Citation: Zhuohao Zhao, Jianguo Liu, Chen-Ho Tung, Wenguang Wang. Nickel-catalyzed cooperative B-H bond activation for hydroboration of N–heteroarenes, ketones and imines^☆[J]. Chinese Chemical Letters, ;2023, 34(10): 108293. doi: 10.1016/j.cclet.2023.108293 shu

Nickel-catalyzed cooperative B-H bond activation for hydroboration of N–heteroarenes, ketones and imines^☆

Zhuohao Zhao ^a ,
Jianguo Liu ^{b, *,} ,
Chen-Ho Tung ^a ,
Wenguang Wang ^{a, b, *,}

a.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
b.
College of Chemistry, Beijing Normal University, Beijing 100875, China

^☆

jgliu1990@126.com

wwg@bnu.edu.cn

Received Date: 11 December 2022
Revised Date: 26 February 2023
Accepted Date: 1 March 2023
Available Online: 5 March 2023

Figures(9)

We report two air-stable nickel(Ⅱ) half-sandwich complexes, Cp*Ni(1,2-Cy₂PC₆H₄O) (1) and Cp*Ni(1,2-Ph₂PC₆H₄NH) (2), for cooperative B-H bond activation and their applications in catalytic hydroboration of unsaturated organic compounds. Both 1 and 2 react with HBpin by adding the B-H bond across the Ni−X bond (X = O or N), giving rise to the 18-electron Ni(Ⅱ)−H active species, [H1(Bpin)] and [H2(Bpin)]. Subtle tuning of the Ni−X pair and the supporting ancillary phosphine have a significant effect on the reactivity and catalytic performance of Cp*Ni(1,2-R₂PC₆H₄X). Unlike [H2(Bpin)], the activation of HBpin in [H1(Bpin)] is reversible, which enables the Ni−O complex to be an effective cooperative catalyst in the hydroboration of N-heteroarenes, and as well as ketones and imines.
- Nickel complex,
- Metal-ligand cooperation,
- B-H activation,
- Hydroboration,
- Metal hydride
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Nickel-catalyzed cooperative B-H bond activation for hydroboration of N–heteroarenes, ketones and imines☆

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通讯作者: 陈斌, bchen63@163.com

Nickel-catalyzed cooperative B-H bond activation for hydroboration of N–heteroarenes, ketones and imines^☆