Citation: Xiaoqiang Pan, Shuchuan Mei, Wu-Jun Liu. Self-supported ultrathin Co₃O₄ nanoarray enabling efficient paired electrolysis of 5-hydroxymethylfurfural for simultaneous dihydroxymethylfuran (DHMF) and furandicarboxylic acid (FDCA) production[J]. Chinese Chemical Letters, ;2023, 34(7): 108034. doi: 10.1016/j.cclet.2022.108034 shu

Self-supported ultrathin Co₃O₄ nanoarray enabling efficient paired electrolysis of 5-hydroxymethylfurfural for simultaneous dihydroxymethylfuran (DHMF) and furandicarboxylic acid (FDCA) production

CAS Key Laboratory of Urban Pollutant Conversion, Department of Environmental Science and Engineering, University of Science and Technology of China, Hefei 230026, China

liuwujun@mail.ustc.edu.cn

Received Date: 14 September 2022
Revised Date: 19 November 2022
Accepted Date: 29 November 2022
Available Online: 1 December 2022

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Production of value-added chemicals and fuels from biomass via electrochemical methods has been of emerging interest in light of the increasing environmental, economic, and political challenges. Paired electrolysis, with anodic oxidation and cathodic reduction reactions pairing in a single electrochemical cell, offers an effective way to produce desired products in both electrodes, thus achieving complete electron economy. In this work, an efficient 5-hydroxymethylfurfural (HMF) paired electrolysis system is developed over a self-supported ultrathin Co₃O₄ nanoarray electrocatalyst for simultaneous production of value-added 2, 5-dihydroxymethylfuran (DHMF) and 2, 5-furandicarboxylic acid (FDCA). The as-designed paired electrolysis cell achieves a high HMF conversion and DHMF/FDCA selectivity at both anode and cathode without external hydrogen and oxygen input. A near-quantitative yield (95.7%) of FDCA and 78.8% yield of DHMF can be achieved in the paired electrolysis system, with a total Faradaic efficiency of 127%. This work will open up new opportunities in designing efficient electrochemical devices to simultaneously produce building-block chemicals from biomass-derived molecules in both anode and cathode.
- Paired electrolysis,
- 5-Hydroxymethylfurfural,
- 2, 5-Dihydroxymethylfuran,
- 2, 5-Furandicarboxylic acid,
- Co₃O₄
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Self-supported ultrathin Co3O4 nanoarray enabling efficient paired electrolysis of 5-hydroxymethylfurfural for simultaneous dihydroxymethylfuran (DHMF) and furandicarboxylic acid (FDCA) production

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通讯作者: 陈斌, bchen63@163.com

Self-supported ultrathin Co₃O₄ nanoarray enabling efficient paired electrolysis of 5-hydroxymethylfurfural for simultaneous dihydroxymethylfuran (DHMF) and furandicarboxylic acid (FDCA) production