Citation: Jing Hao, Feifan Lang, Liqin Hao, Yi Yang, Lulu Zhang, Hao Zhang, Quan-Wen Li, Jiandong Pang, Xian-He Bu. Enhancing the singlet oxygen capture and release rate of metal−organic frameworks through interpenetration tuning[J]. Chinese Chemical Letters, ;2023, 34(12): 108310. doi: 10.1016/j.cclet.2023.108310 shu

Enhancing the singlet oxygen capture and release rate of metal−organic frameworks through interpenetration tuning

Jing Hao ^a ,
Feifan Lang ^b ,
Liqin Hao ^a ,
Yi Yang ^a ,
Lulu Zhang ^a ,
Hao Zhang ^b ,
Quan-Wen Li ^b ,
Jiandong Pang ^{b, c, *,} ,
Xian-He Bu ^{a, b, c, *,}

a.
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
b.
School of Materials Science and Engineering, Smart Sensing Interdisciplinary Science Center, Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China
c.
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China

jdpang@nankai.edu.cn

buxh@nankai.edu.cn

Received Date: 24 December 2022
Revised Date: 17 January 2023
Accepted Date: 6 March 2023
Available Online: 15 March 2023

Figures(5)

Recognized as one of the important active species involved in various reactions, singlet oxygen (¹O₂) shows potential applications in chemical, biological, and environmental related fields. However, the controlled capture and release of ¹O₂ are still facing huge challenges due to its short lifetime and high reactivity. Herein, a framework-interpenetration tuning strategy was applied on a metal-organic framework (MOF) that aiming to improve the capture and release rate of ¹O₂. The porosity of the MOF was remarkably enhanced with the structural evolution from seven-fold (termed NKM-181) to six-fold interpenetration (termed NKM-182), and the active anthracene sites became much more accessible. Such drastic process can be achieved as simple as exchanging the primitive MOF in selected solvent and occurred surprisingly as single-crystal to single-crystal transformation. Also, additionally owing to the unblocked regular channels, NKM-182 shown significantly improved ¹O₂ trapping and releasing rates compared to that of in NKM-181. This work demonstrates an unprecedented regulation of ¹O₂ capture and release process, along with achieving the highest ¹O₂ capture and release rate among reported porous materials. Furthermore, the obtained endoperoxides with ¹O₂ loaded (termed EPO-NKM-181 and EPO-NKM-182) can be used as a high efficiency smart material for anti-fake application
- Metal-organic framework,
- Singlet oxygen capture and release,
- Regulation,
- Single-crystal to single-crystal transformation,
- Anti-fake application
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