Citation: Yanan Wang, Chao Wang, Jingran Zhang, Yurong Guo, Peng Zhao, Xiaoxue Fang, Guangjiu Zhao. Ultralong room temperature phosphorescence via the charge transfer-separation-recombination mechanism based on organic small molecule doping strategy[J]. Chinese Chemical Letters, ;2023, 34(7): 108062. doi: 10.1016/j.cclet.2022.108062 shu

Ultralong room temperature phosphorescence via the charge transfer-separation-recombination mechanism based on organic small molecule doping strategy

Molecular Dynamic Chemistry Center, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Department of Chemistry, School of Science, Tianjin University, Tianjin 300354, China

gjzhao@tju.edu.cn

Received Date: 25 July 2022
Revised Date: 19 November 2022
Accepted Date: 12 December 2022
Available Online: 13 December 2022

Figures(4)

Ultra-long room temperature phosphorescence (URTP) has been increasingly recognized in pure organic luminophor in recent years. Through a simpler molecular design and charge separation-recombination pathway, organic luminophor can achieve even better URTP properties. In this work, we achieved URTP in a system of host-guest doped benzophenone derivatives whose phosphorescence is visible to the naked eye. The differences in the wavelength lifetimes of luminescent emission correspond to different photophysical mechanisms. Through a combination of theoretical calculations and experiments, the host acts as a powerful substrate that restricts the motion of the guest and inhibits the non-radiative transitions of the guest, accompanied by a charge transfer separation-recombination process between the host and the guest, resulting in an URTP phenomenon. Transient absorption results demonstrate the existence of a charge-separated state. The design strategy via charge separation is generic and easy to implement, providing a direction for the future design of doped URTP.
- Ultralong room-temperature phosphorescence,
- Charge transfer-separation-recombination,
- Organic small-molecule,
- Doped system,
- Luminescent mechanism
1. [1]
  S. Cai, H. Shi, J. Li, et al., Adv. Mater. 29 (2017) 1701244. doi: 10.1002/adma.201701244
2. [2]
  Y. Wang, H. Gao, J. Yang, et al., Adv. Mater. 33 (2021) 2007811. doi: 10.1002/adma.202007811
3. [3]
  P. Xue, P. Wang, P. Chen, et al., Chem. Sci. 8 (2017) 6060–6065. doi: 10.1039/C5SC03739E
4. [4]
  Y. Deng, D. Zhao, X. Chen, et al., Chem. Commun. 49 (2013) 5751–5753. doi: 10.1039/c3cc42600a
5. [5]
  Z. Yang, Z. Mao, X. Zhang, et al., Angew. Chem. Int. Ed. 55 (2016) 2181–2185. doi: 10.1002/anie.201509224
6. [6]
  H. Feng, J. Zeng, P. Yin, et al., Nat. Commun. 11 (2020) 2617. doi: 10.1038/s41467-020-16412-4
7. [7]
  J. Lee, H.F. Chen, T. Batagoda, et al., Nat. Mater. 15 (2016) 92–98. doi: 10.1038/nmat4446
8. [8]
  M. Kim, S.K. Jeon, S.H. Hwang, J.Y. Lee, Adv. Mater. 27 (2015) 2515–2520. doi: 10.1002/adma.201500267
9. [9]
  B. Wu, N. Guo, X. Xu, et al., Adv. Opt. Mater. 8 (2020) 2001192. doi: 10.1002/adom.202001192
10. [10]
  Z. Lin, R. Kabe, K. Wang, C. Adachi, Nat. Commun. 11 (2020) 191. doi: 10.1038/s41467-019-14035-y
11. [11]
  K. Jinnai, R. Kabe, Z. Lin, C. Adachi, Nat. Mater. 21 (2021) 338–344.
12. [12]
  R. Kabe, C. Adachi, Nature 550 (2017) 384–387. doi: 10.1038/nature24010
13. [13]
  S. Kuila, S.J. George, Angew. Chem. Int. Ed. 59 (2020) 9393–9397. doi: 10.1002/anie.202002555
14. [14]
  A.M. Messinis, A.S. Batsanov, W.R.H. Wright, et al., ACS Catal. 8 (2018) 11249–11263. doi: 10.1021/acscatal.8b02202
15. [15]
  S. Guo, W. Dai, X. Chen, et al., ACS Mater. Lett. 3 (2021) 379–397. doi: 10.1021/acsmaterialslett.1c00062
16. [16]
  Y. Wen, H. Liu, S. Zhang, et al., J. Mater. Chem. C 7 (2019) 12502–12508. doi: 10.1039/C9TC04580E
17. [17]
  Z. Yang, C. Xu, W. Li, et al., Angew. Chem. Int. Ed. 59 (2020) 17451–17455. doi: 10.1002/anie.202007343
18. [18]
  J. Wei, B. Liang, R. Duan, et al., Angew. Chem. Int. Ed. 55 (2016) 15589– 15593. doi: 10.1002/anie.201607653
19. [19]
  P. Pander, A. Swist, R. Turczyn, et al., J. Phys. Chem. C 122 (2018) 24958–24966. doi: 10.1021/acs.jpcc.8b08329
20. [20]
  Z. An, C. Zheng, Y. Tao, et al., Nat. Mater. 14 (2015) 685–690. doi: 10.1038/nmat4259
21. [21]
  L. Xu, G. Li, T. Xu, et al., Chem. Commun. 54 (2018) 9226–9229. doi: 10.1039/C8CC04734K
22. [22]
  G. Zhang, J. Chen, S.J. Payne, et al., J. Am. Chem. Soc. 129 (2007) 8942–8943. doi: 10.1021/ja0720255
23. [23]
  H. Chen, X. Yao, X. Ma, H. Tian, Adv. Opt. Mater. 4 (2016) 1397–1401. doi: 10.1002/adom.201600427
24. [24]
  L. Gu, H. Wu, H. Ma, et al., Nat. Commun. 11 (2020) 944. doi: 10.1038/s41467-020-14792-1
25. [25]
  Y. Tian, J. Yang, Z. Liu, et al., Angew. Chem. Int. Ed. 60 (2021) 20259–20263. doi: 10.1002/anie.202107639
26. [26]
  X. Liu, Y. Pan, Y. Lei, et al., J. Phys. Chem. Lett. 12 (2021) 7357–7364. doi: 10.1021/acs.jpclett.1c01893
27. [27]
  Y. Chen, Y. Xie, H. Shen, et al., Chem. Eur. J. 26 (2020) 17376–17380. doi: 10.1002/chem.202004291
28. [28]
  Y. Lei, J. Yang, W. Dai, et al., Chem. Sci. 12 (2021) 6518–6625. doi: 10.1039/D1SC01175H
29. [29]
  X. Zhang, L. Du, W. Zhao, et al., Nat. Commun. 10 (2019) 5161. doi: 10.1038/s41467-019-13048-x
30. [30]
  X. Liu, W. Dai, J. Qian, et al., J. Mater. Chem. C 9 (2021) 3391–3395. doi: 10.1039/D1TC00403D
31. [31]
  Y. Lei, W. Dai, J. Guan, et al., Angew. Chem. Int. Ed. 59 (2020) 16054–16060. doi: 10.1002/anie.202003585
32. [32]
  S. Hirata, K. Totani, J. Zhang, et al., Adv. Funct. Mater. 23 (2013) 3386–3397. doi: 10.1002/adfm.201203706
33. [33]
  M.S. Kwon, D. Lee, S. Seo, J. Jung, J. Kim, Angew. Chem. Int. Ed. 53 (2014) 11177–11181. doi: 10.1002/anie.201404490
34. [34]
  B. Ding, L. Ma, Z. Huang, X. Ma, H. Tian, Sci. Adv. 7 (2021) eabf9668. doi: 10.1126/sciadv.abf9668
35. [35]
  Y. Zhao, B. Ding, Z. Huang, X. Ma, Chem. Sci. 13 (2022) 8412–8416. doi: 10.1039/D2SC01622B
36. [36]
  L. Ma, Q. Xu, S. Sun, et al., Angew. Chem. Int. Ed. 61 (2022) e202115748.
37. [37]
  H. Gui, Z. Huang, Z. Yuang, X. Ma, CCS Chem. 4 (2022) 173–181. doi: 10.31635/ccschem.021.202000609
38. [38]
  Y. Pan, J. Li, X. Wang, et al., Adv. Funct. Mater. 32 (2022) 2110207. doi: 10.1002/adfm.202110207
39. [39]
  Y. Sun, G. Wang, X. Li, B. Zhou, K. Zhang, Adv. Opt. Mater. 9 (2021) 2100353. doi: 10.1002/adom.202100353
40. [40]
  Y. Sun, J. Liu, J. Li, et al., Adv. Opt. Mater. 10 (2022) 2101909. doi: 10.1002/adom.202101909
41. [41]
  W. Yuan, X. Shen, H. Zhao, et al., J. Phys. Chem. C 114 (2010) 6090–6099. doi: 10.1021/jp909388y
42. [42]
  W. Luo, Y. Zhang, Y. Gong, et al., Chin. Chem. Lett. 29 (2018) 1533–1536. doi: 10.1016/j.cclet.2018.08.001
43. [43]
  F. Xiao, H. Gao, Y. Lei, et al., Nat. Commun. 13 (2022) 186.
44. [44]
  C. Lee, W. Yang, R.G. Parr, Phys. Rev. B 37 (1988) 785–789. doi: 10.1103/PhysRevB.37.785
45. [45]
  M.J. Frisch, G.W. Trucks, H.B. Schlegel, et al., Gaussian 16 Rev. C. 01, Wallingford, CT (2016).
46. [46]
  T. Lu, F. Chen, J. Comput. Chem. 33 (2012) 580–592. doi: 10.1002/jcc.22885
47. [47]
  Z. Lin, R. Kabe, N. Nishimura, K. Jinnai, C. Adachi, Adv. Mater. 30 (2018) 1803713. doi: 10.1002/adma.201803713
48. [48]
  D. Liu, A.M. El-Zohry, M. Taddei, et al., Angew. Chem. Int. Ed. 59 (2020) 11591–11599. doi: 10.1002/anie.202003560
49. [49]
  C. Chen, Z. Chi, K.C. Chong, et al., Nat. Mater. 20 (2021) 175–180. doi: 10.1038/s41563-020-0797-2
50. [50]
  X. Chen, A.A. Sukhanov. Y. Yan, et al., Angew. Chem. Int. Ed. 61 (2022) e202203758.
51. [51]
  Y. Dong, A. Elmali, J. Zhao, B. Dick, A. Karatay, ChemPhysChem 21 (2020) 1388–1401. doi: 10.1002/cphc.202000300
52. [52]
  M. Li, X. Cai, Z. Chen, et al., Chem. Sci. 12 (2021) 13580. doi: 10.1039/D1SC03420K
53. [53]
  D. Lee, O. Bolton, B.C. Kim, et al., J. Am. Chem. Soc. 135 (2013) 6325–6329. doi: 10.1021/ja401769g
1. [1]
  Kun Zhang , Ni Dan , Dan-Dan Ren , Ruo-Yu Zhang , Xiaoyan Lu , Ya-Pan Wu , Li-Lei Zhang , Hong-Ru Fu , Dong-Sheng Li . A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting. Chinese Journal of Structural Chemistry, 2024, 43(3): 100244-100244. doi: 10.1016/j.cjsc.2024.100244
2. [2]
  Dian-Xue Ma , Yu-Wu Zhong . Achieving highly-efficient room-temperature phosphorescence with a nylon matrix. Chinese Journal of Structural Chemistry, 2024, 43(9): 100391-100391. doi: 10.1016/j.cjsc.2024.100391
3. [3]
  Aolei Tan , Xiaoxiao Ma . Exploring the functional roles of small-molecule metabolites in disease research: Recent advancements in metabolomics. Chinese Chemical Letters, 2024, 35(8): 109276-. doi: 10.1016/j.cclet.2023.109276
4. [4]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
5. [5]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
6. [6]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
7. [7]
  Jianmei Guo , Yupeng Zhao , Lei Ma , Yongtao Wang . Ultra-long room temperature phosphorescence, intrinsic mechanisms and application based on host-guest doping systems. Chinese Journal of Structural Chemistry, 2024, 43(9): 100335-100335. doi: 10.1016/j.cjsc.2023.100335
8. [8]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
9. [9]
  Hui Liu , Xiangyang Tang , Zhuang Cheng , Yin Hu , Yan Yan , Yangze Xu , Zihan Su , Futong Liu , Ping Lu . Constructing multifunctional deep-blue emitters with weak charge transfer excited state for high-performance non-doped blue OLEDs and single-emissive-layer hybrid white OLEDs. Chinese Chemical Letters, 2024, 35(10): 109809-. doi: 10.1016/j.cclet.2024.109809
10. [10]
  Jieqiong Xu , Wenbin Chen , Shengkai Li , Qian Chen , Tao Wang , Yadong Shi , Shengyong Deng , Mingde Li , Peifa Wei , Zhuo Chen . Organic stoichiometric cocrystals with a subtle balance of charge-transfer degree and molecular stacking towards high-efficiency NIR photothermal conversion. Chinese Chemical Letters, 2024, 35(10): 109808-. doi: 10.1016/j.cclet.2024.109808
11. [11]
  Na Wang , Wang Luo , Huaiyi Shen , Huakai Li , Zejiang Xu , Zhiyuan Yue , Chao Shi , Hengyun Ye , Leping Miao . Crystal engineering regulation achieving inverse temperature symmetry breaking ferroelasticity in a cationic displacement type hybrid perovskite system. Chinese Chemical Letters, 2024, 35(5): 108696-. doi: 10.1016/j.cclet.2023.108696
12. [12]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
13. [13]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
14. [14]
  Zhaomin Tang , Qian He , Jianren Zhou , Shuang Yan , Li Jiang , Yudong Wang , Chenxing Yao , Huangzhao Wei , Keda Yang , Jiajia Wang . Active-transporting of charge-reversal Cu(Ⅱ)-doped mesoporous silica nanoagents for antitumor chemo/chemodynamic therapy. Chinese Chemical Letters, 2024, 35(7): 109742-. doi: 10.1016/j.cclet.2024.109742
15. [15]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
16. [16]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
17. [17]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
18. [18]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
19. [19]
  Qian Wang , Ting Gao , Xiwen Lu , Hangchao Wang , Minggui Xu , Longtao Ren , Zheng Chang , Wen Liu . Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor. Chinese Chemical Letters, 2024, 35(7): 108887-. doi: 10.1016/j.cclet.2023.108887
20. [20]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(482)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142