Citation: Lan Liang, Chuanbin Wang, Xukai Lu, Yunan Sun, Beibei Yan, Ning Li, Guanyi Chen, Li'an Hou. Interactions of phenol and benzaldehyde in electrocatalytic upgrading process[J]. Chinese Chemical Letters, ;2024, 35(2): 108581. doi: 10.1016/j.cclet.2023.108581 shu

Interactions of phenol and benzaldehyde in electrocatalytic upgrading process

Lan Liang ^a ,
Chuanbin Wang ^a ,
Xukai Lu ^a ,
Yunan Sun ^b ,
Beibei Yan ^a ,
Ning Li ^{a, c, *,} ,
Guanyi Chen ^{b, c, *,} ,
Li'an Hou ^{a, d, *,}

a.
School of Environmental Science and Engineering, Tianjin Key Lab of Biomass/Wastes Utilization, Tianjin University, Tianjin 300350, China
b.
School of Mechanical Engineering, Tianjin University of Commerce, Tianjin 300134, China
c.
Georgia Tech Shenzhen Institute, Tianjin University, Shenzhen 518071, China
d.
High Tech Inst Beijing, Beijing 100085, China

liningec@tju.edu.cn

chen@tju.edu.cn

houla@cae.cn

Received Date: 23 February 2023
Revised Date: 5 May 2023
Accepted Date: 16 May 2023
Available Online: 19 May 2023

Figures(6)

Biomass pyrolysis oil can be improved effectively by electrocatalytic hydrogenation (ECH). However, the unclear interactions among different components lead to low bio-oil upgrading efficiency in the conversion process. Herein, benzaldehyde and phenol, as common compounds in bio-oil, were chosen as model compounds. The interactions between the two components were explored in the ECH process by combining experiments and theoretical calculations. Results showed that phenol could accelerate the conversion of benzaldehyde in the ECH. The selectivity of benzyl alcohol was increased from 60.9% of unadded phenol to 99.1% with 30 mmol/L phenol concentration at 5 h. Benzaldehyde inhibited the ECH of phenol. In the presence of benzaldehyde, the conversion rate of phenol was below 10.0% with no cyclohexanone and cyclohexanol formation at 5 h. The density functional theory (DFT) calculations revealed that the phenol could promote the adsorption of benzaldehyde and facilitate the targeted conversion of benzaldehyde on the active site by lowering the reaction energy barrier. The research on the interaction between phenol and benzaldehyde in the ECH provides a theoretical basis for the application of ECH in practical bio-oil upgrading.
- Interaction,
- Bio-oil,
- Electrocatalytic hydrogenation,
- Phenol,
- Benzaldehyde
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