Citation: Weikang Hu, Ming Yang, Qingyun Yan, Jiahui Ji, Yan Bao, Jinlong Zhang, Mingyang Xing. Defect electrons accelerate iron cycle of novel Fe-based Fenton: Long-term effective quinoline degradation[J]. Chinese Chemical Letters, ;2023, 34(6): 108109. doi: 10.1016/j.cclet.2022.108109 shu

Defect electrons accelerate iron cycle of novel Fe-based Fenton: Long-term effective quinoline degradation

Weikang Hu ^a ,
Ming Yang ^a ,
Qingyun Yan ^a ,
Jiahui Ji ^a ,
Yan Bao ^a ,
Jinlong Zhang ^{a, b} ,
Mingyang Xing ^{a, b, *,}

a.
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Shanghai Engineering Research Center for Multi-media Environmental Catalysis and Resource Utilization, East China University of Science and Technology, Shanghai 200237, China

mingyangxing@ecust.edu.cn

Received Date: 26 September 2022
Revised Date: 4 December 2022
Accepted Date: 27 December 2022
Available Online: 12 April 2023

Figures(4)

Heterogeneous Fenton has been widely used in the disposal of organic pollutants, however, slow regeneration of Fe(Ⅱ) remains limitation for its practical application of long-term treatment. Herein, we come up with a novel Fe-based heterogeneous Fenton catalyst named as FeS_xO_y-X (X is the ratio of ethylene glycol to N, N-dimethylformamide). With the help of the abundant defect electrons in Sulfur vacancies, Fe(Ⅱ) regeneration on the surface of FeS_xO_y-1:1 was accelerated, resulting in a stable proportion of Fe(Ⅱ) on the surface, which maintained continuously stable generation of hydroxyl radical (^•OH) and singlet oxygen (¹O₂). Thus, without any organic reagents or cocatalysts, FeS_xO_y-1:1 based Fenton system achieved effective long-term degradation of 560 mg/L quinoline within only 7 days, which was evidently better than reported FeS and SV-FeS₂ (SV: Sulfur vacancy). The system had excellent adaptability to water quality and the COD removal rate of biochemical wastewater was as high as 79.8%.
- Fenton reaction,
- Quinoline,
- Defect electron,
- Iron cycle,
- Heterogeneous catalyst
1. [1]
  Q. Bai, L. Yang, R. Li, et al., Environ. Sci. Technol. 49 (2015) 11536–11542. doi: 10.1021/acs.est.5b03293
2. [2]
  A. Mermer, T. Keles, Y. Sirin, Bioorg. Chem. 114 (2021) 105076. doi: 10.1016/j.bioorg.2021.105076
3. [3]
  D. Hu, C. Pi, W. Hu, et al., Chin. Chem. Lett. 33 (2022) 4064–4068. doi: 10.1016/j.cclet.2021.12.072
4. [4]
  K.V. Padoley, S.N. Mudliar, R.A. Pandey, Bioresour. Technol. 99 (2008) 4029–4043. doi: 10.1016/j.biortech.2007.01.047
5. [5]
  S. Zhu, X. Yang, W. Yang, et al., Int. J. Environ. Res. Public Health 9 (2012) 548–563. doi: 10.3390/ijerph9020548
6. [6]
  H. Zheng, Y. Hou, S. Li, et al., Chin. Chem. Lett. 33 (2022) 5103-5022.
7. [7]
  A.N. Soon, B.H. Hameed, Desalination 269 (2011) 1–16. doi: 10.1016/j.desal.2010.11.002
8. [8]
  C. Lai, X. Shi, L. Li, et al., Sci. Total Environ. 775 (2021) 145850. doi: 10.1016/j.scitotenv.2021.145850
9. [9]
  N. Thomas, D.D. Dionysiou, S.C. Pillai, J. Hazard. Mater. 404 (2021) 124082. doi: 10.1016/j.jhazmat.2020.124082
10. [10]
  K. Li, Y. Liang, H. Yang, et al., Catal. Today 371 (2021) 58–63. doi: 10.1016/j.cattod.2020.07.026
11. [11]
  W.P. Ting, M.C. Lu, Y.H. Huang, J. Hazard. Mater. 156 (2008) 421–427. doi: 10.1016/j.jhazmat.2007.12.031
12. [12]
  T. Li, P. Zhu, D. Wang, Z. Zhang, L. Zhou, Environ. Res. 209 (2022) 112830. doi: 10.1016/j.envres.2022.112830
13. [13]
  P. Zhou, W. Ren, G. Nie, et al., Angew. Chem. Int. Ed. 59 (2020) 16517–16526. doi: 10.1002/anie.202007046
14. [14]
  W. Ren, P. Zhou, G. Nie, et al., Water Res. 186 (2020) 116361. doi: 10.1016/j.watres.2020.116361
15. [15]
  Y. Deng, P. Gao, L. Wang, et al., J. Environ. Chem. Eng. 10 (2022) 107481. doi: 10.1016/j.jece.2022.107481
16. [16]
  G. Zhang, X. Yuan, B. Xie, et al., Chem. Eng. J. 433 (2022) 133670. doi: 10.1016/j.cej.2021.133670
17. [17]
  L. Cai, J. He, Q. Liu, et al., J. Am. Chem. Soc. 137 (2015) 2622–2627. doi: 10.1021/ja5120908
18. [18]
  Q. Yan, C. Lian, K. Huang, et al., Angew. Chem. Int. Ed. 60 (2021) 17155–17163. doi: 10.1002/anie.202105736
19. [19]
  W. Xu, W. Xue, H. Huang, et al., Appl. Catal. B: Environ. 291 (2021) 120129. doi: 10.1016/j.apcatb.2021.120129
20. [20]
  M.V. Morales-Gallardo, A.M. Ayala, M. Pal, et al., Chem. Phys. Lett. 660 (2016) 93–98. doi: 10.1016/j.cplett.2016.07.046
21. [21]
  F. Yu, Y. Wang, H. Ma, M. Zhou, Sep. Purif. Technol. 248 (2020) 117022. doi: 10.1016/j.seppur.2020.117022
22. [22]
  R. Canton-Vitoria, Y. Sayed-Ahmad-Baraza, M. Pelaez-Fernandez, et al., npj 2D Mater. Appl. 1 (2017) 13. doi: 10.1038/s41699-017-0012-8
23. [23]
  M. Xiao, R. Li, J. Yin, et al., Colloids Surf. A Physicochem. Eng. Asp. 651 (2022) 129678. doi: 10.1016/j.colsurfa.2022.129678
24. [24]
  E. Neyens, J. Baeyens, J. Hazard. Mater. 98 (2003) 33–50. doi: 10.1016/S0304-3894(02)00282-0
25. [25]
  Q. Yi, J. Ji, B. Shen, et al., Environ. Sci. Technol. 53 (2019) 9725–9733. doi: 10.1021/acs.est.9b01676
26. [26]
  Y. Yang, L. Xu, J. Wang, Chem. Eng. J. 425 (2021) 131497. doi: 10.1016/j.cej.2021.131497
27. [27]
  Z. Yang, J. Qian, A. Yu, B. Pan, Proc. Natl. Acad. Sci. U. S. A. 116 (2019) 6659–6664. doi: 10.1073/pnas.1819382116
28. [28]
  Z. Jiao, X. Zhang, H. Gong, et al., J. Ind. Eng. Chem. 105 (2022) 49–57. doi: 10.1016/j.jiec.2021.10.006
29. [29]
  X. Lai, X.A. Ning, Y. Zhang, et al., Environ. Res. 197 (2021) 110997. doi: 10.1016/j.envres.2021.110997
30. [30]
  R.C.P. Richard, B. Wilhelmy, E. Maijevic, Inorg. Chem. 24 (1985) 3290–3297. doi: 10.1021/ic00214a039
31. [31]
  D. Cheng, A. Neumann, S. Yuan, W. Liao, A. Qian, Environ. Sci. Technol. 54 (2020) 4091–4101. doi: 10.1021/acs.est.9b07012
32. [32]
  C.C. Ling, X.F. Liu, M.Q. Li, et al., Appl. Catal. B: Environ. 290 (2021) 120051. doi: 10.1016/j.apcatb.2021.120051
33. [33]
  J. Huang, A. Jones, T.D. Waite, et al., Chem. Rev. 121 (2021) 8161–8233. doi: 10.1021/acs.chemrev.0c01286
34. [34]
  P. Zhou, Y. Yang, W. Ren, et al., Appl. Catal. B: Environ. 319 (2022) 121916. doi: 10.1016/j.apcatb.2022.121916
1. [1]
  Jia-Cheng Hou , Hong-Tao Ji , Yu-Han Lu , Jia-Sheng Wang , Yao-Dan Xu , Yan-Yan Zeng , Wei-Min He . Sustainable and practical semi-heterogeneous photosynthesis of 5-amino-1,2,4-thiadiazoles over WS₂/TEMPO. Chinese Chemical Letters, 2024, 35(8): 109514-. doi: 10.1016/j.cclet.2024.109514
2. [2]
  Yiyue Ding , Qiuxiang Zhang , Lei Zhang , Qilu Yao , Gang Feng , Zhang-Hui Lu . Exceptional activity of amino-modified rGO-immobilized PdAu nanoclusters for visible light-promoted dehydrogenation of formic acid. Chinese Chemical Letters, 2024, 35(7): 109593-. doi: 10.1016/j.cclet.2024.109593
3. [3]
  Weichen Zhu , Wei Zuo , Pu Wang , Wei Zhan , Jun Zhang , Lipin Li , Yu Tian , Hong Qi , Rui Huang . Fe-N-C heterogeneous Fenton-like catalyst for the degradation of tetracycline: Fe-N coordination and mechanism studies. Chinese Chemical Letters, 2024, 35(9): 109341-. doi: 10.1016/j.cclet.2023.109341
4. [4]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
5. [5]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
6. [6]
  Shiyu Pan , Bo Cao , Deling Yuan , Tifeng Jiao , Qingrui Zhang , Shoufeng Tang . Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation. Chinese Chemical Letters, 2024, 35(7): 109185-. doi: 10.1016/j.cclet.2023.109185
7. [7]
  Kuan Deng , Fei Yang , Zhi-Qi Cheng , Bi-Wen Ren , Hua Liu , Jiao Chen , Meng-Yao She , Le Yu , Xiao-Gang Liu , Hai-Tao Feng , Jian-Li Li . Construction of wavelength-tunable DSE quinoline salt derivatives by regulating the hybridization form of the nitrogen atom and intramolecular torsion angle. Chinese Chemical Letters, 2024, 35(10): 109464-. doi: 10.1016/j.cclet.2023.109464
8. [8]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
9. [9]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
10. [10]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
11. [11]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
12. [12]
  Chi Zhang , Ning Ding , Yuwei Pan , Lichun Fu , Ying Zhang . The degradation pathways of contaminants by reactive oxygen species generated in the Fenton/Fenton-like systems. Chinese Chemical Letters, 2024, 35(10): 109579-. doi: 10.1016/j.cclet.2024.109579
13. [13]
  Shengkai Li , Yuqin Zou , Chen Chen , Shuangyin Wang , Zhao-Qing Liu . Defect engineered electrocatalysts for C–N coupling reactions toward urea synthesis. Chinese Chemical Letters, 2024, 35(8): 109147-. doi: 10.1016/j.cclet.2023.109147
14. [14]
  Zhongsen Wang , Lijun Qiu , Yunhua Huang , Meng Zhang , Xi Cai , Fanyu Wang , Yang Lin , Yanbiao Shi , Xiao Liu . Alcohothermal synthesis of sulfidated zero-valent iron for enhanced Cr(Ⅵ) removal. Chinese Chemical Letters, 2024, 35(7): 109195-. doi: 10.1016/j.cclet.2023.109195
15. [15]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
16. [16]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
17. [17]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
18. [18]
  Heng Yang , Zhijie Zhou , Conghui Tang , Feng Chen . Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds. Chinese Chemical Letters, 2024, 35(6): 109257-. doi: 10.1016/j.cclet.2023.109257
19. [19]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
20. [20]
  Xing Tian , Di Wu , Wanheng Wei , Guifu Dai , Zhanxian Li , Benhua Wang , Mingming Yu . A lipid droplets-targetable fluorescent probe for polarity detection in cells of iron death, inflammation and fatty liver tissue. Chinese Chemical Letters, 2024, 35(6): 108912-. doi: 10.1016/j.cclet.2023.108912

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(592)
HTML views(18)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142