Citation: Xiyang Wang, Keke Huang, Xiaofeng Wu, Long Yuan, Liping Li, Guangshe Li, Shouhua Feng. Manipulation and observation of atomic-scale superlattices in perovskite manganate[J]. Chinese Chemical Letters, ;2023, 34(12): 108267. doi: 10.1016/j.cclet.2023.108267 shu

Manipulation and observation of atomic-scale superlattices in perovskite manganate

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin Provincial International Cooperation Key Laboratory of Advanced Inorganic Solid Functional Materials, Jilin University, Changchun 130012, China

shfeng@jlu.edu.cn

Received Date: 20 October 2022
Revised Date: 23 February 2023
Accepted Date: 23 February 2023
Available Online: 27 February 2023

Figures(4)

Superlattices in crystals, particularly in perovskite oxides with strong correlation effects, can create new states of matter and produce peculiar physicochemical phenomena. However, the newfangled perovskite superlattices depend on physical deposition with unit-cell precision. It has been challenging to explore a new suitable chemical method to tailor perovskite superlattices. Herein, we present a new bottom-up strategy to precisely prepare atomic-scale oxide superlattices of (LaMnO₃)₁-(La_1-x-yCa_xK_yMnO₃)₂ in a monodispersed perovskite La_0.66Ca_0.29K_0.05MnO₃ (LCKMO). The special atomic-scale perovskite superlattices are demonstrated using SAED, HAADF-STEM, XRD, and atomic-resolution elemental mapping. Our experiments reveal that the perovskite superlattices can be fabricated under extreme hydrothermal conditions utilizing ultra-high concentrations of KOH. An approximate molten salt system in the hydrothermal process can induce the disproportionation reaction of MnO₂ solids, which is vital to the growth of ordered perovskite superlattices. This work not only clarifies the hydrothermal growth process of perovskite oxides in extreme conditions, but also proposes a novel engineering route toward perovskite superlattices.
- Perovskite oxides,
- Hydrothermal,
- Ordered superstructure,
- Perovskite superlattice,
- Disproportionation reaction
1. [1]
  A.K. Yadav, C.T. Nelson, S.L. Hsu, et al., Nature 530 (2016) 198–201. doi: 10.1038/nature16463
2. [2]
  V.A. Stoica, N. Laanait, C. Dai, et al., Nat. Mater. 18 (2019) 377–383. doi: 10.1038/s41563-019-0311-x
3. [3]
  Y.L. Tang, Y.L. Zhu, X.L. Ma, et al., Science 348 (2015) 547–551. doi: 10.1126/science.1259869
4. [4]
  S. Das, Y.L. Tang, Z. Hong, et al., Nature 568 (2019) 368–372. doi: 10.1038/s41586-019-1092-8
5. [5]
  A.R. Damodaran, J.D. Clarkson, Z. Hong, et al., Nat. Mater. 16 (2017) 1003–1009. doi: 10.1038/nmat4951
6. [6]
  E. Maniv, R.A. Murphy, S.C. Haley, et al., Nat. Phys. 17 (2021) 525–530. doi: 10.1038/s41567-020-01123-w
7. [7]
  N. Driza, S. Blanco-Canosa, M. Bakr, et al., Nat. Mater. 11 (2012) 675–681. doi: 10.1038/nmat3378
8. [8]
  E. Bousquet, M. Dawber, N. Stucki, et al., Nature 452 (2008) 732–736. doi: 10.1038/nature06817
9. [9]
  J. Ravichandran, A.K. Yadav, R. Cheaito, et al., Nat. Mater. 13 (2014) 168–172. doi: 10.1038/nmat3826
10. [10]
  S. Sengodan, S. Choi, A. Jun, et al., Nat. Mater. 14 (2015) 205–209. doi: 10.1038/nmat4166
11. [11]
  S.J. May, P.J. Ryan, J.L. Robertson, et al., Nat. Mater. 8 (2009) 892–897. doi: 10.1038/nmat2557
12. [12]
  Y.J. Wang, Y.P. Feng, Y.L. Zhu, et al., Nat. Mater. 19 (2020) 881–886. doi: 10.1038/s41563-020-0694-8
13. [13]
  M. Li, C. Tang, T.R. Paudel, et al., Adv. Mater. 31 (2019) e1901386. doi: 10.1002/adma.201901386
14. [14]
  A. Ohtomo, H.Y. Hwang, Nature 427 (2004) 423–426. doi: 10.1038/nature02308
15. [15]
  A. Bhattacharya, S.J. May, S.G.E. te Velthuis, et al., Phys. Rev. Lett. 100 (2008) 257203. doi: 10.1103/PhysRevLett.100.257203
16. [16]
  H. Yamada, P.H. Xiang, A. Sawa, Phys. Rev. B 81 (2010) 014410. doi: 10.1103/PhysRevB.81.014410
17. [17]
  S. García-Martín, E. Urones-Garrote, M.C. Knapp, et al., J. Am. Chem. Soc. 130 (2008) 15028–15037. doi: 10.1021/ja802511d
18. [18]
  S. Garcia-Martin, G. King, E. Urones-Garrote, et al., Chem. Mater. 23 (2011) 163–170. doi: 10.1021/cm102592p
19. [19]
  N.I. Kim, Y.J. Sa, T.S. Yoo, et al., Sci. Adv. 4 (2018) eaap9360. doi: 10.1126/sciadv.aap9360
20. [20]
  M.C. Viola, M.J. Martínez-Lope, J.A. Alonso, et al., Chem. Mater. 15 (2003) 1655–1663. doi: 10.1021/cm0208455
21. [21]
  T. Shimada, J. Nakamura, T. Motohashi, et al., Chem. Mater. 15 (2003) 4494–4497. doi: 10.1021/cm030409y
22. [22]
  Y.L. Jiang, L. Yuan, X.Y. Wang, et al., Angew. Chem. Int. Ed. 59 (2020) 22659–22666. doi: 10.1002/anie.202010246
23. [23]
  Y. Hosaka, N. Ichikawa, T. Saito, et al., J. Am. Chem. Soc. 137 (2015) 7468–7473. doi: 10.1021/jacs.5b03712
24. [24]
  D. Bhattacharya, H.S. Maiti, Phys. Rev. B 66 (2002) 132413. doi: 10.1103/PhysRevB.66.132413
25. [25]
  M.E. Brown, A.H. Bouchez, C.A. Griffith, et al., Nature 420 (2002) 795–797. doi: 10.1038/nature01302
26. [26]
  C. Chen, F. Yu, N. Xu, D. Fan, Ceram. Int. 46 (2020) 15646–15653. doi: 10.1016/j.ceramint.2020.03.114
27. [27]
  S. Feng, H. Yuan, Z. Shi, et al., J. Mater. Sci. 43 (2007) 2131–2137.
28. [28]
  D. Guan, G. Ryu, Z. Hu, et al., Nat. Commun. 11 (2020) 3376. doi: 10.1038/s41467-020-17108-5
29. [29]
  D. Guan, J. Zhong, H. Xu, et al., Appl. Phys. Rev. 9 (2022) 011422. doi: 10.1063/5.0083059
30. [30]
  J. Qian, Q. Guo, L. Liu, J. Mater. Chem. A 5 (2017) 16786–16795. doi: 10.1039/C7TA04008C
31. [31]
  D. Sherman, Am. Miner. 69 (1984) 788–799.
32. [32]
  J. Miao, J. Li, J. Dai, et al., Ind. Eng. Chem. Res. 59 (2019) 99–109.
33. [33]
  D. Guan, J. Zhou, Z. Hu, et al., Adv. Funct. Mater. 29 (2019) 1900704. doi: 10.1002/adfm.201900704
34. [34]
  H. Wu, T. Burnus, Z. Hu, et al., Phys. Rev. Lett. 102 (2009) 026404. doi: 10.1103/PhysRevLett.102.026404
35. [35]
  Y. Shen, Y. Zhu, J. Sunarso, et al., Chemistry 24 (2018) 6950–6957. doi: 10.1002/chem.201705675
36. [36]
  A. Gulec, D. Phelan, C. Leighton, R.F. Klie, ACS Nano 10 (2016) 938–947. doi: 10.1021/acsnano.5b06067
37. [37]
  R. Cortes-Gil, M.L. Ruiz-Gonzalez, D. Gonzalez-Merchante, et al., Nano Lett. 16 (2016) 760–765. doi: 10.1021/acs.nanolett.5b04704
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