Citation: Jingyuan Qiao, Zhuoheng Bao, Lingqiao Kong, Xingyu Liu, Chengjie Lu, Meng Ni, Wei He, Min Zhou, ZhengMing Sun. MOF-derived heterostructure CoNi/CoNiP anchored on MXene framework as a superior bifunctional electrocatalyst for zinc-air batteries[J]. Chinese Chemical Letters, ;2023, 34(12): 108318. doi: 10.1016/j.cclet.2023.108318 shu

MOF-derived heterostructure CoNi/CoNiP anchored on MXene framework as a superior bifunctional electrocatalyst for zinc-air batteries

Jingyuan Qiao ^a ,
Zhuoheng Bao ^a ,
Lingqiao Kong ^a ,
Xingyu Liu ^a ,
Chengjie Lu ^a ,
Meng Ni ^b ,
Wei He ^{a, *,} ,
Min Zhou ^{c, *,} ,
ZhengMing Sun ^{a, *,}

a.
Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
b.
Department of Building and Real Estate, Research Institute for Sustainable Urban Development (RISUD) and Research Institute for Smart Energy (RISE), The Hong Kong Polytechnic University, Hong Kong 999077, China
c.
School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China

weih@seu.edu.cn

mzchem@ustc.edu.cn

zmsun@seu.edu.cn

Received Date: 15 November 2022
Revised Date: 7 February 2023
Accepted Date: 7 March 2023
Available Online: 12 March 2023

Figures(5)

Zinc-air batteries (ZABs) are regarded as promising next-generation energy storage devices but limited by their sluggish oxygen reduction/evolution reactions (ORR/OER). Herein, the bifunctional catalyst consisting of MXene and metal compounds has been constructed via a controllable strategy. For demonstration, a 3D MXene framework with anchored heterostructure CoNi/CoNiP and nitrogen-doped carbon (NC) called H-CNP@M is constructed by metal-ion inducement and phosphorization. The bimetal-semiconductor heterostructure greatly enhances the catalytic performance. The H-CNP@M exhibits superior activities toward ORR (E_1/₂ = 0.833 V) and OER (η₁₀ = 294 mV). Both aqueous and all-solid-state ZAB assembled with H-CNP@M demonstrate superior performance (peak power density of 166.5 mW/cm² in aqueous case). This work provides a facile and general strategy to prepare MXene-supported bimetallic heterostructure for high-performance electrochemical energy devices.
- Heterostructure,
- Metal-organic frameworks,
- MXene,
- Bifunctional electrocatalyst,
- Zn-air battery
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