Citation: Li Gao, Xia Zhong, Junnan Chen, Ying Zhang, Jie Liu, Bingsen Zhang. Optimizing the electronic structure of Fe-doped Co₃O₄ supported Ru catalyst via metal-support interaction boosting oxygen evolution reaction and hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2023, 34(9): 108085. doi: 10.1016/j.cclet.2022.108085 shu

Optimizing the electronic structure of Fe-doped Co₃O₄ supported Ru catalyst via metal-support interaction boosting oxygen evolution reaction and hydrogen evolution reaction

Li Gao ^{a, b, c, 1} ,
Xia Zhong ^{a, b, 1} ,
Junnan Chen ^{a, b} ,
Ying Zhang ^{a, d} ,
Jie Liu ^{a, e} ,
Bingsen Zhang ^{a, b, *,}

a.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
b.
School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
c.
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, China
d.
School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun 113001, China
e.
Department of Chemistry, College of Science, Northeastern University, Shenyang 110819, China

bszhang@imr.ac.cn

Received Date: 19 November 2022
Revised Date: 8 December 2022
Accepted Date: 16 December 2022
Available Online: 19 December 2022

Figures(4)

Metal-support interaction (MSI) is an efficient way in heterogeneous catalysis and electrocatalysis to modulate the electronic structure of metal for enhanced catalytic activity. However, there are still great challenges in promoting the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) simultaneously by this way. Herein, Fe-doped Co₃O₄ supported Ru (Ru/FeCo) catalysts are synthesized by MSI strategies to further improve the electrocatalytic activity and stability of the catalysts. The results show that the optimized Ru/FeCo catalyst exhibits the best catalytic performance. The HER and OER tests at 10 mA/cm² in 1 mol/L KOH solution show excellent overpotentials of 155 mV and 283 mV, respectively. The activity and stability enhancement can be attributed to the MSI that effectively modify the electronic structure and improve interfacial electron transfer between Ru and Fe-doped Co₃O₄ (FeCo). This work provides an innovative direction for the design of high-efficiency bifunctional electrocatalysts by virtue of the MSI.
- Metal-support interaction,
- Fe doping,
- Electronic structure,
- OER,
- HER
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Optimizing the electronic structure of Fe-doped Co3O4 supported Ru catalyst via metal-support interaction boosting oxygen evolution reaction and hydrogen evolution reaction

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通讯作者: 陈斌, bchen63@163.com

Optimizing the electronic structure of Fe-doped Co₃O₄ supported Ru catalyst via metal-support interaction boosting oxygen evolution reaction and hydrogen evolution reaction