Citation: Xuancheng Chen, Yu Huan, Ningqiang Sun, Yuanhui Su, Xuesong Shen, Guoqing Li, Jiaqi Zhang, Tao Wei. Studying the variable energy band structure for energy storage materials in charge/discharge process[J]. Chinese Chemical Letters, ;2024, 35(2): 108380. doi: 10.1016/j.cclet.2023.108380 shu

Studying the variable energy band structure for energy storage materials in charge/discharge process

Xuancheng Chen ^a ,
Yu Huan ^{a, *,} ,
Ningqiang Sun ^a ,
Yuanhui Su ^a ,
Xuesong Shen ^b ,
Guoqing Li ^a ,
Jiaqi Zhang ^a ,
Tao Wei ^{a, *,}

a.
University of Jinan, Ji'nan 250022, China
b.
Weichai Power Co., Ltd., Weifang 261061, China

mse_huany@ujn.edu.cn

mse_weit@ujn.edu.cn

Received Date: 14 February 2023
Revised Date: 10 March 2023
Accepted Date: 24 March 2023
Available Online: 26 March 2023

Figures(5)

So far, a clear understanding about the relationship of variable energy band structure with the corresponding charge-discharge process of energy storage materials is still lacking. Here, using optical spectroscopy (red-green-blue (RGB) value, reflectivity, transmittance, UV–vis, XPS, UPS) to study α-Co(OH)₂ electrode working in KOH electrolyte as the research object, we provide direct experimental evidence that: (1) The intercalation of OH^– ions will reduce the valence/conduction band (VB and CB) and band gap energy (E_g) values; (2) The deintercalation of OH^– ions corresponds with the reversion of VB, CB and E_g to the initial values; (3) The color of Co(OH)₂ electrode also exhibit regular variations in RGB value during the charge-discharge process.
- Variable energy band structure,
- Energy storage materials,
- Charge-discharge process,
- Optical spectroscopy,
- Supercapacitors
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