Citation: Song Peng, Xiaoming Ouyang, Yihan Wang, Qinghu Teng, Yan Li, Xiuqing Zhang, Zhaobo Hu, Kai Wang, Fupei Liang. In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases[J]. Chinese Chemical Letters, ;2023, 34(8): 108044. doi: 10.1016/j.cclet.2022.108044 shu

In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases

Song Peng ^{a, 1} ,
Xiaoming Ouyang ^{a, 1} ,
Yihan Wang ^{a, 1} ,
Qinghu Teng ^{a, *,} ,
Yan Li ^a ,
Xiuqing Zhang ^a ,
Zhaobo Hu ^b ,
Kai Wang ^{a, *,} ,
Fupei Liang ^{a, *,}

a.
Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
b.
Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China

2020130@glut.edu.cn

kaiwang@glut.edu.cn

liangfupei@glut.edu.cn

Received Date: 23 October 2022
Accepted Date: 5 December 2022
Available Online: 7 December 2022

Figures(4)

Chiral high-nuclearity lanthanide (4f) clusters have shown fantastic properties in various fields. However, their synthesis is still of great challenge. Herein, we report two pairs of enantiomers of high-nuclearity Dy-oxo clusters synthesized through in situ strategy. They are [Dy₁₈(^R/SHftp)₄ (^R/SH₂btp)₄(μ₂-OH)₈(μ₃-OH)₂₀(μ₆-O)(NO₃)₄(μ-H₂O)₈]·[solvents] (1R and 1S) and [Dy₉(^R/SHftp)₂ (^R/SH₂btp)₂(OAc)₆(μ₃-OH)₁₀(H₂O)₆](OAc)·[solvents] (2R and 2S), where ^R/SHftp²⁻ and ^R/SH₂btp³⁻ represent in situ formed 2-formyl-6-[N-(threonine)iminomethyl]-4-methylphenol and 2,6-bis[N-(threonine)iminomethyl]-4-methylphenol anions, respectively. These in situ formed clusters were endowed with not only homochirality via introducing ^R/SHftp²⁻ and ^R/SH₂btp³⁻ ligands, but also rich oxo-bridges by controlling the hydrolysis of Dy^Ⅲ ions. Different anions from Dy^Ⅲ salts further induced structural variation between two sets of clusters. 1R and 1S feature an unprecedent four-blade propeller shaped {Dy₁₈} core, whose centered octahedral {Dy₆} unit are surrounded by four triangular {Dy₃} units. Strikingly, they represent the second largest chiral 4f cluster species so far. 2R and 2S display a sandglass-like {Dy₉} skeleton that consist of two square pyramid {Dy₅} units sharing a Dy^Ⅲ vertex. Magnetic investigation revealed possible antiferromagnetic interactions between the Dy^Ⅲ centers in these clusters.
- Chirality,
- Lanthanide-oxo cluster,
- In situ synthesis,
- Threonine Schiff bases,
- Hydrolysis,
- Magnetic properties
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