Citation: Jin Liu, Zi-Xiu Lu, Fa-Fa Wu, Guo-Ling Li, Bin Wang, Xue-Li Cao, Wei Wang, Zhu Zhuo, Qiao-Hong Li, You-Gui Huang. A chiral SrSi₂ (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity[J]. Chinese Chemical Letters, ;2023, 34(9): 108100. doi: 10.1016/j.cclet.2022.108100 shu

A chiral SrSi₂ (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity

Jin Liu ^{a, b, c} ,
Zi-Xiu Lu ^{a, c} ,
Fa-Fa Wu ^d ,
Guo-Ling Li ^{a, c} ,
Bin Wang ^{a, c} ,
Xue-Li Cao ^{a, c} ,
Wei Wang ^{a, c} ,
Zhu Zhuo ^{a, c} ,
Qiao-Hong Li ^{d, *,} ,
You-Gui Huang ^{a, c, e, *,}

a.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen 361021, China
d.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
e.
Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou 350108, China

lqh2382@fjirsm.ac.cn

yghuang@fjirsm.ac.cn

Received Date: 7 November 2022
Revised Date: 4 December 2022
Accepted Date: 22 December 2022
Available Online: 24 December 2022

Figures(4)

Most porous conductive frameworks are highly anisotropic in their structures thus leading to anisotropic charge transport. Here we report a supramolecular self-assembly which is constructed by intermolecular hydrogen bonding and π···π interactions. This material features a chiral, porous, cubic framework structure with π-stacked helical columns along all of the three Cartesian coordinates. As a result, isotropic charge transport with an electrical conductivity (σ) of 2.1 × 10^–7 S/cm is achieved. By achieving isotropic charge transport in a π-stacked supramolecular assembly, these results provide a new type of isotropic conductive framework materials alternative to conductive metal-organic frameworks (MOFs).
- Electrical conductivity,
- Self-assembly,
- Isotropic,
- π···π Interactions,
- Chiral
1. [1]
  M.L. Aubrey, M.T. Kapelewski, J.F. Melville, et al., J. Am. Chem. Soc. 141 (2019) 5005–5013. doi: 10.1021/jacs.9b00654
2. [2]
  S. Zhang, X.B. Pei, W. Fan, J.Y. Xiong, J. Wang, Chin. Chem. Lett. 31 (2020) 1060–1070. doi: 10.1016/j.cclet.2019.11.036
3. [3]
  I. Stassen, J.H. Dou, C. Hendon, M. Dincă, ACS Cent. Sci. 5 (2019) 1425–1431. doi: 10.1021/acscentsci.9b00482
4. [4]
  L. Sun, M.G. Campbell, M. Dincă, Angew. Chem. Int. Ed. 55 (2016) 3566–3579. doi: 10.1002/anie.201506219
5. [5]
  D.W. Feng, T. Lei, M.R. Lukatskaya, et al., Nat. Energy 3 (2018) 30–36. doi: 10.1038/s41560-017-0044-5
6. [6]
  J.W. Liu, C.Y. Chen, K. Zhang, L. Zhang, Chin. Chem. Lett. 32 (2021) 649–659. doi: 10.1016/j.cclet.2020.07.040
7. [7]
  K.W. Nam, S.S. Park, R. Reis, et al., Nat. Commun. 10 (2019) 4948. doi: 10.1038/s41467-019-12857-4
8. [8]
  Z. Meng, A. Aykanat, K.A. Mirica, J. Am. Chem. Soc. 141 (2019) 2046–2053. doi: 10.1021/jacs.8b11257
9. [9]
  D. Sheberla, J.C. Bachman, J.S. Elias, et al., Nat. Mater. 16 (2017) 220–224. doi: 10.1038/nmat4766
10. [10]
  X.J. Li, Q. Hu, H.P. Yang, et al., Chin. Chem. Lett. 33 (2022) 3657–3671. doi: 10.1016/j.cclet.2021.12.001
11. [11]
  X.B. Liu, T. Yue, K. Qi, et al., Chin. Chem. Lett. 31 (2020) 2189–2201. doi: 10.1016/j.cclet.2019.12.009
12. [12]
  S.S. Shinde, C.H. Lee, J.Y. Jung, et al., Energy Environ. Sci. 12 (2019) 727–738. doi: 10.1039/C8EE02679C
13. [13]
  X. Huang, P. Sheng, Z. Tu, et al., Nat. Commun. 6 (2015) 7408. doi: 10.1038/ncomms8408
14. [14]
  A.A. Talin, A. Centrone, A.C. Ford, et al., Science 343 (2014) 66–69. doi: 10.1126/science.1246738
15. [15]
  T. Böttcher, I.K. Gal, R. Kolter, R. Losick, J. Clardy, J. Am. Chem. Soc. 135 (2013) 2927–2930. doi: 10.1021/ja3120955
16. [16]
  M. Hmadeh, Z. Lu, Z. Liu, et al., Chem. Mater. 24 (2012) 3511–3513. doi: 10.1021/cm301194a
17. [17]
  J.G. Park, M.L. Aubrey, J. Oktawiec, et al., J. Am. Chem. Soc. 140 (2018) 8526–8534. doi: 10.1021/jacs.8b03696
18. [18]
  G. Skorupskii, B.A. Trump, T.W. Kasel, et al., Nat. Chem. 12 (2020) 131–136. doi: 10.1038/s41557-019-0372-0
19. [19]
  X. Lin, E. Ning, X. Li, Q.W. Li, Chin. Chem. Lett. 31 (2020) 813–817. doi: 10.1016/j.cclet.2019.05.055
20. [20]
  X.Y. Song, J.J. Liu, T. Zhang, L. Chen, Sci. China Chem. 63 (2020) 1391–1401.
21. [21]
  S.S. Park, E.R. Hontz, L. Sun, et al., J. Am. Chem. Soc. 137 (2015) 1774–1777. doi: 10.1021/ja512437u
22. [22]
  L.S. Xie, S.S. Park, M.J. Chmielewski, et al., Angew. Chem. Int. Ed. 59 (2020) 19623–19626. doi: 10.1002/anie.202004697
23. [23]
  F. Solano, P. Auban-Senzier, L. Olejniczak, et al., Chem. Eur. J. (2022) e202203138.
24. [24]
  T.C. Narayan, T. Miyakai, S. Seki, M. Dincă, J. Am. Chem. Soc. 134 (2012) 12932–12935. doi: 10.1021/ja3059827
25. [25]
  L.Y. Qu, H. Iguchi, S. Takaishi, et al., J. Am. Chem. Soc. 141 (2019) 6802–6806. doi: 10.1021/jacs.9b01717
26. [26]
  L.S. Xie, E.V. Alexandrov, G. Skorupskii, D.M. Proserpio, M. Dincă, Chem. Sci. 10 (2019) 8558–8565. doi: 10.1039/C9SC03348C
27. [27]
  Y. Lu, Y.Y. Zhang, C.Y. Yang, et al., Nat. Commun. 13 (2022) 7240. doi: 10.1038/s41467-022-34820-6
28. [28]
  Y.B. Zou, T.X. Pan, Z.W. Fan, et al., Chem. Eng. J. 454 (2023) 140496. doi: 10.1016/j.cej.2022.140496
29. [29]
  J.H. Dou, M.Q. Arguilla, Y. Luo, et al., Nat. Mater. 20 (2021) 222–228. doi: 10.1038/s41563-020-00847-7
30. [30]
  M. Ko, L. Mendecki, K.A. Mirica, Chem. Commun. 54 (2018) 7873–7891. doi: 10.1039/C8CC02871K
31. [31]
  X.L. Deng, S.L. Zheng, Y.H. Zhong, et al., Coord. Chem. Rev. 450 (2022) 214235. doi: 10.1016/j.ccr.2021.214235
32. [32]
  F. Gándara, F.J. Uribe-Romo, D.K. Britt, et al., Chem. Eur. J. 18 (2012) 10595–10601. doi: 10.1002/chem.201103433
33. [33]
  G. Skorupskii, M. Dincă, J. Am. Chem. Soc. 142 (2020) 6920–6924. doi: 10.1021/jacs.0c01713
34. [34]
  J.Y. Koo, Y. Yakiyama, G.R. Lee, et al., J. Am. Chem. Soc. 138 (2016) 1776–1779. doi: 10.1021/jacs.5b12355
35. [35]
  R. Reher, H.W. Kim, C. Zhang, et al., J. Am. Chem. Soc. 142 (2020) 4114–4120. doi: 10.1021/jacs.9b13786
36. [36]
  J. Su, S. Yuan, J. Li, et al., Chem. Eur. J. 27 (2021) 622–627. doi: 10.1002/chem.202004883
37. [37]
  X.Y. Wu, H.W. Wu, S.C. Wu, et al., Chem. Commun. 58 (2022) 2702–2705. doi: 10.1039/D1CC06407J
38. [38]
  Y. Yoshida, M. Maesato, Y. Kumagai, et al., Eur. J. Inorg. Chem. 24 (2014) 3871–3878.
39. [39]
  T.C. Narayan, T. Miyakai, S. Seki, M. Dincă, J. Am. Chem. Soc. 134 (2012) 12932–12934. doi: 10.1021/ja3059827
40. [40]
  J.H. Deng, J. Luo, Y.L. Mao, et al., Sci. Adv. 6 (2020) eaax9976. doi: 10.1126/sciadv.aax9976
41. [41]
  C. Chen, Z.Y. Di, H. Li, et al., CCS Chem. 4 (2022) 1315–1325. doi: 10.31635/ccschem.021.202100910
42. [42]
  D. Meng, J.L. Yang, C. Xiao, et al., Proc. Natl. Acad. Sci. U. S. A. 117 (2020) 20397–20403. doi: 10.1073/pnas.2010733117
43. [43]
  W.B. Wang, W. Zhai, Y. Chen, Q.Y. He, H. Zhang, Sci. China Chem. 65 (2022) 497–513. doi: 10.1007/s11426-021-1150-7
44. [44]
  H.L. Zhu, H.Y. Chen, Y.X. Han, et al., J. Am. Chem. Soc. 144 (2022) 13319–13326. doi: 10.1021/jacs.2c04670
45. [45]
  Y.G. Huang, B. Mu, P.M. Schoeneck, et al., Angew. Chem. Int. Ed. 50 (2011) 436–440. doi: 10.1002/anie.201004921
46. [46]
  C. Davies, Fuel 52 (1973) 270–273. doi: 10.1016/0016-2361(73)90056-2
47. [47]
  G. Kresse, J. Furthmuller, Comp. Mater. Sci 6 (1996) 15–50. doi: 10.1016/0927-0256(96)00008-0
48. [48]
  G. Kresse, J. Furthmuller, Phys. Rev. B 54 (1996) 11169–11186. doi: 10.1103/PhysRevB.54.11169
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沈阳化工大学材料科学与工程学院沈阳 110142

A chiral SrSi2 (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity

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通讯作者: 陈斌, bchen63@163.com

A chiral SrSi₂ (srs) superstructure constructed by a dual interaction system showing isotropic electrical conductivity