Citation: Ke Jiang, Yuntian Gao, Peng Zhang, Shiwei Lin, Ling Zhang. A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C₂H₂/CO₂ separation[J]. Chinese Chemical Letters, ;2023, 34(8): 108039. doi: 10.1016/j.cclet.2022.108039 shu

A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C₂H₂/CO₂ separation

Ke Jiang ^{b, c} ,
Yuntian Gao ^a ,
Peng Zhang ^a ,
Shiwei Lin ^a ,
Ling Zhang ^{a, *,}

a.
State Key Laboratory of Marine Resource Utilization in South China Sea, School of Materials Science and Engineering, Hainan University, Haikou 570228, China
b.
Key Laboratory of Food Nutrition and Functional Food of Hainan Province, School of Food Science and Engineering, Hainan University, Haikou 570228, China
c.
State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China

ling.zhang@hainanu.edu.cn

Received Date: 16 August 2022
Revised Date: 18 September 2022
Accepted Date: 2 December 2022
Available Online: 5 December 2022

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Adsorptive separation of acetylene (C₂H₂) from carbon dioxide (CO₂) is of great significance in petrochemical industry, but still remains as a daunting challenge by reason of their very similar molecular sizes/shapes and physical properties. Herein, we reported a new perchlorate-based hybrid ultramicroporous material ZJU-194 that features the unique flexible-robust network decorated with rich bare oxygen atoms. By integrating the refined pore space as well as specific binding sites, the activated ZJU-194 (ZJU-194a) enables a selective two-step gate-opening adsorption toward C₂H₂, but blocks off the further uptake of CO₂. It thus exhibits a very high C₂H₂/CO₂ selectivity (22.4) at ambient conditions, which is superior to most reported MOF materials. Its complete separation for 50/50 C₂H₂/CO₂ mixtures is further evidenced by the dynamic breakthrough experiments.
- Porous materials,
- Gas separation,
- Pore chemistry,
- Flexibility,
- Host-guest interaction
1. [1]
  A. Granada, S.B. Karra, S.M. Senkan, Ind. Eng. Chem. Res. 26 (1987) 1901–1905. doi: 10.1021/ie00069a030
2. [2]
  J.R. Li, R.J. Kuppler, H.C. Zhou, Chem. Soc. Rev. 38 (2009) 1477–1504. doi: 10.1039/b802426j
3. [3]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi, Science 341 (2013) 1230444. doi: 10.1126/science.1230444
4. [4]
  H.C. Zhou, S. Kitagawa, Chem. Soc. Rev. 43 (2014) 5415–5418. doi: 10.1039/C4CS90059F
5. [5]
  H.F. Wang, L. Chen, H. Pang, S. Kaskel, Q. Xu, Chem. Soc. Rev. 49 (2020) 1414–1448. doi: 10.1039/c9cs00906j
6. [6]
  L. Zhang, J. Wang, K. Jiang, et al., Angew. Chem. Int. Ed. (2022) e202214794.
7. [7]
  Y. Cui, J. Zhang, H. He, G. Qian, Chem. Soc. Rev. 47 (2018) 5740–5785. doi: 10.1039/C7CS00879A
8. [8]
  D. Yue, J. Zhu, D. Chen, et al., Dyes Pigments 206 (2022) 110655. doi: 10.1016/j.dyepig.2022.110655
9. [9]
  W. Ni, K. Jiang, Q. Ke, et al., J. Mater. Sci. Technol. 141 (2023) 11–20. doi: 10.1016/j.jmst.2022.10.001
10. [10]
  J. Su, P. Jing, K. Jiang, J. Du, Dalton Trans. 51 (2022) 8938–8944. doi: 10.1039/d2dt01039a
11. [11]
  W.G. Cui, T.L. Hu, X.H. Bu, Adv. Mater. 32 (2020) e1806445. doi: 10.1002/adma.201806445
12. [12]
  L. Yang, S. Qian, X. Wang, X. Cui, B. Chen, H. Xing, Chem. Soc. Rev. 49 (2020) 5359–5406. doi: 10.1039/c9cs00756c
13. [13]
  S. Chen, S. Lin, L. Zhang, Mater. Lett. 327 (2022) 133064. doi: 10.1016/j.matlet.2022.133064
14. [14]
  R. Matsuda, R. Kitaura, S. Kitagawa, et al., Nature 436 (2005) 238–241. doi: 10.1038/nature03852
15. [15]
  Z. Niu, X. Cui, T. Pham, et al., Angew. Chem. Int. Ed. 60 (2021) 5283–5288. doi: 10.1002/anie.202016225
16. [16]
  L. Zhang, K. Jiang, L. Yang, et al., Angew. Chem. Int. Ed. 60 (2021) 15995–16002. doi: 10.1002/anie.202102810
17. [17]
  J. Wang, Y. Zhang, Y. Su, et al., Nat. Commun. 13 (2022) 200.
18. [18]
  Y. Yang, H. Zhang, Z. Yuan, et al., Angew. Chem. Int. Ed. (2022) e202207579.
19. [19]
  Y. Xie, H. Cui, H. Wu, et al., Angew. Chem. Int. Ed. 60 (2021) 9604–9609. doi: 10.1002/anie.202100584
20. [20]
  O.T. Qazvini, R. Babarao, S.G. Telfer, Nat. Commun. 12 (2021) 197. doi: 10.1038/s41467-020-20489-2
21. [21]
  L.Z. Cai, Z.Z. Yao, S.J. Lin, M.S. Wang, G.C. Guo, Angew. Chem. Int. Ed. 60 (2021) 18223–18230. doi: 10.1002/anie.202105491
22. [22]
  L. Li, J. Wang, Z. Zhang, et al., ACS Appl. Mater. Interfaces 11 (2019) 2543–2550. doi: 10.1021/acsami.8b19590
23. [23]
  J. Pei, H.M. Wen, X.W. Gu, et al., Angew. Chem. Int. Ed. 60 (2021) 25068–25074. doi: 10.1002/anie.202110820
24. [24]
  L. Liu, Z. Yao, Y. Ye, et al., J. Am. Chem. Soc. 142 (2020) 9258–9266. doi: 10.1021/jacs.0c00612
25. [25]
  X. Mu, Y. Xue, M. Hu, et al., Chin. Chem. Lett. 34 (2023) 107296. doi: 10.1016/j.cclet.2022.03.019
26. [26]
  T. Xu, M. He, L. Fan, et al., Dalton Trans. 50 (2021) 638–646. doi: 10.1039/d0dt03410j
27. [27]
  F. Luo, C. Yan, L. Dang, et al., J. Am. Chem. Soc. 138 (2016) 5678–5684. doi: 10.1021/jacs.6b02030
28. [28]
  W. Fan, S. Yuan, W. Wang, et al., J. Am. Chem. Soc. 142 (2020) 8728–8737. doi: 10.1021/jacs.0c00805
29. [29]
  G.R. Si, W. Wu, T. He, et al., ACS Mater. Lett. 4 (2022) 1032–1036. doi: 10.1021/acsmaterialslett.2c00129
30. [30]
  T. Li, P. Cui, D. Sun, Inorg. Chem. 61 (2022) 4251–4256. doi: 10.1021/acs.inorgchem.2c00409
31. [31]
  X. Wang, L. Yue, P. Zhou, L. Fan, Y. He, Inorg. Chem. 60 (2021) 17249–17257. doi: 10.1021/acs.inorgchem.1c02614
32. [32]
  J. Gao, X. Qian, R.B. Lin, et al., Angew. Chem. Int. Ed. 59 (2020) 4396–4400. doi: 10.1002/anie.202000323
33. [33]
  Y.L. Peng, T. Pham, P. Li, et al., Angew. Chem. Int. Ed. 57 (2018) 10971–10975. doi: 10.1002/anie.201806732
34. [34]
  J. Pei, K. Shao, J.X. Wang, et al., Adv. Mater. 32 (2020) e1908275. doi: 10.1002/adma.201908275
35. [35]
  P. Nugent, Y. Belmabkhout, S.D. Burd, et al., Nature 495 (2013) 80–84. doi: 10.1038/nature11893
36. [36]
  X. Cui, K. Chen, H. Xing, et al., Science 353 (2016) 141–144. doi: 10.1126/science.aaf2458
37. [37]
  L. Li, H.M. Wen, C. He, et al., Angew. Chem. Int. Ed. 57 (2018) 15183–15188. doi: 10.1002/anie.201809869
38. [38]
  A. Cadiau, K. Adil, P.M. Bhatt, Y. Belmabkhout, M. Eddaoudi, Science 353 (2016) 137–140. doi: 10.1126/science.aaf6323
39. [39]
  H. Li, C. Liu, C. Chen, et al., Angew. Chem. Int. Ed. 60 (2021) 7547–7552. doi: 10.1002/anie.202013988
40. [40]
  K.J. Chen, H.S. Scott, D.G. Madden, et al., Chem 1 (2016) 753–765. doi: 10.1016/j.chempr.2016.10.009
41. [41]
  H.S. Scott, M. Shivanna, A. Bajpai, et al., ACS Appl. Mater. Interfaces 9 (2017) 33395–33400. doi: 10.1021/acsami.6b15250
42. [42]
  L. Zhang, K. Jiang, J. Zhang, et al., ACS Sustain. Chem. Eng. 7 (2018) 1667–1672. doi: 10.1094/pdis-02-18-0223-pdn
43. [43]
  W. Gong, H. Cui, Y. Xie, et al., J. Am. Chem. Soc. 143 (2021) 14869–14876. doi: 10.1021/jacs.1c07191
44. [44]
  T. Loiseau, C. Serre, C. Huguenard, et al., Chem. Eur. J. 10 (2004) 1373–1382. doi: 10.1002/chem.200305413
45. [45]
  R.B. Lin, L. Li, H. Wu, et al., J. Am. Chem. Soc. 139 (2017) 8022–8028. doi: 10.1021/jacs.7b03850
46. [46]
  L. Zhang, K. Jiang, L. Li, et al., Chem. Commun. 54 (2018) 4846–4849. doi: 10.1039/c8cc02235f
47. [47]
  Y. Gu, J.J. Zheng, K.I. Otake, et al., Angew. Chem. Int. Ed. 59 (2020) 15517–15521. doi: 10.1002/anie.202003186
48. [48]
  L. Yang, L. Yan, Y. Wang, et al., Angew. Chem. Int. Ed. 60 (2021) 4570–4574. doi: 10.1002/anie.202013965
49. [49]
  H. Zeng, M. Xie, Y.L. Huang, et al., Angew. Chem. Int. Ed. 58 (2019) 8515–8519. doi: 10.1002/anie.201904160
50. [50]
  S. Dutta, S. Mukherjee, O.T. Qazvini, et al., Angew. Chem. Int. Ed. 61 (2022) e202114132. doi: 10.1002/anie.202114132
51. [51]
  S. Mukherjee, Y. He, D. Franz, et al., Chem. Eur. J. 26 (2020) 4923–4929. doi: 10.1002/chem.202000008
52. [52]
  L. Wang, W. Sun, Y. Zhang, et al., Angew. Chem. Int. Ed. 60 (2021) 22865–22870. doi: 10.1002/anie.202107963
53. [53]
  Y.P. Li, Y. Wang, Y.Y. Xue, et al., Angew. Chem. Int. Ed. 58 (2019) 13590–13595. doi: 10.1002/anie.201908378
54. [54]
  O.T. Qazvini, R. Babarao, S.G. Telfer, Chem. Mater. 31 (2019) 4919–4926. doi: 10.1021/acs.chemmater.9b01691
55. [55]
  M. Fischer, F. Hoffmann, M. Froba, ChemPhysChem 11 (2010) 2220–2229. doi: 10.1002/cphc.201000126
56. [56]
  J. Lee, C.Y. Chuah, J. Kim, et al., Angew. Chem. Int. Ed. 57 (2018) 7869–7873. doi: 10.1002/anie.201804442
57. [57]
  W.J.F. Trenholme, D.I. Kolokolov, M. Bound, et al., J. Am. Chem. Soc. 143 (2021) 3348–3358. doi: 10.1021/jacs.0c11202
58. [58]
  T. Xu, Z. Jiang, P. Liu, et al., ACS Appl. Nano Mater. 3 (2020) 2911–2919. doi: 10.1021/acsanm.0c00162
59. [59]
  Z. Di, C. Liu, J. Pang, et al., Angew. Chem. Int. Ed. 60 (2021) 10828–10832. doi: 10.1002/anie.202101907
60. [60]
  Y. Ye, Z. Ma, R.B. Lin, et al., J. Am. Chem. Soc. 141 (2019) 4130–4136. doi: 10.1021/jacs.9b00232
61. [61]
  Y. Zhang, J. Hu, R. Krishna, et al., Angew. Chem. Int. Ed. 59 (2020) 17664–17669. doi: 10.1002/anie.202007681
62. [62]
  X. Zhang, R.B. Lin, H. Wu, et al., Chem. Eng. J. 431 (2022) 134184. doi: 10.1016/j.cej.2021.134184
63. [63]
  Y.M. Gu, H.F. Qi, T.T. Sun, et al., Chem. Mater. 34 (2022) 2708–2716. doi: 10.1021/acs.chemmater.1c04168
64. [64]
  Y. Ye, S. Xian, H. Cui, et al., J. Am. Chem. Soc. 144 (2022) 1681–1689. doi: 10.1021/jacs.1c10620
65. [65]
  Q.L. Qian, X.W. Gu, J. Pei, et al., J. Mater. Chem. A 9 (2021) 9248–9255. doi: 10.1039/d0ta11340a
66. [66]
  X.P. Fu, Y.L. Wang, X.F. Zhang, et al., Chem. Eng. J. 432 (2022) 134433. doi: 10.1016/j.cej.2021.134433
67. [67]
  L. Fan, L. Yue, W. Sun, et al., ACS Appl. Mater. Interfaces 13 (2021) 40788–40797. doi: 10.1021/acsami.1c13524
68. [68]
  E.D. Bloch, W.L. Queen, R. Krishna, et al., Science 335 (2012) 1606–1610. doi: 10.1126/science.1217544
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C2H2/CO2 separation

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通讯作者: 陈斌, bchen63@163.com

A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C₂H₂/CO₂ separation