Citation: Gaigai Duan, Hua Zhang, Chunmei Zhang, Shaohua Jiang, Haoqing Hou. High mass-loading α-Fe₂O₃ nanoparticles anchored on nitrogen-doped wood carbon for high-energy-density supercapacitor[J]. Chinese Chemical Letters, ;2023, 34(12): 108283. doi: 10.1016/j.cclet.2023.108283 shu

High mass-loading α-Fe₂O₃ nanoparticles anchored on nitrogen-doped wood carbon for high-energy-density supercapacitor

Gaigai Duan ^a ,
Hua Zhang ^{b, *,} ,
Chunmei Zhang ^{c, *,} ,
Shaohua Jiang ^{a, *,} ,
Haoqing Hou ^b

a.
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
b.
College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
c.
Institute of Materials Science and Devices, School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China

hzhang1@jxnu.edu.cn

cmzhang@usts.edu.cn

shaohua.jiang@njfu.edu.cn

Received Date: 20 January 2023
Revised Date: 15 February 2023
Accepted Date: 1 March 2023
Available Online: 4 March 2023

Figures(3)

The trade-off between mass-loading and cycling stability is always a big challenge for iron oxide-based electrodes. Herein, α-Fe₂O₃ nanoparticles uniformly anchored on nitrogen-doped wood carbons with high mass-loading have been synthesized via a facile electrodeposition method accompanied by post-heating treatment. The resultant composite delivers a high specific capacitance of 603 F/g at 0.1 A/g and superior capacitance retention of 85.5% after 10,000 cycles at 10 A/g, indicating excellent long-term cycling stability. Such excellent electrochemical performance can be attributed to the synergistic effects of α-Fe₂O₃ nanoparticles and the conductive matrix as well as the formation of interfacial Fe-O-C bonding, which enables the composite electrode to provide plenty of accessible redox active sites, sufficient electron transport and electrolyte ions diffusion, and robust interfacial interaction. Consequently, the asymmetrical supercapacitor exhibits a high energy density of 30.3 Wh/kg at 125 W/kg, suggesting its great potential for practical applications.
- α-Fe₂O₃ nanoparticles,
- High mass-loading,
- Synergistic effect,
- Interfacial interaction,
- Energy density
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High mass-loading α-Fe2O3 nanoparticles anchored on nitrogen-doped wood carbon for high-energy-density supercapacitor

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High mass-loading α-Fe₂O₃ nanoparticles anchored on nitrogen-doped wood carbon for high-energy-density supercapacitor