Citation: Ruyi Zhang, Liangliang Zhu, Bingbing Yue. Luminescent properties and recent progress in applications of lanthanide metal-organic frameworks[J]. Chinese Chemical Letters, ;2023, 34(2): 108009. doi: 10.1016/j.cclet.2022.108009 shu

Luminescent properties and recent progress in applications of lanthanide metal-organic frameworks

Ruyi Zhang ^a ,
Liangliang Zhu ^b ,
Bingbing Yue ^{a, b, *,}

a.
School of Materials and Chemistry, Shanghai Collaborative Innovation Center of Energy Therapy for Tumors, University of Shanghai for Science and Technology, Shanghai 200093, China
b.
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China

yuebingbing@usst.edu.cn

Received Date: 28 September 2022
Revised Date: 23 October 2022
Accepted Date: 15 November 2022
Available Online: 17 November 2022

Figures(11)

Lanthanide metal-organic frameworks (Ln-MOFs), which is composed of organic bridging ligands and Ln³⁺ ions/clusters, is an important component of luminescent MOFs. Compared with transition metal ions, lanthanide ions have a higher coordination number and abundant coordination geometry. Moreover, Ln-MOFs have special characteristics such as good porosity, topological diversity, high surface area and highly adjustable structure. The energy transfer (ET) process in Ln-MOFs could be easily affected by the interaction between host framework and guest, resulting in the change of luminescence intensity or color. Over the past few decades, the features of Ln-MOFs open the door to a range of incredibly important applications. However, there are few reviews on systemic summary of the various applications of Ln-MOFs. In this paper, we summarized the latest progress of Ln-MOFs applications, including the Ln-MOFs in chemical and biological sensors, optical information devices and catalysis, respectively, and discussed design mechanism. The possible problems in current research are briefly prospected, hoping to provide some helpful guidance for the future development of Ln-MOF materials.
- Ln-MOFs,
- Luminescent property,
- Sensors,
- Optical information devices,
- Catalysis
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