Citation: Hua Liu, Quanquan Li, Penghui Pan, Li Zhou, Bing Deng, Shuya Zhao, Ping Liu, Yaoyu Wang, Jianli Li. Robust chromophore-integrated MOFs as highly visible-white-light active and tunable size-selective photocatalysts towards benzothiazoles[J]. Chinese Chemical Letters, ;2023, 34(10): 108562. doi: 10.1016/j.cclet.2023.108562 shu

Robust chromophore-integrated MOFs as highly visible-white-light active and tunable size-selective photocatalysts towards benzothiazoles

Hua Liu ^{a, 1} ,
Quanquan Li ^{a, b, 1} ,
Penghui Pan ^a ,
Li Zhou ^a ,
Bing Deng ^a ,
Shuya Zhao ^a ,
Ping Liu ^{a, *,} ,
Yaoyu Wang ^a ,
Jianli Li ^{a, *,}

a.
College of Chemistry & Materials Science, Northwest University, Xi’an 710127, China
b.
College of Urban and Environmental Sciences, Northwest University, Xi’an 710127, China

liuping@nwu.edu.cn

lijianli@nwu.edu.cn

Received Date: 13 March 2023
Revised Date: 8 May 2023
Accepted Date: 10 May 2023
Available Online: 13 May 2023

Figures(4)

Visible-light heterogeneous photocatalyst with high activity and selectivity is crucial for the development of organic transformations, but remains a formidable challenge. Herein, a simple and effective strategy was developed to integrate tetrazine moiety, a visible light active unit, into robust metal-organic frameworks (2D MOF-1(M), M = Co, Mn, Zn, and 3D MOF-2(Co)). MOF-1 series are isomorphous 2D porous frameworks, and MOF-2(Co) displays 3D porous framework. Interestingly, benefiting from the oxidative active species of O₂^•−, these MOFs all exhibit obviously highly enhanced photocatalytic activities toward the straightforward condensation of o-aminothiophenol and aromatic aldehydes at room temperature in EtOH under visible-white-light irradiation. Notably, compared to 3D MOF, the 2D layered MOF-1(Co) exhibited more excellent catalytic activity with a wide range of substrates possessing preeminent tolerance of steric hindrance. Most impressively, MOF-1(Co) can be recycled at least five times without significant loss of catalytic activity or crystallinity, exhibiting excellent stability and reusability. This study sheds light on the wide-ranging prospects of visible light active 2D MOFs as green photocatalysts for the preparation of fine chemicals.
- Metal-organic framework,
- Heterogeneous photocatalyst,
- Tetrazine,
- Benzothiazole,
- Substrates selectivity
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