Citation: Liangru Yang, Yixin Li, Haifan Zhang, Changming Tian, Qiaohong Cao, Yongmei Xiao, Libo Yuan, Guoxing Liu. Photoisomerization, assembling and fluorescence photoswitching behaviors of a water-soluble stiff-stilbene with cucurbit[7]uril[J]. Chinese Chemical Letters, ;2023, 34(8): 108108. doi: 10.1016/j.cclet.2022.108108 shu

Photoisomerization, assembling and fluorescence photoswitching behaviors of a water-soluble stiff-stilbene with cucurbit[7]uril

Liangru Yang ^{a, *,} ,
Yixin Li ^a ,
Haifan Zhang ^a ,
Changming Tian ^b ,
Qiaohong Cao ^a ,
Yongmei Xiao ^a ,
Libo Yuan ^{a, *,} ,
Guoxing Liu ^{a, b, *,}

a.
College of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China
b.
College of Science, Henan Agricultural University, Zhengzhou 450002, China

lryang2003@aliyun.com

lbyuan@haut.edu.cn

gxliu@henau.edu.cn

Received Date: 24 September 2022
Revised Date: 20 December 2022
Accepted Date: 25 December 2022
Available Online: 26 December 2022

Figures(6)

Photoresponsive supramolecular systems have merited extensive attention for their applications in materials science and life science. Here, we synthesized a water-soluble stiff-stilbene molecular photoswitch, exhibiting outstanding photoisomerization reaction between its (E)- and (Z)-configurations upon irradiation at distinct light. The photoswitch can assemble with cucurbit[7]uril (CB[7]) to form a superior fluorescent supramolecular complex (compared to the only guest) with excellent water solubility, which manifested dramatic photoluminescence enhancement caused by restriction of intramolecular rotation and remained good photochromic characteristics. Furthermore, introduction of CB[7] influence photoreaction quantum yield (Φ) of the stiff-stilbene, leading to reduction of Φ_E→Z and increase of Φ_Z→E of the stiff-stilbene. Importantly, the photoadjustable supramolecular assembly can act as a fluorescence switch, and the phototunable guest further selectively modulate G-quadruplex structure of Tel22 upon light irradiation or with addition of CB[7]. The study provides a new simple way for accurately regulating photochromic properties of molecular switches and developing smart materials with potential applications in controlled modulation of G-quadruplex, targeted biological imaging and so on.
- Supramolecular assemble,
- Photoreponse,
- Stiff-stilbene,
- Cucurbit[7]uril,
- Fluorescence photoswitch,
- Host-guest complexation
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