Citation: Taoyuan Xiu, Simei Zhang, Peng Ren, Siyan Liu, Shuai Wang, Hamza Shehzad, Jingyang Wang, Meng Zhang, Guoan Ye, Caishan Jiao, Qunyan Wu, Liyong Yuan, Zhifang Chai, Weiqun Shi. Efficacious selective separation of U(Ⅵ) over Mo(Ⅵ) using novel 2,9-diamide-1,10-phenanthroline ligands: Liquid-liquid extraction and coordination chemistry[J]. Chinese Chemical Letters, ;2023, 34(11): 108440. doi: 10.1016/j.cclet.2023.108440 shu

Efficacious selective separation of U(Ⅵ) over Mo(Ⅵ) using novel 2,9-diamide-1,10-phenanthroline ligands: Liquid-liquid extraction and coordination chemistry

Taoyuan Xiu ^{a, b, c} ,
Simei Zhang ^{b, d} ,
Peng Ren ^{b, d} ,
Siyan Liu ^b ,
Shuai Wang ^b ,
Hamza Shehzad ^e ,
Jingyang Wang ^{a, b} ,
Meng Zhang ^a ,
Guoan Ye ^{a, c, *,} ,
Caishan Jiao ^{a, *,} ,
Qunyan Wu ^b ,
Liyong Yuan ^{b, *,} ,
Zhifang Chai ^b ,
Weiqun Shi ^{b, *,}

a.
College of Nuclear Science and Technology, Harbin Engineering University, Harbin 150001, China
b.
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
c.
China Institute of Atomic Energy, Beijing 102413, China
d.
State Key Laboratory of Nuclear Resources and Environment, School of Nuclear Science and Technology, East China University of Technology, Nanchang 330013, China
e.
School of Chemistry, University of the Punjab, Lahore 54590, Pakistan

yeguoan@ciae.ac.cn

jiaocaishan@hrbeu.edu.cn

yuanly@ihep.ac.cn

shiwq@ihep.ac.cn

Received Date: 10 February 2023
Revised Date: 29 March 2023
Accepted Date: 7 April 2023
Available Online: 14 April 2023

Figures(6)

Uranium and molybdenum are important strategic elements. The production of ⁹⁹Mo and the hydrometallurgical process of uranium ore face difficult problems of separation of uranium and molybdenum. In this study, the four phenanthroline diamide ligands were synthesized, and extraction and stripping experiments were performed under different conditions to evaluate the potential application of these ligands for separation of U(Ⅵ) over Mo(Ⅵ). With the growth of alkyl chain, the solubility of ligands could be greatly improved, and the separation effect of U(Ⅵ) over Mo(Ⅵ) gradually increased. The SF_U/Mo were around 10,000 at 4 mol/L HNO₃. Three stripping agents were tested with the stripping efficiency of Na₂CO₃ (5%) > H₂O > HNO₃ (0.01 mol/L). The stripping percentages of the three stripping agents were all close to unity, indicating that the ligands had the potential to be recycled. The chemical stoichiometry of U(Ⅵ) complexes with ligands was evaluated as 1:1 using electrospray ionization mass spectrometry, ultraviolet visible spectroscopy and single-crystal X-ray diffraction. The consistency between theoretical calculation and experimental results further explains the coordination mechanism.
- Phenanthroline diamide ligand,
- Uranium,
- Molybdenum,
- Solvent extraction,
- Coordination chemistry
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