Citation: Jinkang Zhu, Xujin Chen, Xin Jin, Qiaochun Wang. Light-driven interconversion of Pd₂L₄ cage and mononuclear PdL₂ mediated by the isomerization of azobenzene ligand[J]. Chinese Chemical Letters, ;2023, 34(6): 108002. doi: 10.1016/j.cclet.2022.108002 shu

Light-driven interconversion of Pd₂L₄ cage and mononuclear PdL₂ mediated by the isomerization of azobenzene ligand

Key Laboratory for Advanced Materials, Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China

qcwang@ecust.edu.cn

Received Date: 30 August 2022
Revised Date: 4 November 2022
Accepted Date: 10 November 2022
Available Online: 12 November 2022

Figures(5)

The lantern-shaped cage Pd₂L₄ and tweezer-like PdL₂ can be synthesized from the trans- and cis-isomer of an azobenzene-containing ligand, respectively, which were characterized by ¹H, ¹³C, ¹H-¹H COSY, DOSY NMR spectroscopies, high-resolution ESI-MS and density function theory (DFT) calculations. The interconversion of Pd₂L₄ and PdL₂ can be achieved via the cis-trans isomerization of the azobenzene unit on the ligand upon alternative irradiation of light 365 nm or 420 nm.
- Molecular cage,
- Azobenzene,
- Isomerization,
- Pd₂L₄,
- PdL₂
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Light-driven interconversion of Pd2L4 cage and mononuclear PdL2 mediated by the isomerization of azobenzene ligand

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Light-driven interconversion of Pd₂L₄ cage and mononuclear PdL₂ mediated by the isomerization of azobenzene ligand