Citation: Chang-Feng Wang, Na Wang, Lang Liu, Le-Ping Miao, Heng-Yun Ye, Yi Zhang, Chao Shi. Enantiomeric hybrid high-temperature multiaxial ferroelectrics with a narrow bandgap and high piezoelectricity[J]. Chinese Chemical Letters, ;2023, 34(8): 108051. doi: 10.1016/j.cclet.2022.108051 shu

Enantiomeric hybrid high-temperature multiaxial ferroelectrics with a narrow bandgap and high piezoelectricity

Chaotic Matter Science Research Center, Department of Materials, Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

amn716@163.com

shic@jxust.edu.cn

Received Date: 27 August 2022
Revised Date: 10 November 2022
Accepted Date: 6 December 2022
Available Online: 8 December 2022

Figures(4)

Ferroelectric semiconductors have sparked growing attention in the field of optoelectronics, due to their unique ferroelectric photovoltaic effect. Recently, substantial efforts have been devoted to the development of ferroelectric semiconductors, including inorganic oxides, organic-inorganic hybrids, and metal-free perovskites. Nevertheless, reports of ferroelectric semiconductors with a bandgap of less than 2 eV have been scarce. Here, in combination with the incorporation of triiodide (I₃⁻) and the introduction of chiral cations, we successfully constructed a pair of enantiomeric organic-inorganic hybrid ferroelectric semiconductors, (S-1,2-DAP·I)₄·I₃·BiI₆ and (R-1,2-DAP·I)₄·I₃·BiI₆ (R/S-1,2-DAP = (R/S)-(–)-1,2-diaminopropane), which possess high-temperature multiaxial ferroelectric phase transition with an Aizu notation of 422F2(s) at 405 K, a narrow bandgap of 1.56 eV comparable to that of CH₃NH₃PbI₃ (~1.5 eV), and an impressive piezoelectric response (piezoelectric coefficient, d₂₂ of 35 pC/N) on par with PVDF (polyvinylidene fluoride, 30 pC/N). With intriguing attributes, (S-1,2-DAP·I)₄·I₃·BiI₆ and (R-1,2-DAP·I)₄·I₃·BiI₆ exhibit great potential for application of self-power polarized-light detection and piezoelectric sensors.
- Chirality,
- Hybrid materials,
- Multiaxial ferroelectrics,
- Semiconductors,
- Piezoelectricity
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