Citation: Yanchao Jin, Suixiaochen Chen, Peiwen Huang, Xiongjian Chen, Chun-Yan Lin, Li-Ping Li, Xiao Chen, Rui Ding, Jianxi Liu, Riyao Chen. Efficient water disinfection with ball milled Mg-biochar: The key role of trace Cu[J]. Chinese Chemical Letters, ;2024, 35(1): 108444. doi: 10.1016/j.cclet.2023.108444 shu

Efficient water disinfection with ball milled Mg-biochar: The key role of trace Cu

Yanchao Jin ^{a, d} ,
Suixiaochen Chen ^{a, d} ,
Peiwen Huang ^{a, d} ,
Xiongjian Chen ^{a, d, *,} ,
Chun-Yan Lin ^{b, d} ,
Li-Ping Li ^c ,
Xiao Chen ^{a, d} ,
Rui Ding ^{a, d} ,
Jianxi Liu ^{a, d} ,
Riyao Chen ^{a, d, *,}

a.
College of Environmental and Resource Sciences, Fujian Normal University, Fuzhou 350117, China
b.
School of Materials and Chemical Engineering, Minjiang University, Fuzhou 350108, China
c.
Research and Development Center for Watershed Environmental Eco-Engineering, Beijing Normal University, Zhuhai 519087, China
d.
Fujian Key Laboratory of Pollution Control & Resource Reuse, Fuzhou 350007, China

xiongjian_chen2022@163.com

rychen409@sina.com

Received Date: 22 December 2022
Revised Date: 20 March 2023
Accepted Date: 10 April 2023
Available Online: 12 April 2023

Figures(6)

In this study, magnesium and coconut shell carbon (CSC) were prepared by a ball milled process and used for water disinfection with adsorbing tiny amounts of copper(Ⅱ). Dissolved oxygen (DO) was reduced to hydrogen peroxide (H₂O₂) via a two-electron pathway by Mg corrosion. Cu(Ⅱ) in the wastewater will be enriched on the CSC surface and efficiently catalyzes H₂O₂ for inactivating E. coli. The results show that E. coli with an initial concentration of approximately 10⁶ CFU/mL was under the detection limit (< 4 CFU/mL) within 15 min. All of the Cu(Ⅱ) could be adsorbed by the composite and catalyzed H₂O₂ to different active species. The quenching experiments, electron spin resonance (ESR) capture measurements and the UV-vis spectroscopy detection confirmed the present of the hydroxyl radicals (^•OH), superoxide radicals (^•O₂⁻) and Cu(Ⅲ). Different with tradition Fenton like process, Cu(Ⅲ), rather than radicals, played the major role during the Mg-CSC/Cu(Ⅱ) process. In addition to the cellular membrane damage, most of the bacterial genomic DNA was also be degraded and the bacterial reactivation was avoided. The Mg-CSC/Cu(Ⅱ) process also showed a satisfied disinfection performance in real wastewater treatment. Overall, this study provides a new strategy for water disinfection.
- Disinfection,
- Magnesium,
- Cu,
- Hydrogen peroxide,
- Biochar
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