Citation: Zeyao Liang, Jiabao Guo, Peng Wang, Li Zhu, Xiaoquan Yao. Recyclable Cu/g-C₃N₄ nanometric semiconductor catalyzed N-formylation of amines via photocatalytic aerobic oxidative CC bond cleavage of aldehydes under visible-light irradiation[J]. Chinese Chemical Letters, ;2023, 34(6): 108001. doi: 10.1016/j.cclet.2022.108001 shu

Recyclable Cu/g-C₃N₄ nanometric semiconductor catalyzed N-formylation of amines via photocatalytic aerobic oxidative CC bond cleavage of aldehydes under visible-light irradiation

Zeyao Liang ^{a, 1} ,
Jiabao Guo ^{a, 1} ,
Peng Wang ^a ,
Li Zhu ^{b, *,} ,
Xiaoquan Yao ^{a, *,}

a.
Department of Applied Chemistry, School of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
b.
Department of Chemistry, School of Pharmacy, Nanjing Medical University, Nanjing 211166, China

zl9422@njmu.edu.cn

yaoxq@nuaa.edu.cn

Received Date: 9 August 2022
Revised Date: 9 November 2022
Accepted Date: 10 November 2022
Available Online: 12 November 2022

Figures(5)

Due to its difficulty and complexity, the cleavage and subsequent functionalization of the C(sp³)-C(sp³) single bond has received less attention than the CC bond formation reactions that have been extensively studied. Herein, by utilizing Cu/g-C₃N₄ nanometric semiconductor as a recyclable photocatalyst, an aerobic oxidative CC bond cleavage of aldehydes was developed with the promotion of amines under visible light irradiation. Based on the reaction, phenylacetaldehyde was selected as a highly efficient formylation reagent for amines. Under blue light irradiation, good to excellent yields of formamides were achieved for various amines in 1 atm oxygen atmosphere at room temperature. This methodology offers a practical, neutral and gentle alternative to the preparation of formamides.
- Photocatalytic C-C bond cleavage,
- N-Formylation of amines,
- Cu/g-C₃N₄,
- Nanometric semiconductor,
- Visible-light
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Recyclable Cu/g-C3N4 nanometric semiconductor catalyzed N-formylation of amines via photocatalytic aerobic oxidative CC bond cleavage of aldehydes under visible-light irradiation

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通讯作者: 陈斌, bchen63@163.com

Recyclable Cu/g-C₃N₄ nanometric semiconductor catalyzed N-formylation of amines via photocatalytic aerobic oxidative CC bond cleavage of aldehydes under visible-light irradiation