Citation: Shuangxi Li, Huijun Yu, Tianwei Lan, Liyi Shi, Danhong Cheng, Lupeng Han, Dengsong Zhang. NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites[J]. Chinese Chemical Letters, ;2024, 35(5): 108240. doi: 10.1016/j.cclet.2023.108240 shu

NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites

State Key Laboratory of Advanced Special Steel, School of Materials Science and Engineering, International Joint Laboratory of Catalytic Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China

lphan@shu.edu.cn

dszhang@shu.edu.cn

Received Date: 7 December 2022
Revised Date: 11 January 2023
Accepted Date: 4 February 2023
Available Online: 23 February 2023

Figures(5)

Commercial V₂O₅-based catalysts have been successfully applied in NH₃ selective catalytic reduction (NH₃-SCR) of NO_x from power stations, but their poor alkali-resistance restrains the wider application in nonelectrical industries. In this study, NO_x reduction against alkali poisoning over V₂O₅/TiO₂ is greatly improved via Ce(SO₄)₂ modification. It has been originally demonstrated that Ce⁴⁺–SO₄²⁻ pair sites play crucial roles in improving NO_x reduction against alkali poisoning over V₂O₅/TiO₂ catalysts. The strong interaction between V species and Ce sites of Ce⁴⁺–SO₄²⁻ pairs triggers the reaction between NH₄⁺species and gaseous NO via Eley-Rideal (E-R) reaction pathway. After K-poisoning, the SO₄²⁻ sites of Ce⁴⁺–SO₄²⁻ pairs as protective sites strongly bond with K and thus maintain the high reaction efficiency via the E-R reaction pathway. This work demonstrates an effective strategy to enhance NO_x reduction against alkali poisoning over catalysts via constructing Ce⁴⁺–SO₄²⁻ pair sites, contributing to developing alkali-resistant SCR catalysts for practical application in nonelectrical industries.
- Air pollution control,
- Selective catalytic reduction,
- NO_x reduction,
- Alkali poisoning,
- Ce(SO₄)₂
1. [1]
  A. Richter, J.P. Burrows, H. Nüß, C. Granier, U. Niemeier, Nature 437 (2005) 129–132. doi: 10.1038/nature04092
2. [2]
  C. Paolucci, I. Khurana, A.P. Atish, et al., Science 357 (2017) 898–903. doi: 10.1126/science.aan5630
3. [3]
  H.K. Chang, G. Qi, K. Dahlberg, W. Li, Science 327 (2010) 1624–1627. doi: 10.1126/science.1184087
4. [4]
  C. Paolucci, A.A. Verma, S.A. Bates, et al., Angew. Chem., Int. Ed. 53 (2014) 11828–11833. doi: 10.1002/anie.201407030
5. [5]
  G. He, Z. Lian, Y. Yu, et al., Sci. Adv. 4 (2018) eaau4637. doi: 10.1126/sciadv.aau4637
6. [6]
  Z. Si, Y. Shen, J. He, et al., Environ. Sci. Technol. 56 (2022) 605–613. doi: 10.1021/acs.est.1c05686
7. [7]
  L. Han, S. Cai, M. Gao, et al., Chem. Rev. 119 (2019) 10916–10976. doi: 10.1021/acs.chemrev.9b00202
8. [8]
  Y. Zhao, L. Shi, Y. Shen, et al., Environ. Sci. Technol. 56 (2022) 4386–4395. doi: 10.1021/acs.est.1c07996
9. [9]
  G. Zhou, P. Maitarad, P. Wang, et al., Environ. Sci. Technol. 54 (2020) 13314–13321. doi: 10.1021/acs.est.0c04536
10. [10]
  L. Yan, Y. Ji, P. Wang, et al., Environ. Sci. Technol. 54 (2020) 9132–9141. doi: 10.1021/acs.est.0c03290
11. [11]
  S.S.R. Putluru, S.B. Kristensen, J. Due-Hansen, A. Riisager, R. Fehrmann, Catal. Today 184 (2012) 192–196. doi: 10.1016/j.cattod.2011.10.012
12. [12]
  S. Gao, P. Wang, X. Chen, et al., Catal. Commun. 43 (2014) 223–226. doi: 10.1016/j.catcom.2013.10.017
13. [13]
  J. Due-Hansen, S. Boghosian, A. Kustov, et al., J. Catal. 251 (2007) 459–473. doi: 10.1016/j.jcat.2007.07.016
14. [14]
  P. Wang, H. Wang, X. Chen, Z. Wu, ChemCatChem 8 (2016) 787–797. doi: 10.1002/cctc.201501064
15. [15]
  P. Wang, S. Gao, H. Wang, et al., Appl. Catal. B 561 (2018) 68–77. doi: 10.1016/j.apcata.2018.05.023
16. [16]
  P. Wang, S. Chen, S. Gao, et al., Appl. Catal. B 231 (2018) 299–309. doi: 10.1016/j.apcatb.2018.03.024
17. [17]
  P. Zhang, P. Wang, A. Chen, et al., Environ. Sci. Technol. 55 (2021) 11970–11978. doi: 10.1021/acs.est.1c02882
18. [18]
  Y. Li, S. Cai, P. Wang, et al., Environ. Sci. Technol. 55 (2021) 9276–9284. doi: 10.1021/acs.est.1c01722
19. [19]
  C. Feng, P. Wang, X. Liu, et al., Environ. Sci. Technol. 55 (2021) 11255–11264. doi: 10.1021/acs.est.1c02061
20. [20]
  L. Kang, L. Han, J. He, et al., Environ. Sci. Technol. 53 (2019) 938–945. doi: 10.1021/acs.est.8b05637
21. [21]
  Z. Chen, S. Ren, M. Wang, et al., Fuel 321 (2022) 124113. doi: 10.1016/j.fuel.2022.124113
22. [22]
  H. Zhou, T. Cheng, B. Du, et al., Environ. Sci. Pollut. Res. 29 (2022) 84421–84433. doi: 10.1007/s11356-022-21748-z
23. [23]
  L. Wang, J. Zhao, S. Bai, H. Zhao, Z. Zhu, Chem. Eng. J. 254 (2014) 399–409. doi: 10.1016/j.cej.2014.05.096
24. [24]
  L. Han, M. Gao, J.Y. Hasegawa, et al., Environ. Sci. Technol. 53 (2019) 6462–6473. doi: 10.1021/acs.est.9b00435
25. [25]
  L. Kang, L. Han, P. Wang, et al., Environ. Sci. Technol. 54 (2020) 14066–14075. doi: 10.1021/acs.est.0c05038
26. [26]
  Z. Chen, S. Ren, X. Xing, et al., Fuel 335 (2022) 126986.
27. [27]
  Z. Chen, S. Ren, M. Wang, Mol. Catal. 531 (2022) 112693. doi: 10.1016/j.mcat.2022.112693
28. [28]
  L. Han, M. Gao, C. Feng, L. Shi, D. Zhang, Environ. Sci. Technol. 53 (2019) 5946–5956. doi: 10.1021/acs.est.9b01217
29. [29]
  Z. Liu, H. Su, B. Chen, J. Li, S.I. Woo, Chem. Eng. J. 299 (2016) 255–262. doi: 10.1016/j.cej.2016.04.100
30. [30]
  Z. Wu, R. Jin, Y. Liu, H. Wang, Catal. Commun. 9 (2008) 2217–2220. doi: 10.1016/j.catcom.2008.05.001
31. [31]
  Z. Chen, R. Guo, S. Ren, et al., J. Mater. Chem. A 10 (2022) 21474. doi: 10.1039/d2ta06199f
32. [32]
  K. Wang, Z. Gong, H. Luo, et al., Combust. Sci. Technol. 190 (2018) 770–783. doi: 10.1080/00102202.2017.1408598
33. [33]
  Y. Zhang, X. Yue, T. Huang, K. Shen, B. Lu, Materials 11 (2018) 1307. doi: 10.3390/ma11081307
34. [34]
  Q. Zhang, J. Fan, P. Ning, et al., Appl. Surf. Sci. 435 (2018) 1037–1045. doi: 10.1016/j.apsusc.2017.11.180
35. [35]
  J. Liu, J. Meeprasert, S. Namuangruk, et al., J. Phys. Chem. C 121 (2017) 4970–4979. doi: 10.1021/acs.jpcc.6b11175
36. [36]
  L. Chen, Z. Si, X. Wu, D. Weng, ACS Appl. Mater. Interfaces 6 (2014) 8134–8145. doi: 10.1021/am5004969
37. [37]
  Y. Yu, J. Wang, J. Chen, et al., Ind. Eng. Chem. Res. 53 (2014) 16229–16234. doi: 10.1021/ie502065b
38. [38]
  L. Huang, K. Zha, S. Namuangruk, et al., Catal. Sci. Technol. 6 (2016) 8516–8524. doi: 10.1039/C6CY02026G
39. [39]
  J. Liu, X. Li, Q. Zhao, et al., Appl. Catal. B 200 (2017) 297–308.
40. [40]
  Q. Zhang, H. Wang, P. Ning, et al., Appl. Surf. Sci. 419 (2017) 733–743. doi: 10.1016/j.apsusc.2017.05.056
41. [41]
  J. Wang, Z. Yan, L. Liu, et al., Appl. Surf. Sci. 313 (2014) 660–669. doi: 10.1016/j.apsusc.2014.06.043
42. [42]
  A. Davydov, Molecular Spectroscopy of Oxide Catalyst Surfaces, John Wiley & Sons Ltd., 2003, Chapter 2, p. 124.
43. [43]
  Z. Liu, S. Zhang, J. Li, L. Ma, Appl. Catal. B 144 (2014) 90–95. doi: 10.1016/j.apcatb.2013.06.036
44. [44]
  N. Liu, J. Wang, F. Wang, J. Liu, J. Rare Earths 36 (2018) 594–602. doi: 10.1016/j.jre.2017.12.009
45. [45]
  H. Hu, S. Cai, H. Li, et al., J. Phys. Chem. C 119 (2015) 22924–22933. doi: 10.1021/acs.jpcc.5b06057
46. [46]
  C. Yu, L. Wang, B. Huang, Aerosol Air Qual. Res. 15 (2015) 1017–1027. doi: 10.4209/aaqr.2014.08.0162
47. [47]
  X. Weng, X. Dai, Q. Zeng, Y. Liu, Z. Wu, J. Colloid Interface Sci. 461 (2016) 9–14. doi: 10.1016/j.jcis.2015.09.004
48. [48]
  S. Wang, R. Guo, W. Pan, et al., Catal. Commun. 89 (2017) 143–147. doi: 10.1016/j.catcom.2016.11.005
49. [49]
  K. Liu, F. Liu, L. Xie, W. Shan, H. He, Catal. Sci. Technol. 5 (2015) 2290–2299. doi: 10.1039/C4CY01550A
1. [1]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
2. [2]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
3. [3]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
4. [4]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
5. [5]
  Feibin Wei , Yongfang Rao , Yu Huang , Wei Wang , Hui Mei . The new challenges for the development of NH₃-SCR catalysts under new situation of energy transition in power generation industry. Chinese Chemical Letters, 2024, 35(6): 108931-. doi: 10.1016/j.cclet.2023.108931
6. [6]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
7. [7]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
8. [8]
  Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM₂@g-C₉N₄ electrocatalysts for enhanced CO reduction toward C₂ products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
9. [9]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
10. [10]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
11. [11]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
12. [12]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
13. [13]
  Chaozheng He , Jia Wang , Ling Fu , Wei Wei . Nitric oxide assists nitrogen reduction reaction on 2D MBene: A theoretical study. Chinese Chemical Letters, 2024, 35(5): 109037-. doi: 10.1016/j.cclet.2023.109037
14. [14]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
15. [15]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
16. [16]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
17. [17]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
18. [18]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
19. [19]
  Tinghui Yang , Min Kuang , Jianping Yang . Mesoporous CuCe dual-metal catalysts for efficient electrochemical reduction of CO2 to methane. Chinese Journal of Structural Chemistry, 2024, 43(8): 100350-100350. doi: 10.1016/j.cjsc.2024.100350
20. [20]
  Di Wang , Qing-Song Chen , Yi-Ran Lin , Yun-Xin Hou , Wei Han , Juan Yang , Xin Li , Zhen-Hai Wen . Tuning strategies and electrolyzer design for Bi-based nanomaterials towards efficient CO2 reduction to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(8): 100346-100346. doi: 10.1016/j.cjsc.2024.100346

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(105)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

NOx reduction against alkali poisoning over Ce(SO4)2-V2O5/TiO2 catalysts by constructing the Ce4+–SO42− pair sites

Metrics

通讯作者: 陈斌, bchen63@163.com

NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites