Citation: Pingping Wang, Huixian Miao, Kechuan Sheng, Bin Wang, Fan Feng, Xuankun Cai, Wei Huang, Dayu Wu. Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs[J]. Chinese Chemical Letters, ;2024, 35(4): 108600. doi: 10.1016/j.cclet.2023.108600 shu

Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs

Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Advanced Catalysis & Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China

whuang@cczu.edu.cn

wudy@cczu.edu.cn

Received Date: 9 April 2023
Revised Date: 15 May 2023
Accepted Date: 22 May 2023
Available Online: 24 May 2023

Figures(5)

The blue-light-excitable phosphors play a crucial role in the high-performance white LEDs. Here, we report on two new Cu(Ⅰ) coordination network materials as yellow-emitting phosphors prepared by suitably expanded π-conjugated triazole ligands. Upon blue-light irradiation, these complexes exhibit efficient solid-state emission and enhanced photostability. Through incorporating the yellow phosphor and a commercial blue-green powder (BaSi₂N₂O₂:Eu²⁺) with a blue LED chip, the phosphor-converted LED devices display remarkable white emission properties. The experimental results demonstrate that the Cu(Ⅰ) coordination network materials function as promising blue-light excitable phosphors with great application potential for full-spectrum white LEDs.
- Metal-organic framework,
- Coordination polymer,
- Photoluminescence,
- Phosphor material,
- White-light LED,
- Phosphor-converted LED
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