Citation: Chao-Yi Wang, Yu-Qing Liu, Chengguo Jia, Ming-Zhe Zhang, Chun-Li Song, Changling Xu, Ran Hao, Jian-Chun Qin, Ying-Wei Yang. An integrated supramolecular fungicide nanoplatform based on pH-sensitive metal–organic frameworks[J]. Chinese Chemical Letters, ;2023, 34(10): 108400. doi: 10.1016/j.cclet.2023.108400 shu

An integrated supramolecular fungicide nanoplatform based on pH-sensitive metal–organic frameworks

Chao-Yi Wang ^{a, b} ,
Yu-Qing Liu ^b ,
Chengguo Jia ^b ,
Ming-Zhe Zhang ^b ,
Chun-Li Song ^a ,
Changling Xu ^a ,
Ran Hao ^a ,
Jian-Chun Qin ^{b, *,} ,
Ying-Wei Yang ^{a, *,}

a.
College of Chemistry, Jilin University, Changchun 130012, China
b.
College of Plant Science, Jilin University, Changchun 130062, China

qinjc@jlu.edu.cn

ywyang@jlu.edu.cn

Received Date: 10 February 2023
Revised Date: 18 March 2023
Accepted Date: 28 March 2023
Available Online: 31 March 2023

Figures(4)

The construction of an integrated nanoplatform with controlled fungicide delivery features in the specific microenvironment produced by fungal pathogens is a highly desirable strategy to improve the utilization of fungicides. Herein, we report a supramolecular fungicide delivery system based on benzimidazole-modified NH₂-MIL-101(Fe) metal–organic frameworks (B-MIL-101(Fe) MOFs) as carriers loaded with osthole (OS), and β-cyclodextrin (β-CD) as nanovalves to form β-CD@B-MIL-101(Fe)-OS. The nanoplatform can release the loaded OS for fungus control through self-degradation of the MOFs skeleton in an oxalic acid microenvironment produced by Botrytis cinerea. The experimental results exhibit that the constructed supramolecular fungicide delivery system could effectively inhibit mycelial growth and protect the tomatoes from infection by B. cinerea during the ripening stage. This strategy constructs a facile and integrated supramolecular drug delivery system for B. cinerea control and opens up a new avenue for the sustainable development of modern agriculture.
- Controlled release,
- Fungicide nanoplatform,
- Host-guest chemistry,
- Microenvironment-responsive,
- Supramolecular chemistry
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