Citation: Mugilan Narayanasamy, Balakrishnan Balan, Chao Yan, Subramania Angaiah. Cauliflower-like nanostructured ZnV₂S₄ as a potential cathode material to boost-up high capacity and durability of the aqueous zinc-ion battery[J]. Chinese Chemical Letters, ;2023, 34(8): 108076. doi: 10.1016/j.cclet.2022.108076 shu

Cauliflower-like nanostructured ZnV₂S₄ as a potential cathode material to boost-up high capacity and durability of the aqueous zinc-ion battery

a.
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
b.
Electro-Materials Research Laboratory, Centre for Nanoscience and Technology, Pondicherry University, Puducherry 605014, India

chaoyan@just.edu.cn

a.subramania@gmail.com

Received Date: 8 September 2022
Revised Date: 27 October 2022
Accepted Date: 14 December 2022
Available Online: 22 December 2022

Figures(8)

Owing to their unique design and development, high safety and low-cost efficient cathode is still at the forefront of research for rechargeable zinc-ion batteries. However, the suitable cathode operating with ultrahigh capacity with a dendrite-free anode reaction mechanism remains challenging. In this, the first archetype of a high-rate and morphologically stabled cathode material is constructed from novel cauliflower-like nano-ZnV₂S₄ for aqueous zinc-ion batteries. Thus, nano-ZnV₂S₄ was prepared with an anion exchange reaction using ZnV₂(OH)₈ cauliflower-like nanostructured array as a template interestingly no morphological and shape changes were detected. The as-prepared nano-ZnV₂S₄ electrode reveals a specific discharge capacity of 348.2 mAh/g during 0.5 A/g with enhanced rate capability and excellent capacity retention of 89.2% at 4 A/g current density even after completing 1000 cycles.
- Aqueous zinc-ion battery,
- Anion-exchange reaction,
- High-capacity cathode,
- Metal vanadium sulfides,
- Nano-ZnV₂S₄
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Cauliflower-like nanostructured ZnV2S4 as a potential cathode material to boost-up high capacity and durability of the aqueous zinc-ion battery

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通讯作者: 陈斌, bchen63@163.com

Cauliflower-like nanostructured ZnV₂S₄ as a potential cathode material to boost-up high capacity and durability of the aqueous zinc-ion battery