Citation: Yongjie Li, Mingjie Huang, Wen-Da Oh, Xiaohui Wu, Tao Zhou. Efficient activation of sulfite for reductive-oxidative degradation of chloramphenicol by carbon-supported cobalt ferrite catalysts[J]. Chinese Chemical Letters, ;2023, 34(10): 108247. doi: 10.1016/j.cclet.2023.108247 shu

Efficient activation of sulfite for reductive-oxidative degradation of chloramphenicol by carbon-supported cobalt ferrite catalysts

Yongjie Li ^a ,
Mingjie Huang ^{a, *,} ,
Wen-Da Oh ^b ,
Xiaohui Wu ^a ,
Tao Zhou ^{a, *,}

a.
School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800, Malaysia

huangmingjie@hust.edu.cn

zhoutao@hust.edu.cn

Received Date: 20 September 2022
Revised Date: 6 February 2023
Accepted Date: 19 February 2023
Available Online: 22 February 2023

Figures(4)

Activation of (bi)sulfite (S(Ⅳ)) by metal oxides is strongly limited by low electrons utilization. In this study, two carbon-supported cobalt ferrites spinels (CoFe₂O₄ QDs-GO and CoFe₂O₄ MOFs-CNTs) have been successfully synthesized by one-step solvothermal method. It was found that both catalysts could efficiently activate S(Ⅳ), with rapid reductive dechlorination and then oxidative degradation of a recalcitrant antibiotic chloramphenicol (CAP). Characterizations revealed that CoFe₂O₄ spinels were tightly coated on the carbon bases (GO and CNTs), with effectiveness of the internal transfer of electrons. O₂˙⁻ was identified for the reductive dechlorination of CAP, with simultaneously detection of both ^•OH and SO₄˙⁻ responsible for further oxidative degradation. The sulfur oxygen radical conversion reactions and molecular oxygen activation would occur together upon the carbon-based spinels. Spatial-separated interfacial reductive-oxidation of CAP would occur with dechlorination of CAP by O₂˙⁻ on the carbon bases, and oxidative degradation of intermediates by SO₄˙⁻/^•OH upon the CoFe₂O₄ catalysts.
- Cobalt ferrite spinel,
- Sulfite activation,
- Reductive dechlorination,
- Carbon supports,
- Sulfur oxygen radical reactions
1. [1]
  X. Wang, Y. Lin, Y. Zheng, F. Meng, Environ. Polluti. 293 (2022) 118541. doi: 10.1016/j.envpol.2021.118541
2. [2]
  D. Kong, B. Liang, H. Yun, et al., Water Res. 72 (2015) 281–292. doi: 10.1016/j.watres.2015.01.025
3. [3]
  J. Yu, X. Hou, X. Hu, et al., Appl. Catal. B: Environ. 256 (2019) 117876. doi: 10.1016/j.apcatb.2019.117876
4. [4]
  M. Sun, C. Chu, F. Geng, et al., Environ. Sci. Technol. Lett. 5 (2018) 186–191. doi: 10.1021/acs.estlett.8b00065
5. [5]
  U. Ushani, X. Lu, J. Wang, et al., Chem. Eng. J. 402 (2020) 126232. doi: 10.1016/j.cej.2020.126232
6. [6]
  Y. Li, W. Xiang, T. Zhou, et al., Chin. Chem. Lett. 31 (2020) 2757–2761. doi: 10.1016/j.cclet.2020.01.032
7. [7]
  P. Westerhoff, G. Aiken, G. Amy, et al., Water Res. 33 (1999) 2265–2276. doi: 10.1016/S0043-1354(98)00447-3
8. [8]
  T. Liu, Z. Xie, P. Zhou, Z, et al., Chem. Eng. J. 431 (2022) 133464. doi: 10.1016/j.cej.2021.133464
9. [9]
  Y. Yuan, Oxidative of organic compounds by Oxysulfur radicals in the presence of transition metal ions and sulfite, Université Clermont Auvergne [2017-2020]; Université de Wuhan (Chine), 2018.
10. [10]
  S. Wu, L. Shen, Y. Lin, et al., Chem. Eng. J. 414 (2021) 128872. doi: 10.1016/j.cej.2021.128872
11. [11]
  T. Liu, Y. Liu, P. Zhou, et al., J. Hazard. Mater. 440 (2022) 129809. doi: 10.1016/j.jhazmat.2022.129809
12. [12]
  W. -J. Liu, E. Kwon, N.N. Huy, et al., J. Taiwan Inst. Chem. Eng. 133 (2022) 104253. doi: 10.1016/j.jtice.2022.104253
13. [13]
  Q. Jing, H. Li, Curr. Organocatal. 7 (2020) 179–198. doi: 10.2174/2213337207999200802025735
14. [14]
  Z. Liu, S. Yang, Y. Yuan, et al., J. Hazard. Mater. 324 (2017) 583–592. doi: 10.1016/j.jhazmat.2016.11.029
15. [15]
  S. Yang, X. Qiu, P. Jin, et al., Chem. Eng. J. 353 (2018) 329–339. doi: 10.1016/j.cej.2018.07.105
16. [16]
  Y. Su, M. Lu, R. Su, et al., Chin. Chem. Lett. 33 (2022) 2573–2578. doi: 10.1016/j.cclet.2021.08.078
17. [17]
  X. Ma, P. Zhang, Y. Zhao, et al., Chem. Eng. J. 327 (2017) 1000–1010. doi: 10.1016/j.cej.2017.06.084
18. [18]
  D. Zhou, L. Chen, J. Li, et al., Chem. Eng. J. 346 (2018) 726–738. doi: 10.1016/j.cej.2018.04.016
19. [19]
  S. Zou, Q. Chen, Y. Liu, et al., Chin. Chem. Lett. 32 (2021) 2066–2072. doi: 10.1016/j.cclet.2021.02.019
20. [20]
  D. Wu, P. Ye, M. Wang, et al., J. Hazard. Mater. 352 (2018) 148–156. doi: 10.1016/j.jhazmat.2018.03.040
21. [21]
  P. Neta, R.E. Huie, Environ. Health Perspect. 64 (1985) 209–217. doi: 10.1289/ehp.8564209
22. [22]
  X. Wang, X. Pu, Y. Yuan, et al., Chin. Chem. Lett. 31 (2020) 2634–2640. doi: 10.1016/j.cclet.2020.08.007
23. [23]
  L. Yao, H. Deng, Q. -A. Huang, et al., J. Alloys Compd. 693 (2017) 929–935. doi: 10.1016/j.jallcom.2016.09.148
24. [24]
  H.Y. Hafeez, S.K. Lakhera, N. Narayanan, et al., ACS Omega 4 (2019) 880–891.
25. [25]
  J. Han, Y. Wang, C. Yu, et al., Anal. Chim. Acta. 685 (2011) 138–145. doi: 10.1016/j.aca.2010.11.033
26. [26]
  H. Ma, C. Liu, Front. Energy. 15 (2021) 621–630. doi: 10.1007/s11708-021-0761-0
27. [27]
  N.B. Velhal, N.D. Patil, A.R. Shelke, et al., AIP Adv. 5 (2015) 097166. doi: 10.1063/1.4931908
28. [28]
  S. Yadav, S. Sharma, S. Dutta, et al., Inorg. Chem. 59 (2020) 8334–8344. doi: 10.1021/acs.inorgchem.0c00752
29. [29]
  T. Muthukumaran, J. Philip, Colloids Surf. A 610 (2021) 125755.
30. [30]
  Z. Wu, Y. Wang, Z. Xiong, et al., Appl. Catal. B: Environ. 277 (2020) 119136. doi: 10.1016/j.apcatb.2020.119136
31. [31]
  M. Yang, Z. Hou, X. Zhang, et al., Environ. Sci. Technol. 56 (2022) 11635–11645. doi: 10.1021/acs.est.2c01261
32. [32]
  Y. Shang, X. Liu, Y. Li, et al., Chem. Eng. J. 446 (2022): 137120. doi: 10.1016/j.cej.2022.137120
33. [33]
  Y. Shang, X. Duan, S. Wang, et al., Chin. Chem. Lett. 33 (2022): 663–673. doi: 10.1016/j.cclet.2021.07.050
34. [34]
  M. Huang, Y. Han, W. Xiang, et al., Environ. Sci. Technol. 55 (2021) 15361–15370. doi: 10.1021/acs.est.1c03758
35. [35]
  G. Cai, L. Li, D. Li, et al., Water Res. 222 (2022) 118839. doi: 10.1016/j.watres.2022.118839
36. [36]
  L. Wang, H. Xu, N. Jiang, et al., Environ. Sci. Technol. 54 (2020) 4686–4694. doi: 10.1021/acs.est.0c00284
37. [37]
  J.G. Scandalios, Plant Physiol. 101 (1993) 7. doi: 10.1104/pp.101.1.7
38. [38]
  C. Wang, Y. Liu, T. Zhou, et al., Chin. Chem. Lett. 30 (2019) 2231–2235. doi: 10.1016/j.cclet.2019.08.055
39. [39]
  W. Xiang, M. Huang, X. Wu, et al., Chin. Chem. Lett. 33 (2022) 1275–1278. doi: 10.1016/j.cclet.2021.07.072
40. [40]
  M. Huang, W. Xiang, C. Wang, et al., Chin. Chem. Lett. 31 (2020) 2769–2773. doi: 10.1016/j.cclet.2020.06.040
41. [41]
  W. Xiang, M. Huang, Y. Wang, et al., Chin. Chem. Lett. 31 (2020) 2831–2834. doi: 10.1016/j.cclet.2020.08.006
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