Citation: Hang Peng, Qin Liu, Yuhua Liu, Yanzi Lu, Weiqiang Liao. A chiral lead-free tin(Ⅳ)-based halide organic-inorganic semiconductor with dielectric switching and phase transition[J]. Chinese Chemical Letters, ;2023, 34(8): 107980. doi: 10.1016/j.cclet.2022.107980 shu

A chiral lead-free tin(Ⅳ)-based halide organic-inorganic semiconductor with dielectric switching and phase transition

Ordered Matter Science Research Center, Nanchang University, Nanchang 330031, China

liaowq@ncu.edu.cn

Received Date: 14 September 2022
Revised Date: 18 October 2022
Accepted Date: 2 November 2022
Available Online: 4 November 2022

Figures(4)

Chiral organic-inorganic metal halide semiconductors (OIMHSs) have recently attracted numerous interests due to their unique chirality, structural tunability, and extensive physical properties. However, most reported chiral OIMHSs contain toxic lead, which will be a potential obstacle to their further applications. Herein, we successfully synthesized a novel chiral lead-free tin(Ⅳ)-based OIMHS [(R)-3-hydroxyquinuclidinium]₂SnCl₆ ([R-HQ]₂SnCl₆). It exhibits a wide band gap (E_g) of about 4.11 eV. Moreover, [R-HQ]₂SnCl₆ undergoes a phase transition around 330 K (T_c) and shows distinct dielectric switching characteristics with good repeatability. This work enriches the chiral lead-free OIMHS family and stimulates further exploration of chiral lead-free OIMHS switching materials
- Lead-free,
- Chirality,
- Organic-inorganic metal halides,
- Dielectric switch,
- Phase transition
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