Citation: Zi-Xin Yang, Liangchuan Lai, Jingze Chen, Hong Yan, Ke-Yin Ye, Fen-Er Chen. Stereoselective electrochemical carboxylation of α,β-unsaturated sulfones[J]. Chinese Chemical Letters, ;2023, 34(6): 107956. doi: 10.1016/j.cclet.2022.107956 shu

Stereoselective electrochemical carboxylation of α,β-unsaturated sulfones

Zi-Xin Yang ^a ,
Liangchuan Lai ^a ,
Jingze Chen ^a ,
Hong Yan ^{a, *,} ,
Ke-Yin Ye ^{a, *,} ,
Fen-Er Chen ^{a, b, c, *,}

a.
Institute of Pharmaceutical Science and Technology, College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
Department of Chemistry, Engineering Center of Catalysis and Synthesis for Chiral Molecules, Fudan University, Shanghai 200433, China
c.
Shanghai Engineering Research Center of Industrial Asymmetric Catalysis of Chiral Drugs, Fudan University, Shanghai 200433, China

hongyan@fzu.edu.cn

kyye@fzu.edu.cn

rfchen@fudan.edu.cn

Received Date: 3 May 2022
Revised Date: 14 October 2022
Accepted Date: 23 October 2022
Available Online: 27 October 2022

Figures(5)

As an attractive C1 synthon, carbon dioxide (CO₂) has been extensively used in organic synthesis to produce carboxylic acids. In this research, stereoselective electrochemical carboxylation of α,β-unsaturated sulfones has been developed under transition-metal-free conditions. All the cinnamic acids and the derivatives are obtained selectively in the E-configuration. Besides, arylpropiolates also can be produced from alkynyl sulfones.
- Electrosynthesis,
- Carbon dioxide,
- Carboxylation,
- α,β-Unsaturated sulfone,
- α,β-Unsaturated carboxylic acid
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