Citation: Mingzhen Ding, Ruyu Shi, Jie Qu, Minman Tong. Construction of highly stable LiI/LiBr-based nanocomposite cathode via triple confinement mechanisms for lithium-halogen batteries[J]. Chinese Chemical Letters, ;2023, 34(11): 108248. doi: 10.1016/j.cclet.2023.108248 shu

Construction of highly stable LiI/LiBr-based nanocomposite cathode via triple confinement mechanisms for lithium-halogen batteries

Mingzhen Ding ^a ,
Ruyu Shi ^b ,
Jie Qu ^{a, *,} ,
Minman Tong ^{b, *,}

a.
College of Chemistry and Chemical Engineering, Key Laboratory of Light Energy Conversion Materials of Hunan Province College, Hunan Normal University, Changsha 410081, China
b.
School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou 221116, China

qujie@hunnu.edu.cn

tongmm@jsnu.edu.cn

Received Date: 24 November 2022
Revised Date: 17 December 2022
Accepted Date: 20 February 2023
Available Online: 24 February 2023

Figures(4)

Lithium-halogen batteries (LHBs), including lithium iodide (Li-I₂) and lithium bromide (Li-Br₂) batteries, are receiving more attention for offering high energy density and excellent kinetic performance. However, LHBs commercialization is seriously hindered by the high solubility of halides, causing lower capacity and poor cyclability. This research covers the fabrication of a highly stable cathode of amorphous carbon coated CMK-3/LiI/LiBr nanocomposite for metal lithium batteries. The nanopores and coated layer can physically trap the dissolution of active materials. The amorphous carbon generated from polyacrylonitrile carries abundant nitrogen heteroatoms for the stable anchorage of halogens and halides via strong chemical adsorption. In addition, iodine can act as a complexing agent with bromine to reduce solvation energy. Consequently, the as-prepared CMK-3/LiI/LiBr/carbon (CIBP) nanocomposite cathode demonstrates an ultra-high reversible capacity of 407.4 mAh/g at the current density of 1.0 C performing up to 300 stable cycles.
- Lithium-halogen batteries,
- Cathode,
- LiI/LiBr,
- High capacity,
- Triple confinement
1. [1]
  J. Cui, T.G. Zhan, K.D. Zhang, et al., Chin. Chem. Lett. 28 (2017) 2171–2179. doi: 10.1016/j.cclet.2017.11.039
2. [2]
  D. Zhang, G. Chen, H. Wang, et al., Chin. Chem. Lett. 33 (2022) 3925–3930. doi: 10.1016/j.cclet.2021.11.021
3. [3]
  Y. Zou, Z. Cao, J. Zhang, et al., Adv. Mater. 33 (2021) 2102964. doi: 10.1002/adma.202102964
4. [4]
  S. Koul, Y. Morita, F. Fujisaki, et al., J. Electrochem. Soc. 169 (2022) 020542. doi: 10.1149/1945-7111/ac4ea5
5. [5]
  Z. Xue, Z. Gao, X. Zhao, Energy Environ. Mater. 5 (2022) 1155–1179. doi: 10.1002/eem2.12442
6. [6]
  L. Qiao, C. Wang, X.S. Zhao, ACS Appl. Energy Mater. 4 (2021) 7012–7019. doi: 10.1021/acsaem.1c01068
7. [7]
  Z. Su, Z. Wei, C. Lai, et al., Energy Storage Mater. 14 (2018) 129–135. doi: 10.1016/j.ensm.2018.03.002
8. [8]
  Q. Zhang, Y.H. Zeng, S.H. Ye, et al., J. Power Sources 463 (2020) 228212. doi: 10.1016/j.jpowsour.2020.228212
9. [9]
  K. Li, S. Chen, S. Chen, et al., Nano Res. 12 (2018) 549–555. doi: 10.1021/acsnano.7b07247
10. [10]
  Z. Wu, J. Xu, Q. Zhang, et al., Energy Storage Mater. 10 (2018) 62–68. doi: 10.1016/j.ensm.2017.08.010
11. [11]
  Y.L. Wang, Q.L. Sun, Q.Q. Zhao, et al., Energy Environ. Sci. 4 (2011) 3947–3950. doi: 10.1039/c1ee01875b
12. [12]
  Q. Zhao, Y. Lu, Z. Zhu, et al., Nano Lett. 15 (2015) 5982–5987. doi: 10.1021/acs.nanolett.5b02116
13. [13]
  K. Takemoto, H. Yamada, J. Power Sources 281 (2015) 334–340. doi: 10.1016/j.jpowsour.2015.02.015
14. [14]
  K. Li, Z. Hu, J. Ma, et al., Adv. Mater. 31 (2019) 1902399. doi: 10.1002/adma.201902399
15. [15]
  Z. Cheng, H. Pan, F. Li, et al., Nat. Commun. 13 (2022) 125. doi: 10.1038/s41467-021-27728-0
16. [16]
  M. Xing, Z.Z. Zhao, Y.J. Zhang, et al., Mater. Today Energy 18 (2020) 100534. doi: 10.1016/j.mtener.2020.100534
17. [17]
  Y.L. Wang, X. Wang, L.Y. Tian, et al., J. Mater. Chem. A 3 (2015) 1879–1883. doi: 10.1039/C4TA05569A
18. [18]
  B.B. Peterson, E.M. Andrews, F. Hung, et al., J. Power Sources 492 (2021) 229658. doi: 10.1016/j.jpowsour.2021.229658
19. [19]
  S.M. Zhu, H.A. Zhou, M. Hibino, et al., Adv. Funct. Mater. 15 (2005) 381–386. doi: 10.1002/adfm.200400222
20. [20]
  G. Jiang, N. Zheng, X. Chen, et al., Chem. Eng. J. 373 (2019) 1309–1318. doi: 10.1016/j.cej.2019.05.119
21. [21]
  F.K. Shan, G.X. Liu, W.J. Lee, et al., J. Cryst. Growth 291 (2006) 328–333. doi: 10.1016/j.jcrysgro.2006.03.036
22. [22]
  Y.H. Wu, H.H. Pan, X. Zhou, et al., Chem. Sci. 6 (2015) 4615–4622. doi: 10.1039/C5SC00708A
23. [23]
  Mukarromah, D.I. Pamungkas, Darminto, AIP Conf. Proc. 2120 (2019) 050011.
24. [24]
  D.C. Gong, B. Wang, J.Y. Zhu, et al., Adv. Energy Mater. 7 (2017) 1601885. doi: 10.1002/aenm.201601885
25. [25]
  S. Wei, L. Ma, K.E. Hendrickson, et al., J. Am. Chem. Soc. 137 (2015) 12143–12152. doi: 10.1021/jacs.5b08113
26. [26]
  V. Sortur, J. Yenagi, J. Tonannavar, et al., Spectrochim. Acta A 71 (2008) 688–694. doi: 10.1016/j.saa.2008.01.016
27. [27]
  S. Ramalingam, P. Anbusrinivasan, S. Periandy, Spectrochim. Acta A 78 (2011) 826–834. doi: 10.1016/j.saa.2010.12.041
28. [28]
  Q.J. Shen, W.J. Jin, Phys. Chem. Chem. Phys. 13 (2011) 13721–13729. doi: 10.1039/c1cp20522f
29. [29]
  H. Li, M. Li, X. Zhou, et al., Sustain. Energy Fuels 4 (2020) 3871–3878. doi: 10.1039/D0SE00161A
30. [30]
  J. He, Y. Chen, W. Lv, et al., ACS Nano 10 (2016) 10981–10987. doi: 10.1021/acsnano.6b05696
31. [31]
  R.R. Salunkhe, Y. Kamachi, N.L. Torad, et al., J. Mater. Chem. A 2 (2014) 19848–19854. doi: 10.1039/C4TA04277H
32. [32]
  S. Ma, Z. Zhang, Y. Wang, et al., Chem. Eng. J. 418 (2021) 129410. doi: 10.1016/j.cej.2021.129410
33. [33]
  T.I.T. Okpalugo, P. Papakonstantinou, H. Murphy, et al., Carbon 43 (2005) 153–161. doi: 10.1016/j.carbon.2004.08.033
34. [34]
  A. Bunde, W. Dieterich, E. Roman, Phys. Rev. Lett. 55 (1985) 5–8. doi: 10.1103/PhysRevLett.55.5
35. [35]
  Y.S. Choi, Y.S. Lee, K.H. Oh, et al., Phys. Chem. Chem. Phys. 18 (2016) 22540–22547. doi: 10.1039/C6CP03563A
36. [36]
  X.F. He, Y.Z. Zhu, Y.F. Mo, Nat. Commun. 8 (2017) 15893. doi: 10.1038/ncomms15893
37. [37]
  Z. Liu, Y. Zhang, J. Hao, et al., Inorg. Chem. Commun. 112 (2020) 107761. doi: 10.1016/j.inoche.2019.107761
38. [38]
  D. Pan, S. Wang, B. Zhao, et al., Chem. Mater. 21 (2009) 3136–3142. doi: 10.1021/cm900395k
39. [39]
  B. Xie, Y. Chen, M. Yu, et al., Carbon 99 (2016) 35–42. doi: 10.1016/j.carbon.2015.11.077
40. [40]
  K. Li, B. Lin, Q. Li, et al., ACS Appl. Mater. Interfaces 9 (2017) 20508–20518. doi: 10.1021/acsami.7b02943
41. [41]
  H.F. Wang, G.M. Zhang, L.L. Ke, et al., Nanoscale 9 (2017) 9365–9375. doi: 10.1039/C7NR02311A
42. [42]
  Q. Zhang, Z.Z. Wu, F. Liu, et al., J. Mater. Chem. A 5 (2017) 15235–15242. doi: 10.1039/C7TA04246A
43. [43]
  W.K. Behl, J. Electrochem. Soc. 136 (1989) 2305–2310. doi: 10.1149/1.2097315
44. [44]
  S. Kim, S.K. Kim, P.C. Sun, et al., Nano Lett. 17 (2017) 6893–6899. doi: 10.1021/acs.nanolett.7b03290
45. [45]
  M. Winter, R.J. Brodd, Chem. Rev. 104 (2004) 4245–4270. doi: 10.1021/cr020730k
1. [1]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
2. [2]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
3. [3]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
4. [4]
  Yue Wang , Caixia Xu , Xingtao Tian , Siyu Wang , Yan Zhao . Challenges and Modification Strategies of High-Voltage Cathode Materials for Li-ion Batteries. Chinese Journal of Structural Chemistry, 2023, 42(10): 100167-100167. doi: 10.1016/j.cjsc.2023.100167
5. [5]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
6. [6]
  Yun Wei , Lei Zhou , Wenbin Hu , Liming Yang , Guang Yang , Chaoqiang Wang , Hui Shi , Fei Han , Yufa Feng , Xuan Ding , Penghui Shao , Xubiao Luo . Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries: Process analysis and evaluation. Chinese Chemical Letters, 2024, 35(7): 109172-. doi: 10.1016/j.cclet.2023.109172
7. [7]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
8. [8]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
9. [9]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
10. [10]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
11. [11]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
12. [12]
  Zhe Wang , Li-Peng Hou , Qian-Kui Zhang , Nan Yao , Aibing Chen , Jia-Qi Huang , Xue-Qiang Zhang . High-performance localized high-concentration electrolytes by diluent design for long-cycling lithium metal batteries. Chinese Chemical Letters, 2024, 35(4): 108570-. doi: 10.1016/j.cclet.2023.108570
13. [13]
  Yunfei Shen , Long Chen . Gradient imprinted Zn metal anodes assist dendrites-free at high current density/capacity. Chinese Journal of Structural Chemistry, 2024, 43(10): 100321-100321. doi: 10.1016/j.cjsc.2024.100321
14. [14]
  Tao Wei , Jiahao Lu , Pan Zhang , Qi Zhang , Guang Yang , Ruizhi Yang , Daifen Chen , Qian Wang , Yongfu Tang . An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity. Chinese Chemical Letters, 2024, 35(8): 109122-. doi: 10.1016/j.cclet.2023.109122
15. [15]
  Jun Jiang , Tong Guo , Wuxin Bai , Mingliang Liu , Shujun Liu , Zhijie Qi , Jingwen Sun , Shugang Pan , Aleksandr L. Vasiliev , Zhiyuan Ma , Xin Wang , Junwu Zhu , Yongsheng Fu . Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(4): 108565-. doi: 10.1016/j.cclet.2023.108565
16. [16]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
17. [17]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
18. [18]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
19. [19]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
20. [20]
  Mei-Chen Liu , Qing-Song Liu , Yi-Zhou Quan , Jia-Ling Yu , Gang Wu , Xiu-Li Wang , Yu-Zhong Wang . Phosphorus-silicon-integrated electrolyte additive boosts cycling performance and safety of high-voltage lithium-ion batteries. Chinese Chemical Letters, 2024, 35(8): 109123-. doi: 10.1016/j.cclet.2023.109123

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(305)
HTML views(15)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142