Citation: Qianqian Huang, Rui Wang, Xiya Li, Tianfu Liu, A. R. Mahammed Shaheer, Rong Cao. The effects of local environment towards yield and selectivity on photocatalytic CO₂ reduction catalyzed by metal-organic framework[J]. Chinese Chemical Letters, ;2023, 34(12): 108517. doi: 10.1016/j.cclet.2023.108517 shu

The effects of local environment towards yield and selectivity on photocatalytic CO₂ reduction catalyzed by metal-organic framework

Qianqian Huang ^{a, b} ,
Rui Wang ^a ,
Xiya Li ^a ,
Tianfu Liu ^{a, b, c} ,
A. R. Mahammed Shaheer ^{a, *,} ,
Rong Cao ^{a, b, c, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Fujian Science Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

asmshaheer@fjirsm.ac.cn

rcao@fjirsm.ac.cn

Received Date: 6 March 2023
Revised Date: 20 April 2023
Accepted Date: 26 April 2023
Available Online: 4 May 2023

Figures(6)

The CO₂ photoconversion is sensitive to the local reaction environment, of which activity and selectivity can be regulated by the change of reaction systems. This paper focuses on investigating the photocatalytic CO₂ reduction behaviors of MOFs with the involvement of water under different reaction modes, including gas-solid and liquid-solid systems. The CO₂ photoreduction in a liquid-solid system shows high performance in generating HCOOH with the selectivity of 100%. In contrast, the gas-solid system referring to the synergistic interaction of MOFs and H₂O vapor benefits to the formation of gas-phase products, such as CO and CH₄. The possible mechanisms of photocatalytic CO₂ reaction in two modes were investigated by in-situ Fourier-transform infrared spectroscopy, which indicates that the distinction in reaction consequence may result from the difference in CO₂ chemisorbed modes and the proton provision. The choice of reaction system plays an important role in the achievement of high efficiency and selectivity for photocatalytic CO₂ reduction, which is of great practical value in real-world applications.
- Photocatalysis,
- CO₂,
- Reaction mode,
- Yield,
- Selectivity
1. [1]
  R. Li, W. Zhang, K. Zhou, Adv. Mater. 30 (2018) 1705512. doi: 10.1002/adma.201705512
2. [2]
  H.B. Huang, Z.B. Fang, R. Wang, et al., Small 18 (2022) 2200407. doi: 10.1002/smll.202200407
3. [3]
  J.H. Zhang, Y.C. Wang, H.J. Wang, D.C. Zhong, T.B. Lu, Chin. Chem. Lett. 33 (2022) 2065–2068. doi: 10.1016/j.cclet.2021.09.035
4. [4]
  A.A. Zhang, D.H. Si, H.B. Huang, et al., Angew. Chem. Int. Ed. 61 (2022) 202203955. doi: 10.1002/anie.202203955
5. [5]
  L.S. Chen, Q.Q. Tang, S.H. Wu, et al., Chin. Chem. Lett. 34 (2023) 107903. doi: 10.1016/j.cclet.2022.107903
6. [6]
  A.A. Zhang, R. Wang, H.B. Huang, T.F. Liu, R. Cao, Chin. Chem. Lett. 34 (2023) 107311. doi: 10.1016/j.cclet.2022.03.034
7. [7]
  P.Y. Kuang, Z.R. Ni, J.G. Yu, J.X. Low, Mater. Rep. Energy 2 (2022) 100081.
8. [8]
  S.S. Fu, S. Yao, S. Guo, et al., J. Am. Chem. Soc. 143 (2021) 20792–20801. doi: 10.1021/jacs.1c08908
9. [9]
  Y. Ma, X.L. Wang, Y.S. Jia, et al., Chem. Rev. 114 (2014) 9987–10043. doi: 10.1021/cr500008u
10. [10]
  W.J. Shen, Y.D. Dong, F.Z. Huang, Y.B. Cheng, J. Zhong, Mater. Rep. Energy 1 (2021) 10060.
11. [11]
  Q.Q. Huang, Z.B. Fang, K. Pang, et al., Adv. Funct. Mater. 32 (2022) 2205147. doi: 10.1002/adfm.202205147
12. [12]
  L. Li, Z.B. Fang, W.Z. Deng, et al., CCS Chem. 4 (2022) 2782–2792. doi: 10.31635/ccschem.021.202101241
13. [13]
  X.J. Hu, Z.X. Li, H. Xue, et al., CCS Chem. 2 (2020) 616–622. doi: 10.31635/ccschem.019.201900040
14. [14]
  Q.Q. Huang, Y. Hu, Y. Pei, J.H. Zhang, M.L. Fu, Appl. Catal. B 259 (2019) 118106. doi: 10.1016/j.apcatb.2019.118106
15. [15]
  L.Y. Chen, Q.L. Liu, J. Yang, Y.L. Li, G.Q. Li, Chin. Chem. Lett. 34 (2023) 107335. doi: 10.1016/j.cclet.2022.03.058
16. [16]
  S. Guo, L.H. Kong, P. Wang, et al., Angew. Chem. Int. Ed. 61 (2022) 202206193. doi: 10.1002/anie.202206193
17. [17]
  T. Luo, J. Zhang, W. Li, et al., ACS Appl. Mater. Interfaces 9 (2017) 41594–41598. doi: 10.1021/acsami.7b13900
18. [18]
  Z.B. Fang, T.T. Liu, J.X. Liu, et al., J. Am. Chem. Soc. 142 (2020) 12515–12523. doi: 10.1021/jacs.0c05530
19. [19]
  D. Li, M. Kassymova, X. Cai, S.Q. Zang, H.L. Jiang, Coord. Chem. Rev. 412 (2020) 213262. doi: 10.1016/j.ccr.2020.213262
20. [20]
  T.C. Zhuo, Y. Song, G.L. Zhuang, et al., J. Am. Chem. Soc. 143 (2021) 6114–6122. doi: 10.1021/jacs.0c13048
21. [21]
  J.W. Wang, L.Z. Qiao, H.D. Nie, et al., Nat. Commun. 12 (2021) 813. doi: 10.1038/s41467-021-21084-9
22. [22]
  H.W. Chang, Y.N. Zhou, S.Y. Zhang, X.L. Zheng, Q. Xu, Adv. Mater. Interfaces 8 (2021) 2100205. doi: 10.1002/admi.202100205
23. [23]
  Y. Wang, N.Y. Huang, J.Q. Shen, et al., J. Am. Chem. Soc. 140 (2018) 38–41. doi: 10.1021/jacs.7b10107
24. [24]
  Y.H. Fu, D.R. Sun, Y.J. Chen, et al., Angew. Chem. Int. Ed. 51 (2012) 3364–3367. doi: 10.1002/anie.201108357
25. [25]
  P. Horcajada, S. Surble, C. Serre, et al., Chem. Commun. 27 (2007) 2820–2822.
26. [26]
  X.Y. Dao, J.H. Guo, X.Y. Zhang, et al., J. Mater. Chem. A 8 (2020) 25850–25856. doi: 10.1039/d0ta10278d
27. [27]
  X.Y. Zhang, P. Wang, Y. Zhang, X.M. Cheng, W.Y. Sun, ACS Appl. Mater. Interfaces 15 (2023) 3348–3356. doi: 10.1021/acsami.2c19236
28. [28]
  J.T. Feaster, C. Shi, E.R. Cave, et al., ACS Catal. 7 (2017) 4822–4827. doi: 10.1021/acscatal.7b00687
29. [29]
  S. Kattel, B.H. Yan, Y.X. Yang, J.G. Chen, P. Liu, J. Am. Chem. Soc. 138 (2016) 12440–12450. doi: 10.1021/jacs.6b05791
30. [30]
  M.Y. He, J.M. White, J. Mol. Catal. 30 (1985) 415–430. doi: 10.1016/0304-5102(85)85051-3
31. [31]
  T. Yan, P. Wang, W.Y. Sun, Small 19 (2023) 2206070. doi: 10.1002/smll.202206070
32. [32]
  F. Guo, R.X. Li, S. Yang, et al., Angew. Chem. Int. Ed. 62 (2023) 202216232. doi: 10.1002/anie.202216232
33. [33]
  J.C. Zhu, W.W. Shao, X.D. Li, et al., J. Am. Chem. Soc. 143 (2021) 18233–18241. doi: 10.1021/jacs.1c08033
34. [34]
  Y. Zhang, X.Y. Zhang, W.Y. Sun, ACS Catal. 13 (2023) 1553–15445. doi: 10.3390/e25111553
35. [35]
  C. Du, X. Wang, W. Chen, et al., Mater. Today Adv. 6 (2020) 100071. doi: 10.1016/j.mtadv.2020.100071
36. [36]
  M. Bhattacharya, S. Sebghati, R.T. VanderLinden, C.T. Saouma, J. Am. Chem. Soc. 142 (2020) 17589–17597. doi: 10.1021/jacs.0c07763
37. [37]
  S. Dey, F. Masero, E. Brack, M. Fontecave, V. Mougel, Nature 607 (2022) 499–506. doi: 10.1038/s41586-022-04874-z
38. [38]
  M.H. Ronne, D. Cho, M.R. Madsen, et al., J. Am. Chem. Soc. 142 (2020) 4265–4275. doi: 10.1021/jacs.9b11806
39. [39]
  N.D. Loewen, E.J. Thompson, M. Kagan, et al., Chem. Sci. 7 (2016) 2728–2735. doi: 10.1039/C5SC03169A
40. [40]
  E.E. Benson, C.P. Kubiak, A.J. Sathrum, J.M. Smieja, Chem. Soc. Rev. 38 (2009) 89–99. doi: 10.1039/B804323J
41. [41]
  N.D. Loewen, T.V. Neelakantan, L.A. Berben, Acc. Chem. Res. 50 (2017) 2362–2370. doi: 10.1021/acs.accounts.7b00302
42. [42]
  M.D. Rail, L.A. Berben, J. Am. Chem. Soc. 133 (2011) 18577–18579. doi: 10.1021/ja208312t
43. [43]
  C. Costentin, M. Robert, J.M. Saveant, Chem. Soc. Rev. 42 (2013) 2423–2436. doi: 10.1039/C2CS35360A
44. [44]
  P. Kang, C. Cheng, Z. Chen, T.J. Meyer, J. Am. Chem. Soc. 134 (2012) 5500–5503. doi: 10.1021/ja300543s
45. [45]
  T.J. Schmeier, G.E. Dobereiner, R.H. Crabtree, N. Hazari, J. Am. Chem. Soc. 133 (2011) 9274–9277. doi: 10.1021/ja2035514
46. [46]
  S.E. Lee, A. Nasirian, Y.E. Kim, et al., J. Am. Chem. Soc. 142 (2020) 19142–19149. doi: 10.1021/jacs.0c08145
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The effects of local environment towards yield and selectivity on photocatalytic CO2 reduction catalyzed by metal-organic framework

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通讯作者: 陈斌, bchen63@163.com

The effects of local environment towards yield and selectivity on photocatalytic CO₂ reduction catalyzed by metal-organic framework