Citation: Yiru Ma, Huiqi Qu, Wenna Wang, Ziyang Guo, Yueqin Yu, Feng Liu, Bin Yu, Minge Tian, Zhenjiang Li, Bin Li, Lei Wang. Graphdiyne scaffold anchored highly dispersed ruthenium nanoparticles as an efficient cathode catalyst for rechargeable Li–CO₂ battery[J]. Chinese Chemical Letters, ;2024, 35(1): 108352. doi: 10.1016/j.cclet.2023.108352 shu

Graphdiyne scaffold anchored highly dispersed ruthenium nanoparticles as an efficient cathode catalyst for rechargeable Li–CO₂ battery

Yiru Ma ^a ,
Huiqi Qu ^{a, d} ,
Wenna Wang ^a ,
Ziyang Guo ^a ,
Yueqin Yu ^a ,
Feng Liu ^e ,
Bin Yu ^e ,
Minge Tian ^f ,
Zhenjiang Li ^b ,
Bin Li ^{b, *,} ,
Lei Wang ^{a, c, *,}

a.
College of Chemistry and Molecular Engineering, State Key Laboratory Base of Eco-Chemical Engineering, International Science and Technology Cooperation Base of Eco-Chemical Engineering and Green Manufacturing, Qingdao University of Science and Technology, Qingdao 266042, China
b.
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
c.
College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
d.
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
e.
Biomedical Sensing Engineering Technology Research Center, Shandong University, Ji’nan 250100, China
f.
Scientific Green (Shandong) Environmental Technology Co., Ltd., Jining Economic Development Zone, Jining 272499, China

binli@qust.edu.cn

inorchemwl@126.com

Received Date: 9 January 2023
Revised Date: 9 February 2023
Accepted Date: 16 March 2023
Available Online: 20 March 2023

Figures(4)

Lithium (Li)–CO₂ battery is rising as an attractive energy-storage system with the competence of CO₂ conversion/fixation. However, its practical development is seriously hindered by the high overpotential. Herein, a rational design on a highly catalytic Li–CO₂ battery electrode built by graphdiyne powder as a multi-functional laminar scaffold with anchored highly dispersed Ru nanoparticles is explored. The strong interaction between the abundant acetylenic bond sites of graphdiyne scaffold and Ru nanoparticles can effectively promote the electrochemical progress and reduce the voltage polarization. The unique channels architecture of the cathodic catalyst with enough space not only accelerates CO₂ diffusion and electrons/Li⁺ transport, but also allows a large amount of accommodation for discharged product (Li₂CO₃) to assure an advanced capacity. The corresponding Li–CO₂ battery displays an advanced discharged capacity of 15,030 mAh/g at 500 mA/g, great capacity retention of 8873 mAh/g at 2 A/g, high coulombic efficiency of 97.6% at 500 mA/g and superior life span for 120 cycles with voltage gap of 1.67 V under a restricted capacity of 1000 mAh/g at 500 mA/g. Ex/in-situ studies prove that synergy between Ru nanoparticles and acetylene bonds of GDY can boost the round-trip CO₂RR and CO₂ER kinetics.
- Nanopores,
- Li–CO₂ battery,
- Anchored Ru nanoparticles,
- Graphdiyne,
- Synergistic effect
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Graphdiyne scaffold anchored highly dispersed ruthenium nanoparticles as an efficient cathode catalyst for rechargeable Li–CO2 battery

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Graphdiyne scaffold anchored highly dispersed ruthenium nanoparticles as an efficient cathode catalyst for rechargeable Li–CO₂ battery