Citation: Chunwei Zhuo, Han Cao, Xiaoshen Wang, Shunjie Liu, Xianhong Wang. Polymeric aluminum porphyrin: Controllable synthesis of ultra-low molecular weight CO₂-based polyols[J]. Chinese Chemical Letters, ;2023, 34(8): 108011. doi: 10.1016/j.cclet.2022.108011 shu

Polymeric aluminum porphyrin: Controllable synthesis of ultra-low molecular weight CO₂-based polyols

Chunwei Zhuo ^a ,
Han Cao ^a ,
Xiaoshen Wang ^{a, b} ,
Shunjie Liu ^{a, b, *,} ,
Xianhong Wang ^{a, b, *,}

a.
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Science and Technology of China, Hefei 230026, China

sjliu@ciac.ac.cn

xhwang@ciac.ac.cn

Received Date: 28 October 2022
Revised Date: 9 November 2022
Accepted Date: 16 November 2022
Available Online: 21 November 2022

Figures(3)

Carbon dioxide-based polyols with ultra-low molecular weight (ULMW, M_n < 1000 g/mol) are emergent polyurethane precursors with economic and environmental benefits. However, the lack of effective proton-tolerant catalytic systems limits the development of this field. In this work, the polymeric aluminum porphyrin catalyst (PAPC) system was applied to the copolymerization of CO₂ and propylene oxide, where sebacic acid, bisphenol A, poly(ethylene glycol), and water were used as chain transfer agents to achieve the controlled synthesis of CO₂-polyols. The molecular weight of the resulting CO₂-polyols could be facilely regulated in the range of 400–930 g/mol at low catalyst loadings, fully demonstrating its catalytic advantages of high activity, high product selectivity, and excellent proton tolerance of PAPC. Meanwhile, the catalytic efficiency of PAPC could reach up to 2.1–5.2 kg/g under organic CTA conditions, even reaching 1.9 kg/g using water as the CTA. The cPC content could be controlled within 1.0 wt% under the optimized conditions, indicating the excellent controllability of the PAPC system. ULMW CO₂-polyols combines the advantages of low viscosity (~3000 mPa s at 25 ℃), low glass transition temperature (~−73 ℃), and high carbonate unit content (~40%), which is important for the development of high-performance polyurethanes.
- CO₂-polyols,
- Polymeric catalyst,
- Aluminum porphyrin,
- Ultra-low molecular weight,
- Proton tolerance
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Polymeric aluminum porphyrin: Controllable synthesis of ultra-low molecular weight CO2-based polyols

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通讯作者: 陈斌, bchen63@163.com

Polymeric aluminum porphyrin: Controllable synthesis of ultra-low molecular weight CO₂-based polyols