Citation: Yanxia Wang, Jianping Sheng, Xiaoli Zhao, Ye He, Fan Dong, Yanjuan Sun. Boosted photocatalytic efficiency of GQDs sensitized (BiO)₂CO₃/β-Bi₂O₃ heterojunction via enhanced interfacial charge transfer[J]. Chinese Chemical Letters, ;2023, 34(6): 107967. doi: 10.1016/j.cclet.2022.107967 shu

Boosted photocatalytic efficiency of GQDs sensitized (BiO)₂CO₃/β-Bi₂O₃ heterojunction via enhanced interfacial charge transfer

Yanxia Wang ^a ,
Jianping Sheng ^{a, *,} ,
Xiaoli Zhao ^a ,
Ye He ^a ,
Fan Dong ^b ,
Yanjuan Sun ^{a, *,}

a.
School of Resources and Environment, University of Electronic Science and Technology of China, Chengdu 611731, China
b.
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 611731, China

jpshengchn@163.com

sunyj@uestc.edu.cn

Received Date: 20 June 2022
Revised Date: 18 October 2022
Accepted Date: 30 October 2022
Available Online: 4 November 2022

Figures(5)

The NO gas is easily oxidized to form toxic by-products (NO₂) during the oxidation process, which are adsorbed on the catalyst surface and inhibit the subsequent reaction. For photocatalytic NO removal, a significant challenge is to achieve catalytic stability while maintaining high conversion efficiency. Here, we fabricated a (BiO)₂CO₃/β-Bi₂O₃ heterostructure that enables efficient charge transfer and promotes the NO removal. We propose that the catalytic stability depends on the heterojunction structure, which is able to generate interfacial charge transfer channels. In addition, we further introduce graphene quantum dots on the heterojunction structure, which further strengthens the interfacial charge transfer dynamics and finally realizes that the NO₂ byproduct could gain electrons and convert to the final product (nitrite or nitrate). This composite structure not only exhibits high activity for NO removal but also maintains long-term stability under visible light.
- Heterostructure,
- GQDs,
- Photocatalysis,
- Charge transfer,
- Reaction mechanism
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Boosted photocatalytic efficiency of GQDs sensitized (BiO)2CO3/β-Bi2O3 heterojunction via enhanced interfacial charge transfer

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通讯作者: 陈斌, bchen63@163.com

Boosted photocatalytic efficiency of GQDs sensitized (BiO)₂CO₃/β-Bi₂O₃ heterojunction via enhanced interfacial charge transfer