Citation: Jixuan Zhang, Pengfei Tian, Aihao Xu, Like Ouyang, Zixu Yang, Jing Xu. Manipulation of the PdAu‒PdAuO_x interface on Pd-Au bimetallic catalysts for the direct synthesis of hydrogen peroxide[J]. Chinese Chemical Letters, ;2023, 34(11): 108446. doi: 10.1016/j.cclet.2023.108446 shu

Manipulation of the PdAu‒PdAuO_x interface on Pd-Au bimetallic catalysts for the direct synthesis of hydrogen peroxide

Jixuan Zhang ^a ,
Pengfei Tian ^b ,
Aihao Xu ^c ,
Like Ouyang ^d ,
Zixu Yang ^{a, *,} ,
Jing Xu ^{a, c, *,}

a.
State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Key Laboratory of Pressure Systems and Safety, Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
c.
Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
d.
College of Chemical Engineering, Sichuan University, Chengdu 610065, China

zixu.yang@ecust.edu.cn

xujing@ecust.edu.cn

Received Date: 27 January 2023
Revised Date: 9 April 2023
Accepted Date: 11 April 2023
Available Online: 13 April 2023

Figures(5)

Direct synthesis of H₂O₂ from H₂ and O₂ via heterogeneous catalysis is an environmentally friendly and atomically economic alternative to the traditional anthraquinone oxidation (AO) process. Optimizing the electronic and geometric structures of the active metals to break the current limitations of hydrogenation rate and H₂O₂ selectivity is a promising and challenging topic. In this study, a series of Pd-Au bimetallic catalysts supported on TiO₂ with a metal loading of 3.0 wt% and a constant Pd/Au molar ratio (Pd:Au = 2:1) were prepared. The catalysts were reduced in H₂ at different temperatures (473, 573 and 673 K), and their catalytic activity for the direct H₂O₂ synthesis were evaluated at 283 K and 0.1 MPa. H₂ reduced Pd-Au catalysts exhibited superior performance in direct H₂O₂ synthesis. The maximum H₂O₂ selectivity of 87.7% and H₂O₂ yield of 3116.4 mmol h⁻¹ g_Pd⁻¹ were achieved over the Pd_2.0Au_1.0-573 catalyst with a H₂ conversion of 12.8%. The tailored local chemical environment caused by H₂ reduction creates a balanced ratio of Pd⁰ and PdO_x sites, thus improving the selectivity towards H₂O₂. This work developed an effective strategy for fabrication of highly active and stable Pd-based H₂O₂ synthesis catalysts with high H₂O₂ yield.
- H₂O₂ synthesis,
- Bimetallic catalysts,
- Palladium particle size,
- Pd⁰/Pd²⁺ ratio,
- Structure-performance relationship
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沈阳化工大学材料科学与工程学院沈阳 110142

Manipulation of the PdAu‒PdAuOx interface on Pd-Au bimetallic catalysts for the direct synthesis of hydrogen peroxide

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通讯作者: 陈斌, bchen63@163.com

Manipulation of the PdAu‒PdAuO_x interface on Pd-Au bimetallic catalysts for the direct synthesis of hydrogen peroxide