Citation: Jun Jiang, Tong Guo, Wuxin Bai, Mingliang Liu, Shujun Liu, Zhijie Qi, Jingwen Sun, Shugang Pan, Aleksandr L. Vasiliev, Zhiyuan Ma, Xin Wang, Junwu Zhu, Yongsheng Fu. Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries[J]. Chinese Chemical Letters, ;2024, 35(4): 108565. doi: 10.1016/j.cclet.2023.108565 shu

Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries

Jun Jiang ^a ,
Tong Guo ^a ,
Wuxin Bai ^a ,
Mingliang Liu ^a ,
Shujun Liu ^a ,
Zhijie Qi ^a ,
Jingwen Sun ^a ,
Shugang Pan ^{b, *,} ,
Aleksandr L. Vasiliev ^c ,
Zhiyuan Ma ^{a, d} ,
Xin Wang ^a ,
Junwu Zhu ^{a, *,} ,
Yongsheng Fu ^{a, *,}

a.
Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China
b.
Changzhou Institute of Technology, Changzhou 213032, China
c.
Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow 119333, Russia
d.
Jiangsu Pylon Battery Co., Ltd., Yangzhou 211400, China

pansg@czu.cn

zhujw@njust.edu.cn

fuyongsheng@njust.edu.cn

Received Date: 3 March 2023
Revised Date: 6 May 2023
Accepted Date: 11 May 2023
Available Online: 12 May 2023

Figures(8)

Popularization of lithium-sulfur batteries (LSBs) is still hindered by shuttle effect and volume expansion. Herein, a new modularized sulfur storage strategy is proposed to solve above problems and accomplished via employing 100% space utilization host material of cobalt loaded carbon nanoparticles derived from ZIF-67. The modular dispersed storage of sulfur not only greatly increases the proportion of active sulfur, but also inhibits the occurrence of volume expansion. Meanwhile, 100% space utilization host material can greatly improve the conductivity of the cathode, provide a larger electrolyte wetting interface and effectively suppress the shuttle effect. Moreover, loaded cobalt particles have high catalytic activity for electrochemical reaction and can effectively improve the redox kinetics. The cell with new cathode host material carbonized at 650 ℃ (ZIF-67 (650 ℃)) exhibits superior rate performance and can maintain a high specific capacity of 950 mAh/g after 100 cycles at 0.2 C, showing a good cycle stability.
- Modularized sulfur storage,
- Space utilization,
- Cathode host material,
- ZIF-67,
- Lithium-sulfur batteries
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