Citation: Yuhang Liu, Zhewen Guo, Yuchen Guo, Guangfeng Li, Shengbing Yang, Xuzhou Yan, Yi Shen, Jinbing Wang. Topological effect on fluorescence emission of tetraphenylethylene-based metallacages[J]. Chinese Chemical Letters, ;2023, 34(12): 108531. doi: 10.1016/j.cclet.2023.108531 shu

Topological effect on fluorescence emission of tetraphenylethylene-based metallacages

Yuhang Liu ^{a, b, 1} ,
Zhewen Guo ^{a, b, 1} ,
Yuchen Guo ^b ,
Guangfeng Li ^b ,
Shengbing Yang ^c ,
Xuzhou Yan ^{b, *,} ,
Yi Shen ^{a, *,} ,
Jinbing Wang ^{a, *,}

a.
Department of Oral and Maxillofacial-Head and Neck Oncology, Shanghai Ninth People's Hospital, Shanghai Jiao Tong University School of Medicine, College of Stomatology, National Center for Stomatology, National Clinical Research Center for Oral Diseases, Shanghai Key Laboratory of Stomatology, Shanghai Jiao Tong University, Shanghai Research Institute of Stomatology, Shanghai 200011, China
b.
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai 200240, China
c.
Shanghai Key Laboratory of Orthopaedic Implants, Department of Orthopaedic Surgery, Shanghai Ninth People's Hospital, Shanghai Jiao Tong University School of Medicine, Shanghai 200125, China

^☆

xzyan@sjtu.edu.cn

SHENYI1866@sh9hospital.org.cn

118030@sh9hospital.org.cn

Received Date: 18 December 2022
Revised Date: 23 April 2023
Accepted Date: 27 April 2023
Available Online: 30 April 2023

Figures(5)

Herein, we describe the selective formation of a barrel-shaped or a ball-shaped fluorescent metallacage by controlling the shape and stoichiometry of the building blocks. Specifically, the tetraphenylethylene-based donor and two acceptors with different numbers of Pt(Ⅱ) centers were combined via coordination-driven self-assembly. Owing to the differences in the shapes of the assemblies, the resultant ball-shaped metallacage displayed stronger and blue-shifted fluorescence compared to the barrel-shaped one in dilute solutions, while a reversal of fluorescence intensities was observed in the aggregation process. Overall, this work demonstrates that the photophysical properties of supramolecular coordination complexes can be affected by subtle geometrical factors, which can be controlled precisely at the molecular level.
- Topological effect,
- Photophysical properties,
- Aggregation-induced emission,
- Coordination-driven self-assembly,
- Supramolecular metallacages
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