Citation: Bo Li, Qiangqiang Xu, Xin Shen, Tiezheng Pan, Jie Shang, Yan Ge, Zhenhui Qi. Atom-economic macrocyclic amphiphile based on guanidinium-functionalized selenacrown ether acting as redox-responsive nanozyme[J]. Chinese Chemical Letters, ;2023, 34(4): 108015. doi: 10.1016/j.cclet.2022.108015 shu

Atom-economic macrocyclic amphiphile based on guanidinium-functionalized selenacrown ether acting as redox-responsive nanozyme

Sino-German Joint Research Lab for Space Biomaterials and Translational Technology, Synergetic Innovation Center of Biological Optoelectronics and Healthcare Engineering (BOHE), Shaanxi Provincial Synergistic Innovation Center for Flexible Electronics & Health Sciences (FEHS), School of Life Sciences, Northwestern Polytechnical University, Xi'an 710072, China

ge@nwpu.edu.cn

qi@nwpu.edu.cn

Received Date: 31 August 2022
Revised Date: 17 November 2022
Accepted Date: 20 November 2022
Available Online: 29 November 2022

Figures(6)

Control of self-assembly is significant to the preparation of supramolecular materials, but the control of hydration, responsiveness, dimension, catalysis of macrocyclic amphiphiles in an atom-economic manner is still a great challenge. The herein presented 527 Da low-molecular-weight macrocyclic amphiphile was fabricated by utilizing the selenium-containing crown ether as a hydrophobic motif together with guanidinium group as the hydrophilic moiety. The resulting benzo[21]crown-7 based macrocyclic amphiphile readily forms a redox-responsive solid nanoparticles in water, which can further interconnect into wrinkled pattern on-surface, as well as exhibits as a nanozyme for catalyzing disulfid bond formation. The present work highlights the great potential of guanidinium- and selenium-containing crown ethers for the control of functional assemblies.
- Selenium,
- Guanidinium,
- Macrocycle amphiphile,
- Crown ether,
- Molecular assembly,
- Winkled surface,
- Nanozyme
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