Citation: Aadil Nabi Chishti, Zhiyuan Ma, Junjie Zha, Muhammad Ahmad, Peisen Wang, Jagadis Gautam, Ming Chen, Lubin Ni, Guowang Diao. Preparation of novel magnetic noble metals supramolecular composite for the reduction of organic dyes and nitro aromatics[J]. Chinese Chemical Letters, ;2023, 34(8): 108122. doi: 10.1016/j.cclet.2022.108122 shu

Preparation of novel magnetic noble metals supramolecular composite for the reduction of organic dyes and nitro aromatics

Aadil Nabi Chishti ^a ,
Zhiyuan Ma ^a ,
Junjie Zha ^a ,
Muhammad Ahmad ^{a, b} ,
Peisen Wang ^a ,
Jagadis Gautam ^a ,
Ming Chen ^a ,
Lubin Ni ^{a, *,} ,
Guowang Diao ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
b.
College of Environmental Science and Engineering, Yangzhou University, Yangzhou 225002, China

lbni@yzu.edu.cn

gwdiao@yzu.edu.cn

Received Date: 27 July 2022
Revised Date: 21 December 2022
Accepted Date: 27 December 2022
Available Online: 28 December 2022

Figures(11)

By considering the exceptional properties of supramolecular, noble metals (NM) and magnetic nanoparticles (NPs), we successfully synthesized a novel magnetic, metals and supramolecular composite. Briefly, the Fe₃O₄@SiO₂ core-shell spheres were first modified with gold (Au) and palladium (Pd) NPs and then with mono-6-thio-β-cyclodextrin (SH-β-CD). The synthesized Fe₃O₄@SiO₂-Au-Pd@SH-β-CD nanocomposite shows a good magnetic response (42.3 emu/g). The nanocomposite showed good performance for the reductive degradation of rhodamine B (RhB) and 4-nitrophenol (4-NP). The calculated rate constant (k) values for the reduction of 4-NP and RhB were 0.062± 0.02 s⁻¹ and 0.027± 0.01 s^−1, respectively. The high catalytical performance was supposed to be due to the host-guest interaction of β-CD and also due to the NM synergic effect. The nanocomposite structural and chemical morphology was investigated by various spectroscopic techniques. Furthermore, the catalyst was recycled six times and it maintains morphology, chemical nature, and high magnetic behavior, as demonstrated by FTIR and TEM analysis of the recycled catalyst. These results demonstrate a very efficient, cost-effective, and recyclable catalyst in the field of catalysis technology development.
- Fe₃O4@SiO₂-Au-Pd@SH-β-CD composite,
- Catalysis,
- Reduction,
- Degradation,
- Synergistic effect
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