Citation: Lu Zhang, Jin Xiong, Yin-Shan Meng, Tao Liu. Structures and magnetic relaxation properties of cyclopentadienyl/β-diketonate/trispyrazolylborate hybridized dysprosium single-molecule magnets[J]. Chinese Chemical Letters, ;2023, 34(8): 108055. doi: 10.1016/j.cclet.2022.108055 shu

Structures and magnetic relaxation properties of cyclopentadienyl/β-diketonate/trispyrazolylborate hybridized dysprosium single-molecule magnets

Lu Zhang ^{a, 1} ,
Jin Xiong ^{b, 1} ,
Yin-Shan Meng ^{a, *,} ,
Tao Liu ^{a, *,}

a.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China
b.
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States

mengys@dlut.edu.cn

liutao@dlut.edu.cn

Received Date: 27 October 2022
Revised Date: 16 November 2022
Accepted Date: 9 December 2022
Available Online: 10 December 2022

Figures(4)

The combination of cyclopentadiene, β-diketonate and tripyrazoylborate ligands with dysprosium ion afforded five mononuclear compounds: [(Cp)₂Dy(Tp*)] (1Dy), [(Cp)Dy(Tp*)Cl(THF)] (2Dy), [(Cp)Dy(Tp)Cl(THF)] (3Dy), [(DBM)Dy(Tp)Cl(THF)] (4Dy), [{(Tp)Dy(DBM)₂(H₂O)}·THF] (5Dy) (Cp = cyclopentadiene; Tp* = hydrotris(3,5-dimethyl-1-pyrazolyl)borate; Tp = hydrotris(1-pyrazolyl)borate; DBM = dibenzoylmethanoate). Magnetic study revealed that 1Dy and 3Dy exhibited typical butterfly-type hysteresis. AC susceptibility study combined with ab initio calculations indicated that the magnetic relaxation behaviors of 1Dy–4Dy were governed by the Orbach and Raman processes under applied DC field. Moreover, 3Dy showed two-step magnetic relaxation, which was attributed to the static disordering of the coordinated THF molecule. Magnetic anisotropy analysis indicated that it was the relative strength of the interactions between Dy^III and surrounding ligands that determined the orientation of the magnetic easy axis.
- Single-molecule magnets,
- Lanthanide complexes,
- Magnetic anisotropy,
- Magnetic relaxations,
- Quantum tunneling of magnetization
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