Citation: Yue Gao, Yu Du, Weiping Su. Free amino group-directed C(sp²)–H arylation of α-amino-β-aryl esters by palladium catalysis[J]. Chinese Chemical Letters, ;2024, 35(2): 108505. doi: 10.1016/j.cclet.2023.108505 shu

Free amino group-directed C(sp²)–H arylation of α-amino-β-aryl esters by palladium catalysis

Yue Gao ^{a, b, c} ,
Yu Du ^{a, b, c, *,} ,
Weiping Su ^{a, b, c, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

duyu@fjirsm.ac.cn

wpsu@fjirsm.ac.cn

Received Date: 23 November 2022
Revised Date: 13 April 2023
Accepted Date: 23 April 2023
Available Online: 27 April 2023

Figures(4)

Native amino-directed palladium-catalyzed C(sp³)–H activation/functionalization has been developed for modification of α-amino acids and peptides. Herein a palladium(Ⅱ)-catalyzed C(sp²)–H arylation of α-amino-β-aryl esters has been disclosed, using the native amino as the directing group. A variety of chiral α-amino-β-aryl esters can be functionalized to give the corresponding ortho-substituted mono- and di-arylated products.
- Native amino-directed,
- Palladium catalyst,
- C(sp²)-H arylation,
- α-Amino-β-aryl ester,
- Chiral α-amino acid
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Free amino group-directed C(sp2)–H arylation of α-amino-β-aryl esters by palladium catalysis

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通讯作者: 陈斌, bchen63@163.com

Free amino group-directed C(sp²)–H arylation of α-amino-β-aryl esters by palladium catalysis