Citation: Fengbin Sun, Xudong Yang, Feng Shao, Fan Li, Zhicheng Pan, Lin Qiao, Ziniu Xiao, Wen Liu. In-situ construction of Co(OH)₂ nanoparticles decorated biochar for highly efficient degradation of tetracycline hydrochloride via peracetic acid activation[J]. Chinese Chemical Letters, ;2023, 34(9): 108563. doi: 10.1016/j.cclet.2023.108563 shu

In-situ construction of Co(OH)₂ nanoparticles decorated biochar for highly efficient degradation of tetracycline hydrochloride via peracetic acid activation

Fengbin Sun ^{a, b} ,
Xudong Yang ^c ,
Feng Shao ^d ,
Fan Li ^c ,
Zhicheng Pan ^e ,
Lin Qiao ^{a, *,} ,
Ziniu Xiao ^{b, *,} ,
Wen Liu ^c

a.
Institute of Urban Meteorology, China Meteorological Administration, Beijing 100089, China
b.
State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
c.
The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
d.
College of Landscape Architecture, Zhejiang Agriculture and Forestry University, Hangzhou 311300, China
e.
Water Safety and Water Pollution Control Engineering Technology Research Center in Sichuan Province, Haitian Water Group, Chengdu 610299, China

bjs_qxt@sina.com

xiaozn@lasg.iap.ac.cn

Received Date: 17 January 2023
Revised Date: 11 April 2023
Accepted Date: 9 May 2023
Available Online: 13 May 2023

Figures(4)

Peracetic acid (CH₃C(O)OOH, PAA)-based heterogeneous advanced oxidation process (AOP) has attacked intensive interests due to production of various reactive species. Herein, Co(OH)₂ nanoparticles decorated biochar (Co(OH)₂/BC) was fabricated by a simple and controllable method, which was used to degrade tetracycline hydrochloride (TTCH) in water through PAA activation. The results indicated that 100% TTCH (C₀ = 10 µmol/L) degradation efficiency was realized within 7 min at pH 7, with a high kinetic rate constant (k₁) of 0.64 min⁻¹ by the optimized Co(OH)₂/BC. Material characterizations suggested that Co(OH)₂ nanoparticle was successfully decorated on biochar, leading to more active sites and electronic structure alteration of biochar, thus greatly promoting the catalytic cleavage of PAA for radicals production. Then, the reactive oxygen species (ROS) quenching experiments and electron paramagnetic resonance (EPR) analysis demonstrated the key species were alkoxyl radicals (R–O^•, mainly CH₃CO₂^• and CH₃CO₃^•), HO^• and ¹O₂ in this system. Besides, density functional theory (DFT) calculation on Fukui index further revealed that the vulnerable sites of TTCH and three possible degradation pathways were proposed. This study can provide a new strategy for synthesis functional materials in PAA activation AOPs for removal of antibiotics in water.
- Biochar,
- Peracetic acid (PAA),
- Tetracycline hydrochloride,
- Intermediates,
- DFT calculation
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沈阳化工大学材料科学与工程学院沈阳 110142

In-situ construction of Co(OH)2 nanoparticles decorated biochar for highly efficient degradation of tetracycline hydrochloride via peracetic acid activation

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通讯作者: 陈斌, bchen63@163.com

In-situ construction of Co(OH)₂ nanoparticles decorated biochar for highly efficient degradation of tetracycline hydrochloride via peracetic acid activation