581-021-04350-0
7. [7]
  P.L. Feng, W.S. Hou, Z. Bai, et al., Chin. Chem. Lett. 34 (2023) 107427. doi: 10.1016/j.cclet.2022.04.025
8. [8]
  X.Y. Li, S. Feng, C.X. Zhao, et al., J. Am. Chem. Soc. 32 (2022) 14638–14646. doi: 10.1021/jacs.2c04176
9. [9]
  C.X. Zhao, W.Z. Chen, Z. Meng, et al., EcoMat 3 (2021) e12066. doi: 10.1002/eom2.12066
10. [10]
  B. He, Z.X. Rao, Z.X. Cheng, et al., Adv. Energy Mater. 11 (2021) 2003690. doi: 10.1002/aenm.202003690
11. [11]
  W.J. Chen, B.Q. Li, C.X. Zhao, et al., Angew. Chem. Int. Ed. 59 (2020) 10732–10745. doi: 10.1002/anie.201912701
12. [12]
  Z.Y. Shen, W.D. Zhang, S.L. Mao, et al., ACS Energy Lett. 6 (2021) 2673–2681. doi: 10.1021/acsenergylett.1c01091
13. [13]
  S.M. Sabet, N. Sapkota, S. Chiluwal, et al., ACS Sustain. Chem. Eng. 11 (2023) 2314–2323. doi: 10.1021/acssuschemeng.2c05886
14. [14]
  Y. Liu, D. Yang, W. Yan, Q. Huang, Y. Wu, iScience 19 (2019) 316–325. doi: 10.1016/j.isci.2019.07.027
15. [15]
  W.J. Chen, C.X. Zhao, B.Q. Li, et al., Energy Environ. Mater. 3 (2020) 160–165. doi: 10.1002/eem2.12073
16. [16]
  A.A. Razzaq, G. Chen, X. Zhao, et al., J. Energy Chem. 61 (2021) 170–178. doi: 10.1016/j.jechem.2021.01.012
17. [17]
  H.G. Lee, S.Y. Kim, J.S. Lee, Npj Comput. Mater. 103 (2022) 4723. doi: 10.3390/cancers14194723
18. [18]
  A. Aleshin, S. Bravo, K. Redquest, K.N. Wood, ACS Appl. Mater. Interfaces 13 (2021) 2654–2661. doi: 10.1021/acsami.0c19269
19. [19]
  S. Fang, Y. Zhang, X. Liu, Chem. Eng. J. 426 (2021) 131880. doi: 10.1016/j.cej.2021.131880
20. [20]
  H.J. Yang, A. Naveed, Q.Y. Li, et al., Energy Storage Mater. 15 (2018) 299–307. doi: 10.1016/j.ensm.2018.05.014
21. [21]
  Y.K. Liu, C.Z. Zhao, J. Du, et al., Small 19 (2022) 2205315.
22. [22]
  Y. Deng, M. Wang, C. Fan, C. Luo, J. Gao, Nano Lett. 21 (2021) 1896–1901. doi: 10.1021/acs.nanolett.1c00140
23. [23]
  X.Z. Zheng, G.H. Fang, Y. Pan, et al., J. Power Sources 439 (2019) 227081. doi: 10.1016/j.jpowsour.2019.227081
24. [24]
  B. Tong, J.W. Wang, Z.J. Liu, et al., J. Power Sources 400 (2018) 225–231. doi: 10.1016/j.jpowsour.2018.08.007
25. [25]
  Y.L. Ma, Z.X. Zhou, C.J. Li, et al., Energy Storage Mater. 11 (2018) 197–204. doi: 10.1016/j.ensm.2017.10.015
26. [26]
  Y. Li, Y.L. An, Y. Tian, et al., J. Electrochem. Soc. 166 (2019) A2736–A2740. doi: 10.1149/2.0081913jes
27. [27]
  Q. Wu, Y. Qan, X. Tang, et al., ACS Appl. Energy Mater. 4 (2021) 10234–10243. doi: 10.1021/acsaem.1c02115
28. [28]
  Z.K. Xie, Z.J. Wu, X.W. An, et al., Chem. Eng. J. 393 (2020) 124789. doi: 10.1016/j.cej.2020.124789
29. [29]
  Z.K. Xie, X.W. An, Z.J. Wu, et al., J. Mater. Sci. Technol. 74 (2021) 119–127. doi: 10.1016/j.jmst.2020.10.017
30. [30]
  X.X. Ma, X. Shen, X. Chen, et al., Small Struct. 3 (2022) 2200071. doi: 10.1002/sstr.202200071
31. [31]
  P. Shi, F. Liu, Y.Z. Feng, et al., Small Struct. 16 (2020) 2001989.
32. [32]
  T.X. Yang, H.N. Zeng, W.L. Wang, et al., J. Mater. Chem. A 7 (2019) 8292–8301. doi: 10.1039/c9ta01293a
33. [33]
  B. Liao, H.Y. Li, M.Q. Xu, et al., Adv. Energy Mater. 8 (2018) 1800802. doi: 10.1002/aenm.201800802
34. [34]
  H.M. Kim, J.Y. Hwang, D. Aurbach, Y.K. Sun, J. Phys. Chem. Lett. 8 (2017) 5331–5337. doi: 10.1021/acs.jpclett.7b02354
35. [35]
  B.D. Adams, J.M. Zheng, X.D. Ren, W. Xu, J.G. Zhang, Adv. Energy Mater. 8 (2017) 1702097.
36. [36]
  D. N Zhao, J. Wang, H.L. Lu, et al., J. Power Sources 456 (2020) 228006. doi: 10.1016/j.jpowsour.2020.228006
37. [37]
  T. Deng, L.S. Cao, X.Z. He, et al., Chem 7 (2021) 3052–3068. doi: 10.1016/j.chempr.2021.06.019
38. [38]
  S.K. Merso, T.M. Tekaligne, H.H Weldeyohannes, et al., J. Energy Storage 56 (2022) 105955. doi: 10.1016/j.est.2022.105955
39. [39]
  Q.Y. Zhang, J.L. Ma, L. Mei, et al., Matter 5 (2022) 1235–1250. doi: 10.1016/j.matt.2022.01.015
40. [40]
  M. Jiang, K.L. Wang, S. Gao, et al., ChemElectroChem 6 (2018) 1365–1370. doi: 10.1007/978-981-10-6190-5_120
41. [41]
  X.Y. Wang, X.Z. Wei, H.F. Dai, J. Energy Storage 21 (2018) 618–631.
42. [42]
  L. Wang, X.M. He, J.J. Li, et al., Electrochim. Acta 72 (2012) 114–119. doi: 10.1016/j.electacta.2012.04.005
43. [43]
  F. Jin, C.J. Hu, C.H. Liu, et al., J. Electroanal. Chem. 835 (2019) 156–160. doi: 10.1016/j.jelechem.2019.01.032
44. [44]
  F.J. Lin, J.L. Wang, H. Jia, et al., J. Power Sources 223 (2013) 18–22. doi: 10.1016/j.jpowsour.2012.09.021
45. [45]
  Y. Shuai, Z. Zhang, K. Chen, J. Lou, Y. Wang, Chem. Commun. 55 (2019) 2376–2379. doi: 10.1039/c8cc09372e
46. [46]
  H. Jia, J. Wang, F. Lin, et al., Chem. Commun. 50 (2014) 7011–7013. doi: 10.1039/C4CC01151A
47. [47]
  Y. Liu, D. Yang, W. Yan, et al., iScience 19 (2019) 316–325. doi: 10.1016/j.isci.2019.07.027
48. [48]
  Y. Zhang, Y. Zhao, Z. Bakenov, D. Gosselink, P. Chen, J. Solid State Electrochem. 18 (2014) 1111–1116. doi: 10.1007/s10008-013-2366-y
49. [49]
  J. Wang, F. Lin, H. Jia, et al., Angew. Chem. Int. Ed. 53 (2014) 10099–10104. doi: 10.1002/anie.201405157
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