Citation: Qian Zhou, Shanqiang Wang, Xiaoyun Ran, Linzhi Shen, Xiaolin Luo, Gui Wang, Hui Yang, Zhouyu Wang, Xiaoqi Yu. The water-soluble bicyclic 2-pyridone-based fluorescent probe for fast and selective detection of hypochlorite[J]. Chinese Chemical Letters, ;2023, 34(6): 107922. doi: 10.1016/j.cclet.2022.107922 shu

The water-soluble bicyclic 2-pyridone-based fluorescent probe for fast and selective detection of hypochlorite

Qian Zhou ^{a, 1} ,
Shanqiang Wang ^{b, 1} ,
Xiaoyun Ran ^{a, 1} ,
Linzhi Shen ^a ,
Xiaolin Luo ^a ,
Gui Wang ^b ,
Hui Yang ^a ,
Zhouyu Wang ^{a, *,} ,
Xiaoqi Yu ^{a, b, c, *,}

a.
Asymmetric Synthesis and Chiral Technology Key Laboratory of Sichuan Province, Research and Application of Small Organic Chiral Molecules Key Laboratory of Yibin City, Department of Chemistry, Xihua University, Chengdu 610039, China
b.
School of Food and Bioengineering, Xihua University, Chengdu 610039, China
c.
Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China

zhouyuwang@mail.xhu.edu.cn

xqyu@scu.edu.cn

Received Date: 2 August 2022
Revised Date: 10 October 2022
Accepted Date: 18 October 2022
Available Online: 20 October 2022

Figures(6)

As a strong oxidizer, hypochlorite (ClO^–) are widely employed as bleaching agents and disinfectants. Determination of ClO^– is required to ensure bactericidal effects and avoid hazards caused by excessive residual chlorine. Herein, the derivative bicyclic 2-pyridone, namely DHIP-Py, was prepared successfully to establish a new ClO^–-quantitative method. The probe exhibits excellent ClO^– selectivity over other ROS and anions/cations, high sensitivity (LOD = 1.32 µmol/L), fast response (<5 s), and wide-pH tolerance (pH 4~10). Benefit from its good water solubility, DHIP-Py is well suited for water sample analysis and has been successfully applied to detect ClO^– in real-world food and environmental samples, including tap water, bottled water and river water. The detection results were essentially identical to that of obtained from traditional DPD method. Moreover, visual detection of ClO^– via filter paper-based solid sensor and imaging of ClO^– in Escherichia coli were also achieved by DHIP-Py. These satisfactory results demonstrate that this bicyclic 2-pyridone-based hypochlorite probe is a promising free chlorine chemosensor with great potential for analytical applications.
- Fluorescent probe,
- Hypochlorite,
- Bicyclic 2-pyridone,
- Tap water,
- Bioimaging
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