Citation: Xiaofang Chen, Ya Wang, Min Feng, Die Deng, Xiaoyi Xie, Caixia Deng, Kashif Nawaz Khattak, Xiupei Yang. Dual-active-site Fe/Cu single-atom nanozymes with multifunctional specific peroxidase-like properties for S²⁻ detection and dye degradation[J]. Chinese Chemical Letters, ;2023, 34(6): 107969. doi: 10.1016/j.cclet.2022.107969 shu

Dual-active-site Fe/Cu single-atom nanozymes with multifunctional specific peroxidase-like properties for S²⁻ detection and dye degradation

Xiaofang Chen ^a ,
Ya Wang ^{a, *,} ,
Min Feng ^a ,
Die Deng ^a ,
Xiaoyi Xie ^a ,
Caixia Deng ^b ,
Kashif Nawaz Khattak ^a ,
Xiupei Yang ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, China West Normal University, Nanchong 637000, China
b.
College of Environmental Science and Engineering, China West Normal University, Nanchong 637000, China

ywang312@163.com

xiupeiyang@cwnu.edu.cn

Received Date: 31 August 2022
Revised Date: 18 October 2022
Accepted Date: 1 November 2022
Available Online: 4 November 2022

Figures(7)

Designing single-atom nanozymes with densely exposed metal atom active sites and enhancing catalytic activity to detect pollutants remain a serious challenge. Herein, we reported a single-atom nanozyme with layered stacked Fe/Cu dual active sites (Fe/Cu-NC SAzyme) synthesized via hydrothermal and high-temperature pyrolysis using folic acid as a template. Compared with Fe-NC and Cu-NC SAzyme, Fe/Cu-NC SAzyme has higher peroxidase-like activity, which indicates that the doping of synthesized Fe/Cu bimetals can improve the catalytic activity and that the atomic loading of Fe and Cu in Fe/Cu-NC is 5.5 wt% and 2.27 wt%, respectively. When S²⁻ is added to the Fe/Cu-NC catalytic system, a high-sensitivity and high-selectivity S²⁻ colorimetric sensing platform can be established, with a wide linear range (0.09–6 µmol/L) and a low detection limit (30 nmol/L), which can be used to detect S²⁻ in environmental water samples. What's more, the Fe/Cu-NC SAzyme can activate peroxymonosulfate (PMS) to degrade 99.9% of rhodamine B (RhB) within 10 min with a degradation kinetics of 0.5943 min⁻¹. This work details attractive applications in Fe/Cu-NC SAzyme colorimetric sensing and dye degradation.
- Single-atom nanozymes,
- Dual active sites,
- Peroxidase-like catalyst,
- Colorimetric detection,
- Dye degradation
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沈阳化工大学材料科学与工程学院沈阳 110142

Dual-active-site Fe/Cu single-atom nanozymes with multifunctional specific peroxidase-like properties for S2− detection and dye degradation

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通讯作者: 陈斌, bchen63@163.com

Dual-active-site Fe/Cu single-atom nanozymes with multifunctional specific peroxidase-like properties for S²⁻ detection and dye degradation