Citation: Zhilong Jiang, He Zhao, Jun Wang, Bangtang Chen, Wenzhi Lv, Yiming Li, Qiangqiang Dong, Die Liu, Weiya Liu, Min Wang, Fan Fu, Seok-Ho Hwang, Mingzhao Chen, Pingshan Wang. Trefoil-shaped metallacycle and metallacage via heteroleptic self-assembly[J]. Chinese Chemical Letters, ;2023, 34(12): 108334. doi: 10.1016/j.cclet.2023.108334 shu

Trefoil-shaped metallacycle and metallacage via heteroleptic self-assembly

Zhilong Jiang ^{a, 1} ,
He Zhao ^{b, 1} ,
Jun Wang ^a ,
Bangtang Chen ^a ,
Wenzhi Lv ^c ,
Yiming Li ^b ,
Qiangqiang Dong ^b ,
Die Liu ^b ,
Weiya Liu ^a ,
Min Wang ^a ,
Fan Fu ^a ,
Seok-Ho Hwang ^d ,
Mingzhao Chen ^{a, *,} ,
Pingshan Wang ^{a, b, *,}

a.
Institute of Environmental Research at Greater Bay Area, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou 510006, China
b.
Department of Organic and Polymer Chemistry, Hunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
c.
College of Chemistry and Chemical Engineering, Qiannan Normal University for Nationalities, Duyun 558000, China
d.
Materials Chemistry & Engineering Laboratory, Department of Polymer Science & Engineering, Dankook University, Yongin, Gyeonggi-do 16890, South Korea

jinyulinzhao@foxmail.com

chemwps@csu.edu.cn

Received Date: 3 January 2023
Revised Date: 1 March 2023
Accepted Date: 12 March 2023
Available Online: 17 March 2023

Figures(4)

Template-oriented multi-component synthesis method has been proven to be an exceedingly reasonable and excellent method for the synthesis of giant two-dimensional (2D) and three-dimensional (3D) supramolecules, but designing and constructing heteroleptic and controllable self-assembly without unexpected by-products remains a challenge. Here we report two discrete trefoil-shaped metallacycle S1 and metallacage S2 by heteroleptic self-assembly using one hexaphenylbenzene core ligand and two capping ligands. The 2D trefoil-shaped metallacycle S1 could resemble the emblem of the classic 'Mitsubishi' motif. The use of template-oriented ligand and bent spacer ligand promotes the quantitative formation of the desired 3D trefoil-shaped metallacage S2. The formed metallacage S2 possesses a molecular weight up to 36 kDa, diameter 6.6 nm and height 3.0 nm. All supramolecular coordination complexes were fully characterized by NMR spectroscopy (¹H NMR, 2D COSY, 2D NOESY, 2D DOSY), high-resolution electrospray ionization mass spectrometry ESI-MS, ESI-TWIM-MS, TEM and AFM.
- Supramolecular coordination complex,
- 'Mitsubishi' molecule,
- Trefoil-shaped metallacage,
- Heteroleptic self-assembly,
- Terpyridine
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