Citation: Jiaying Wang, Jiejie Wang, Sijin Zuo, Jianchuan Pei, Weiping Liu, Juan Wang. Cooperative coupling of photocatalytic production of H₂O₂ and oxidation of organic pollutants over gadolinium ion doped WO₃ nanocomposite[J]. Chinese Chemical Letters, ;2023, 34(9): 108157. doi: 10.1016/j.cclet.2023.108157 shu

Cooperative coupling of photocatalytic production of H₂O₂ and oxidation of organic pollutants over gadolinium ion doped WO₃ nanocomposite

Jiaying Wang ^{a, 1} ,
Jiejie Wang ^{b, 1} ,
Sijin Zuo ^a ,
Jianchuan Pei ^{b, *,} ,
Weiping Liu ^a ,
Juan Wang ^{a, *,}

a.
Institute of Environmental Health, MOE Key Laboratory of Environmental Remediation and Ecosystem Health, College of Environment and Resources Science, Zhejiang University, Hangzhou 310058, China
b.
College of Environment and Resources, Zhejiang A&F University, Hangzhou 311300, China

147927078@qq.com

wjuan@zju.edu.cn

Received Date: 11 September 2022
Revised Date: 7 January 2023
Accepted Date: 19 January 2023
Available Online: 22 January 2023

Figures(5)

This work reported the lanthanide ion (Gd³⁺) doped tungsten trioxide (Gd-WO₃) nanocrystal for remarkable promoted photocatalytic degradation of organic pollutants and simultaneous in-situ H₂O₂ production. With doped lanthanide ion (Gd³⁺), Gd-WO₃ showed a much broad and enhanced solar light absorption, which not only promoted the photocatalytic degradation efficiency of organic compounds, but also provided a suitable bandgap for direct reduction of oxygen to H₂O₂. Additionally, the isolated Gd³⁺ on WO₃ surface can efficiently weaken the *OOH binding energy, increasing the activity and selectivity of direct reduction of oxygen to H₂O₂, with a rate of 0.58 mmol L⁻¹ g⁻¹ h⁻¹. The in-situ generated H₂O₂ can be subsequently converted to ^•OH based on Fenton reaction, further contributed to the overall removal of organic pollutants. Our results demonstrate a cascade photocatalytic oxidation-Fenton reaction which can efficiently utilize photo-generated electrons and holes for organic pollutants treatment.
- Lanthanide ion,
- Photocatalytic oxidation,
- Photocatalytic generation of H₂O₂ in situ,
- Cascade reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

Cooperative coupling of photocatalytic production of H2O2 and oxidation of organic pollutants over gadolinium ion doped WO3 nanocomposite

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通讯作者: 陈斌, bchen63@163.com

Cooperative coupling of photocatalytic production of H₂O₂ and oxidation of organic pollutants over gadolinium ion doped WO₃ nanocomposite