Citation: Ziling Jiang, Shaoqing Chen, Chaochao Wei, Ziqi Zhang, Zhongkai Wu, Qiyue Luo, Liang Ming, Long Zhang, Chuang Yu. Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer[J]. Chinese Chemical Letters, ;2024, 35(4): 108561. doi: 10.1016/j.cclet.2023.108561 shu

Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer

Ziling Jiang ^{a, b} ,
Shaoqing Chen ^c ,
Chaochao Wei ^a ,
Ziqi Zhang ^b ,
Zhongkai Wu ^a ,
Qiyue Luo ^a ,
Liang Ming ^a ,
Long Zhang ^{d, *,} ,
Chuang Yu ^{a, b, *,}

a.
School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
State Key Laboratory of Advanced Electromagnetic Engineering and Technology, School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
c.
Innovation Center for Chemical Sciences, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
d.
College of Physics and Energy, Fujian Normal University, Fuzhou 350117 China

longzhang2023@163.com

cyu2020@hust.edu.cn

Received Date: 17 March 2023
Revised Date: 12 April 2023
Accepted Date: 10 May 2023
Available Online: 13 May 2023

Figures(4)

LiNi_0.8Co_0.15Al_0.05O₂ (NCA) is a promising cathode for sulfide-based solid-state lithium batteries (ASSLBs) profiting from its high specific capacity and voltage plateau, which yielding high energy density. However, the inferior interfacial stability between the bare NCA and sulfides limits its electrochemical performance. Hereien, the dual-electrolyte layer is proposed to mitigate this effect and enhance the battery performances of NCA-based ASSLIBs. The Li₃InCl₆ wih high conductivity and excellent electrochemcial stability act both as an ion additives to promote Li-ion diffusion across the interface in the cathode and as a buffer layer between the cathode layer and the solid electrolyte layer to avoid side reactions and improve the interface stability. The corresponding battery exhibits high discharge capacities and superior cyclabilities at both room and elevated temperatures. It exhibits discharge performance of 237.04 and 216.07 mAh/g at 0.1 and 0.5 C, respectively, when cycled at 60 ℃, and sustains 95.9% of the capacity after 100 cycles at 0.5 C. The work demonstrates a simple strategy to ensure the superior performances of NCA in sulfide-based ASSLBs.
- LiNi_0.8Co_0.15Al_0.05O₂,
- Li_5.5PS_4.5Cl_1.5,
- Double solid electrolyte layer configuration,
- Operating temperatures,
- Electrochemical performances
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Enabling superior electrochemical performance of NCA cathode in Li5.5PS4.5Cl1.5-based solid-state batteries with a dual-electrolyte layer

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通讯作者: 陈斌, bchen63@163.com

Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer