Citation: Giday Fisseha, Yiping Hu, Yanan Yu, Shaojie Lu, Dongsheng Ma, Pei Nian, Zheng Wang, Qin Yue. Ultrathin ternary PtNiGa nanowires for enhanced oxygen reduction reaction[J]. Chinese Chemical Letters, ;2024, 35(2): 108445. doi: 10.1016/j.cclet.2023.108445 shu

Ultrathin ternary PtNiGa nanowires for enhanced oxygen reduction reaction

Giday Fisseha ^a ,
Yiping Hu ^{a, *,} ,
Yanan Yu ^a ,
Shaojie Lu ^a ,
Dongsheng Ma ^a ,
Pei Nian ^b ,
Zheng Wang ^b ,
Qin Yue ^{a, *,}

a.
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
b.
State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China

yipinghu@uestc.edu.cn

qinyue@uestc.edu.cn

Received Date: 19 January 2023
Revised Date: 11 March 2023
Accepted Date: 12 April 2023
Available Online: 13 April 2023

Figures(4)

Achieving high activity and durability for the oxygen reduction reaction (ORR) with an ultra-low amount of platinum is significant to promote the widespread application of proton exchange membrane fuel cells (PEMFCs). Here we report a new ultrathin (~1 nm) ternary PtNiGa alloy nanowires (PtNiGa NWs) electrocatalyst, in which the presence of gallium (Ga) enhances the oxidation resistance of platinum (Pt) and nickel (Ni) and suppresses the dissolution of Ni. The mass and specific activities of PtNiGa NWs are about 11.2 and 7.6 times higher than those of commercial Pt/C catalysts for ORR. Moreover, the mass activity of PtNiGa/C NWs nanocatalyst decreased only by 12.8% and largely retained its electrochemical surface area (ECSA) after 10,000 potential cycles, compared with 38% loss of ECSA for commercial Pt/C catalyst. Therefore, this work provides a general guideline for preparing ternary alloy electrocatalysts and enhancing the activity and stability of the cathode ORR reaction of PEMFCs.
- Ultrathin nanowires,
- Gallium,
- Oxygen reduction reaction,
- Ternary alloy,
- Durability
1. [1]
  D. Feng, Y. Dong, P. Nie, L. Zhang, Z.A. Qiao, Chem. Eng. J. 430 (2022) 132883. doi: 10.1016/j.cej.2021.132883
2. [2]
  Y. Song, Y. Peng, S. Yao, et al., Chin. Chem. Lett. 33 (2022) 1047–1050. doi: 10.1016/j.cclet.2021.08.045
3. [3]
  F. Guo, M. Zhang, S. Yi, et al., Nano Res. Energy 1 (2022) 9120027. doi: 10.26599/NRE.2022.9120027
4. [4]
  H. Jin, S. Zou, Q. Wen, et al., Chin. Chem. Lett. 34 (2023) 107441. doi: 10.1016/j.cclet.2022.04.039
5. [5]
  K. Wang, N. Li, Y. Yang, et al., Chin. Chem. Lett. 32 (2021) 3159–3163. doi: 10.1016/j.cclet.2021.02.045
6. [6]
  L. Zhao, J. Zhu, Y. Zheng, et al., Adv. Energy Mater. 12 (2022) 2102665. doi: 10.1002/aenm.202102665
7. [7]
  H. Xu, H. Shang, C. Wang, Y. Du, Adv. Funct. Mater. 30 (2020) 2006317. doi: 10.1002/adfm.202006317
8. [8]
  R. Chen, T. Shu, F. Zhao, et al., Nano Res. 15 (2022) 9010–9018. doi: 10.1007/s12274-022-4577-y
9. [9]
  C. Chen, Y. Kang, Z. Huo, et al., Science 343 (2014) 1339–1343. doi: 10.1126/science.1249061
10. [10]
  S.M. Dull, O. Vinogradova, et al., ACS Appl. Energy Mater. 5 (2022) 8282–8291. doi: 10.1021/acsaem.2c00816
11. [11]
  K. Li, X. Li, H. Huang, et al., J. Am. Chem. Soc. 140 (2018) 16159–16167. doi: 10.1021/jacs.8b08836
12. [12]
  G. Nie, Z. Zhang, T. Wang, C. Wang, Z. Kou, ACS Appl. Mater. Interfaces 13 (2021) 37961–37978. doi: 10.1021/acsami.1c08798
13. [13]
  L. Chong, J. Wen, J. Kubal, et al., Science 362 (2018) 1276–1281. doi: 10.1126/science.aau0630
14. [14]
  V.R. Stamenkovic, B.S. Mun, M. Arenz, et al., Nat. Mater. 6 (2007) 241–247. doi: 10.1038/nmat1840
15. [15]
  T.H. Yang, J. Ahn, S. Shi, et al., Chem. Rev. 121 (2021) 796–833. doi: 10.1021/acs.chemrev.0c00940
16. [16]
  Z. Yang, L. Shang, X. Xiong, et al., Chem. Eur. J. 26 (2020) 4090–4096. doi: 10.1002/chem.201904208
17. [17]
  X. Huang, Z. Zhao, L. Cao, et al., Science 348 (2015) 1230–1234. doi: 10.1126/science.aaa8765
18. [18]
  M. Escudero-Escribano, P. Malacrida, M.H. Hansen, et al., Science 352 (2016) 73–76. doi: 10.1126/science.aad8892
19. [19]
  X. Wang, L. Figueroa-Cosme, X. Yang, et al., Nano Lett. 16 (2016) 1467–1471. doi: 10.1021/acs.nanolett.5b05140
20. [20]
  F. Kong, Z. Ren, M.N. Banis, et al., ACS Catal. 10 (2020) 4205–4214. doi: 10.1021/acscatal.9b05133
21. [21]
  M. Li, F. Tian, T. Lin, et al., Small Methods 5 (2021) 2100154. doi: 10.1002/smtd.202100154
22. [22]
  C. Wang, M. Chi, D. Li, et al., J. Am. Chem. Soc. 133 (2011) 14396–14403. doi: 10.1021/ja2047655
23. [23]
  H. Huang, K. Li, Z. Chen, et al., J. Am. Chem. Soc. 139 (2017) 8152–8159. doi: 10.1021/jacs.7b01036
24. [24]
  H. Zhu, S. Zhang, S. Guo, D. Su, S. Sun, J. Am. Chem. Soc. 135 (2013) 7130–7133. doi: 10.1021/ja403041g
25. [25]
  W. Zhang, Y. Yang, B. Huang, F. Lv, et al., Adv. Mater. 31 (2019) 1805833. doi: 10.1002/adma.201805833
26. [26]
  Z. Yao, Y. Yuan, T. Cheng, et al., Nano Lett. 21 (2021) 9354–9360. doi: 10.1021/acs.nanolett.1c03805
27. [27]
  L. Sahoo, R. Garg, K. Kaur, C.P. Vinod, U.K. Gautam, Nano Lett. 22 (2022) 246–254. doi: 10.1021/acs.nanolett.1c03704
28. [28]
  L. Gao, X. Li, Z. Yao, et al., J. Am. Chem. Soc. 141 (2019) 18083–18090. doi: 10.1021/jacs.9b07238
29. [29]
  Y. Li, F. Quan, L. Chen, et al., RSC Adv. 4 (2014) 1895–1899. doi: 10.1039/C3RA46299D
30. [30]
  J. Lim, H. Shin, M. Kim, et al., Nano Lett. 18 (2018) 2450–2458. doi: 10.1021/acs.nanolett.8b00028
31. [31]
  Y. Yu, F. Xia, C. Wang, et al., Nano Res. 15 (2022) 7868–7876. doi: 10.1007/s12274-022-4432-1
32. [32]
  R. Shen, X. Wu, X. Li, et al., ChemistrySelect 6 (2021) 3891–3896. doi: 10.1002/slct.202101015
33. [33]
  A. Zhang, Y. Liang, H. Zhang, Z. Geng, J. Zeng, Chem. Soc. Rev. 50 (2021) 9817–9844. doi: 10.1039/D1CS00330E
34. [34]
  X.X. Wang, S. Hwang, Y.T. Pan, et al., Nano Lett. 18 (2018) 4163–4171. doi: 10.1021/acs.nanolett.8b00978
35. [35]
  Y. Yan, J.S. Du, K.D. Gilroy, et al., Adv. Mater. 29 (2017) 1605997. doi: 10.1002/adma.201605997
36. [36]
  V.B. Kumar, J. Sanetuntikul, P. Ganesan, et al., Electrochim. Acta 190 (2016) 659–667. doi: 10.1016/j.electacta.2015.12.193
37. [37]
  J. Lim, C. Jung, D. Hong, et al., J. Mater. Chem. A 10 (2022) 7399–7408. doi: 10.1039/D2TA00127F
38. [38]
  H.Y. Kim, T. Kwon, Y. Ha, et al., Nano Lett. 20 (2020) 7413–7421. doi: 10.1021/acs.nanolett.0c02812
39. [39]
  H. Ma, Z. Zheng, H. Zhao, et al., J. Mater. Chem. A 9 (2021) 23444–23450. doi: 10.1039/D1TA07488A
40. [40]
  P. Weber, D.J. Weber, C. Dosche, M. Oezaslan, ACS Catal. 12 (2022) 6394–6408. doi: 10.1021/acscatal.2c00514
41. [41]
  D. Liu, N. Yang, Q. Zeng, et al., Chin. Chem. Lett. 32 (2021) 3288–3297. doi: 10.1016/j.cclet.2021.04.053
42. [42]
  J. Guan, S. Yang, T. Liu, et al., Angew. Chem. Int. Ed. 60 (2021) 21899–21904. doi: 10.1002/anie.202107437
43. [43]
  Q. Shao, K. Lu, X. Huang, Small Methods 3 (2019) 1800545. doi: 10.1002/smtd.201800545
44. [44]
  Z. Yang, H. Yang, L. Shang, T. Zhang, Angew. Chem. Int. Ed. 61 (2022) e202113278. doi: 10.1002/anie.202113278
45. [45]
  B. Fang, X. Chu, X. Han, et al., Chem. Commun. 58 (2022) 13803–13806. doi: 10.1039/D2CC05503A
46. [46]
  D.A. Torelli, S.A. Francis, J.C. Crompton, et al., ACS Catal. 6 (2016) 2100–2104. doi: 10.1021/acscatal.5b02888
1. [1]
  Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li . Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization. Chinese Journal of Structural Chemistry, 2023, 42(11): 100021-100021. doi: 10.1016/j.cjsc.2023.100021
2. [2]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
3. [3]
  Shaojie Ding , Henan Wang , Xiaojing Dai , Yuru Lv , Xinxin Niu , Ruilian Yin , Fangfang Wu , Wenhui Shi , Wenxian Liu , Xiehong Cao . Mn-modulated Co–N–C oxygen electrocatalysts for robust and temperature-adaptative zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100302-100302. doi: 10.1016/j.cjsc.2024.100302
4. [4]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
5. [5]
  Kunsong Hu , Yulong Zhang , Jiayi Zhu , Jinhua Mai , Gang Liu , Manoj Krishna Sugumar , Xinhua Liu , Feng Zhan , Rui Tan . Nano-engineered catalysts for high-performance oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(10): 109423-. doi: 10.1016/j.cclet.2023.109423
6. [6]
  Jialin Cai , Yizhe Chen , Ruiwen Zhang , Cheng Yuan , Zeyu Jin , Yongting Chen , Shiming Zhang , Jiujun Zhang . Interfacial Pt-N coordination for promoting oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(2): 110255-. doi: 10.1016/j.cclet.2024.110255
7. [7]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
8. [8]
  Jin Long , Xingqun Zheng , Bin Wang , Chenzhong Wu , Qingmei Wang , Lishan Peng . Improving the electrocatalytic performances of Pt-based catalysts for oxygen reduction reaction via strong interactions with single-CoN₄-rich carbon support. Chinese Chemical Letters, 2024, 35(5): 109354-. doi: 10.1016/j.cclet.2023.109354
9. [9]
  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
10. [10]
  Yixuan Wang , Jiexin Li , Zhihao Shang , Chengcheng Feng , Jianmin Gu , Maosheng Ye , Ran Zhao , Danna Liu , Jingxin Meng , Shutao Wang . Wettability-driven synergistic resistance of scale and oil on robust superamphiphobic coating. Chinese Chemical Letters, 2024, 35(7): 109623-. doi: 10.1016/j.cclet.2024.109623
11. [11]
  Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang . Elucidating oxygen evolution and reduction mechanisms in nitrogen-doped carbon-based photocatalysts. Chinese Chemical Letters, 2025, 36(2): 110439-. doi: 10.1016/j.cclet.2024.110439
12. [12]
  Yanan Zhou , Li Sheng , Lanlan Chen , Wenhua Zhang , Jinlong Yang . Axial coordinated iron-nitrogen-carbon as efficient electrocatalysts for hydrogen evolution and oxygen redox reactions. Chinese Chemical Letters, 2025, 36(1): 109588-. doi: 10.1016/j.cclet.2024.109588
13. [13]
  Yaxin Sun , Huiyu Li , Shiquan Guo , Congju Li . Metal-based cathode catalysts for electrocatalytic ORR in microbial fuel cells: A review. Chinese Chemical Letters, 2024, 35(5): 109418-. doi: 10.1016/j.cclet.2023.109418
14. [14]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
15. [15]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
16. [16]
  Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt₃M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188
17. [17]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
18. [18]
  Jiaqi Lin , Pupu Yang , Yimin Jiang , Shiqian Du , Dongcai Zhang , Gen Huang , Jinbo Wang , Jun Wang , Qie Liu , Miaoyu Li , Yujie Wu , Peng Long , Yangyang Zhou , Li Tao , Shuangyin Wang . Surface decoration prompting the decontamination of active sites in high-temperature proton exchange membrane fuel cells. Chinese Chemical Letters, 2024, 35(11): 109435-. doi: 10.1016/j.cclet.2023.109435
19. [19]
  Liyong Ding , Zhenhua Pan , Qian Wang . 2D photocatalysts for hydrogen peroxide synthesis. Chinese Chemical Letters, 2024, 35(12): 110125-. doi: 10.1016/j.cclet.2024.110125
20. [20]
  Wenbiao Zhang , Bolong Yang , Zhonghua Xiang . Atomically dispersed Cu-based metal-organic framework directly for alkaline polymer electrolyte fuel cells. Chinese Chemical Letters, 2025, 36(2): 109630-. doi: 10.1016/j.cclet.2024.109630

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(309)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142