Citation: Mengmeng Wang, Xixi Meng, Ning Liu, Yi-Quan Zhang, Na Xu, Wei Shi, Peng Cheng. Two monofluoride-bridged Dy^Ⅲ dimers with different magnetization dynamics[J]. Chinese Chemical Letters, ;2023, 34(6): 107995. doi: 10.1016/j.cclet.2022.107995 shu

Two monofluoride-bridged Dy^Ⅲ dimers with different magnetization dynamics

Mengmeng Wang ^{a, 1} ,
Xixi Meng ^{a, 1} ,
Ning Liu ^a ,
Yi-Quan Zhang ^b ,
Na Xu ^{a, *,} ,
Wei Shi ^{a, *,} ,
Peng Cheng ^{a, *,}

a.
Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE) and Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin 300071, China
b.
Jiangsu Key Lab for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, China

naxu@nankai.edu.cn

shiwei@nankai.edu.cn

pcheng@nankai.edu.cn

Received Date: 6 October 2022
Revised Date: 1 November 2022
Accepted Date: 7 November 2022
Available Online: 10 November 2022

Figures(6)

As a monoatomic bridge, fluoride ion can transmit efficient magnetic interaction between lanthanide ions but its effect on tuning the magnetization dynamics has not been well understood. Herein, two monofluoride-bridged dinuclear dysprosium complexes [Dy₂F(bbpen)₂(EtOH)₂]Br·EtOH (1) and [Dy₂F(bbppy)₂]Br·2EtOH (2) with Dy-F-Dy angles of ~178° and their diamagnetic-ion diluted analogues 1´ and 2´ were synthesized. Magnetic studies reveal that 1 and 1´ barely show any magnetization dynamics, but 2 and 2´ exhibit strong magnetization dynamics. Systematical experimental analysis combined with ab initio calculations reveals that the different magnetization dynamics between 1 and 2 mainly originate from the effect of magnetic anisotropy by terminal ligand and bridging group of the chelating ligand, and the fluoride bridge can effectively suppress the quantum tunneling of the magnetization and turn on Orbach process in 2.
- Fluoride ion bridge,
- Dinuclear Dy^Ⅲ complexes,
- Magnetization dynamics,
- Single-molecule magnet,
- Suppressing QTM
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沈阳化工大学材料科学与工程学院沈阳 110142

Two monofluoride-bridged DyⅢ dimers with different magnetization dynamics

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通讯作者: 陈斌, bchen63@163.com

Two monofluoride-bridged Dy^Ⅲ dimers with different magnetization dynamics